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1. 发明申请

US20080182945A1 Mixtures Based on Thermoplastic Elastomers 有权
标题翻译：基于热塑性弹性体的混合物
公开(公告)号：US20080182945A1
公开(公告)日：2008-07-31
申请号：US11911219
申请日：2006-04-12
申请人： Frederic Malet , Thibaut Montanari , Christophe Lacroix
发明人： Frederic Malet , Thibaut Montanari , Christophe Lacroix
IPC分类号： C08L77/02
CPC分类号： C08L77/12 , C08L77/00 , C08L77/02 , C08L77/06 , C08L2666/20
摘要： The invention relates to a mixture comprising by weight, to give a total of 100%, 99-10% a polyamide block and polyether block copolymer (A) predominantly consisting of lauryl lactam radicals, 1-99% at least one type of polymer (B) selected from polyamides other than polyamide 12, copolyamides which do not consist of the lauryl lactam radicals and the polyamide block and polyether block copolymers whose polyamide blocks do not predominantly consist of the lauryl lactam radicals. The articles, for example, films, foils, strings and tubes made from the inventive mixture are also disclosed.
摘要翻译：本发明涉及一种重量比的混合物，以总共100％，99-10％为主要由月桂基内酰胺基团组成的聚酰胺嵌段和聚醚嵌段共聚物（A），1-99％至少一种类型的聚合物 B）选自聚酰胺12以外的聚酰胺，不由月桂基内酰胺基团组成的共聚酰胺和聚酰胺嵌段和聚醚嵌段共聚物，其聚酰胺嵌段不主要由月桂基内酰胺基团组成。还公开了由本发明混合物制成的制品，例如薄膜，箔，线和管。

2. 发明授权

US07718740B2 Mixtures based on thermoplastic elastomers 有权
标题翻译：基于热塑性弹性体的混合物
公开(公告)号：US07718740B2
公开(公告)日：2010-05-18
申请号：US11911219
申请日：2006-04-12
申请人： Frederic Malet , Thibaut Montanari , Christophe Lacroix
发明人： Frederic Malet , Thibaut Montanari , Christophe Lacroix
IPC分类号： C08L77/00
CPC分类号： C08L77/12 , C08L77/00 , C08L77/02 , C08L77/06 , C08L2666/20
摘要： The invention relates to a mixture comprising by weight, to give a total of 100%, 99-10% a polyamide block and polyether block copolymer (A) predominately consisting of lauryl lactam radicals, 1-99% at least on type of polymer (B) selected from polyamides other than polyamide 12, copolyamides which do not consist of the lauryl lactam radicals and the polyamide block and polyether block copolymers whose polyamide blocks do not predominantly consist of the lauryl lactam radicals. The articles, for example, films, foils, strings and tubes made from the inventive mixture are also disclosed.
摘要翻译：本发明涉及一种包含重量比的混合物，以总共100％，99-10％为主要由月桂基内酰胺基团组成的聚酰胺嵌段和聚醚嵌段共聚物（A），1-99％的至少一种类型的聚合物 B）选自聚酰胺12以外的聚酰胺，不由月桂基内酰胺基团组成的共聚酰胺和聚酰胺嵌段和聚醚嵌段共聚物，其聚酰胺嵌段不主要由月桂基内酰胺基团组成。还公开了由本发明混合物制成的制品，例如薄膜，箔，线和管。

3. 发明授权

US08952103B2 Copolymers having amide units and ether units with improved optical properties 有权
标题翻译：具有酰胺单元和醚单元的共聚物具有改进的光学性能
公开(公告)号：US08952103B2
公开(公告)日：2015-02-10
申请号：US12302668
申请日：2007-06-08
申请人： Philippe Blondel , Inci Turan , Thibaut Montanari , Frederic Malet
发明人： Philippe Blondel , Inci Turan , Thibaut Montanari , Frederic Malet
IPC分类号： C08L77/12 , C08G69/40
CPC分类号： C08G69/40
摘要： The present invention is a copolymer based on amide units and ether units, wherein the amide units being comprise a major portion of an equimolar combination of at least one diamine and at least one dicarboxylic acid, the diamine(s) is/are mainly cycloaliphatic and the dicarboxylic acid(s) is/are mainly linear and aliphatic, the amide units optionally comprise, but in a minor proportion, at least one other polyamide comonomer, the respective proportions of ether and amide unit monomers are selected in such a way that said copolymer is highly transparent to such an extent that the transmittance at 560 nm on a plate 2 mm thick is greater than 75%; the crystallinity of said copolymer is such that the enthalpy of fusion during the first heating of a ISO DSC (delta Hm(2)) is at least 30 J/g, where the mass is related to the number of amide units contained or of polyamide contained, which fusion corresponds to that of the amide units; and said copolymer has a glass transition temperature of at least 75° C.
摘要翻译：本发明是基于酰胺单元和醚单元的共聚物，其中酰胺单元包含至少一种二胺和至少一种二羧酸的等摩尔组合的主要部分，二胺主要是脂环族和二羧酸主要是直链和脂族的，酰胺单元任选地包含但少量的至少一种其它聚酰胺共聚单体，醚和酰胺单元单体的各自比例选择为使得所述共聚物高度透明，使得2mm厚的560nm处的透射率大于75％; 所述共聚物的结晶度使得在ISO DSC（ΔHm（2））的第一次加热期间的熔融焓为至少30J / g，其中质量与所含酰胺单元或聚酰胺的数量有关包含，该融合对应于酰胺单元的融合; 并且所述共聚物的玻璃化转变温度至少为75℃

4. 发明申请

US20090264601A1 COPOLYMERS HAVING AMIDE UNITS AND ETHER UNITS WITH IMPROVED OPTICAL PROPERTIES 有权
标题翻译：具有改进光学特性的单元和单元的共聚物
公开(公告)号：US20090264601A1
公开(公告)日：2009-10-22
申请号：US12302668
申请日：2007-06-08
申请人： Philippe Blondel , Inci Turan , Thibaut Montanari , Frederic Malet
发明人： Philippe Blondel , Inci Turan , Thibaut Montanari , Frederic Malet
IPC分类号： C08G69/26 , C08G69/48
CPC分类号： C08G69/40
摘要： A subject-matter of the present invention is a copolymer based on amide units and based on ether units, the amide units being composed predominantly of an equimolar combination of at least one diamine and of at least one dicarboxylic acid, the diamine or diamines being predominantly cycloaliphatic and the dicarboxylic acid or acids being predominantly linear aliphatic, it being possible for the amide units optionally to comprise, but to a minor extent, at least one other polyamide comonomer, the respective proportions of monomers of the ether and amide units being chosen so that: the said copolymer exhibits a high transparency which is such that the transmission at 560 nm through a sheet with a thickness of 2 mm is greater than 75%; the said copolymer exhibits a crystallinity such that the enthalpy of fusion during the second heating of an ISO DSC (delta Hm(2)) is at most equal to 30 J/g, the weight being with respect to the amount of amide units present or of polyamide present, this melting corresponding to that of the amide units; the said copolymer has a glass transition temperature at least equal to 75° C.
摘要翻译：本发明的主题是基于酰胺单元并基于醚单元的共聚物，酰胺单元主要由至少一种二胺和至少一种二羧酸的等摩尔组合组成，二胺或二胺主要是脂环族和二羧酸或酸主要是直链脂肪族，酰胺单元可能任选地包含至少一种其它聚酰胺共聚单体，所以单独的醚和酰胺单元的相应比例被选择为所述共聚物表现出高透明度，使得通过厚度为2mm的片材在560nm的透射率大于75％; 所述共聚物显示出结晶度，使得在ISO DSC（ΔHm（2））的第二次加热期间的熔化焓最多等于30J / g，其重量相对于存在的酰胺单元的量或的聚酰胺存在，这种熔融对应于酰胺单元的熔融; 所述共聚物的玻璃化转变温度至少等于75℃

5. 发明授权

US11332576B2 Block copolymer derived from renewable materials and method for making such a block copolymer 有权
公开(公告)号：US11332576B2
公开(公告)日：2022-05-17
申请号：US13639662
申请日：2011-04-05
申请人： Frederic Malet , Guillaume Le , Julien Jouanneau
发明人： Frederic Malet , Guillaume Le , Julien Jouanneau
IPC分类号： C08G65/26 , C08G69/40 , C08G63/672 , C12P7/10 , C12P5/02 , C08L71/02 , C07D301/02 , C08G18/48
摘要： The invention relates to a block copolymer derived from at least one ethylene oxide and/or propylene oxide monomer containing 14C.
The present invention also relates to a method for preparing such a block copolymer.

6. 发明申请

US20120108694A1 METHOD FOR SYNTHESISING A BLOCK COPOLYMER ALLOY HAVING IMPROVED ANTISTATIC PROPERTIES 有权
标题翻译：合成具有改进抗静电性能的嵌段共聚物合金的方法
公开(公告)号：US20120108694A1
公开(公告)日：2012-05-03
申请号：US13147505
申请日：2010-02-02
申请人： Frederic Malet , Eric Gamache , Perrine Babin , Benoit Andre , Michael Werth
发明人： Frederic Malet , Eric Gamache , Perrine Babin , Benoit Andre , Michael Werth
IPC分类号： C08G81/00 , H01B1/22 , B29C71/00 , C08L77/02 , H01B1/12 , B82Y30/00
CPC分类号： C08G69/40 , C08K5/0075 , C08L77/12 , C08L87/005 , C08L101/00 , C08L2666/24
摘要： The invention relates to a method for synthesising a block copolymer alloy including at least one rigid polyamide block PA, including the steps of: a) producing said block copolymer; b) adding, during step a) and to at least a portion of said block copolymer, 0.1 to 30 wt % of at least one organic salt in the molten state relative to the total weight of the alloy, so that the alloy thus obtained has improved antistatic properties and identical mechanical properties when compared to the same polymer produced without adding an organic salt. The invention also relates to a block copolymer alloy having improved antistatic properties and obtained by said method, to the use thereof in a polymer matrix, and to a composition containing same.
摘要翻译：本发明涉及一种合成包含至少一种刚性聚酰胺嵌段PA的嵌段共聚物合金的方法，包括以下步骤：a）制备所述嵌段共聚物; b）在步骤a）期间和在至少一部分所述嵌段共聚物中，相对于合金的总重量，在熔融状态下加入0.1至30重量％的至少一种有机盐，使得由此获得的合金具有当与不添加有机盐制备的相同聚合物相比时，改善的抗静电性能和相同的机械性能。本发明还涉及具有改进的抗静电性能并通过所述方法获得的嵌段共聚物合金，其在聚合物基质中的用途以及含有它的组合物。

7. 发明申请

US20100234539A1 POLYAMIDE, POLYESTER AND POLYETHER BLOCK COPOLYMER 有权
标题翻译：聚酰胺，聚酯和聚醚嵌段共聚物
公开(公告)号：US20100234539A1
公开(公告)日：2010-09-16
申请号：US12301772
申请日：2007-12-05
申请人： Frederic Malet
发明人： Frederic Malet
IPC分类号： C08L77/06 , A63B37/00
CPC分类号： C08G69/44 , A63B37/0024 , A63B37/0039 , A63B37/0051 , A63B37/0093 , C08G69/40 , C08G81/00 , C08G2261/126 , C08L77/06 , C08L77/12
摘要： The subject of the invention is a segmented block copolymer comprising polyamide blocks, polyester blocks and polyether blocks, of general formula: -[HB-SB]n- (I) in which: HB or Hard Block represents a polyamide block; SB or Soft Block represents a blend of polyether blocks and polyester blocks; and n represents the number of -HB-SB- units of said copolymer, characterized in that the percentage of polyether blocks (abbreviated to PE blocks) is strictly greater than 15% by weight of said copolymer and that said polyester blocks (abbreviated to PES blocks) have a glass transition temperature Tg below 10° C.
摘要翻译：本发明的主题是包含以下通式的聚酰胺嵌段，聚酯嵌段和聚醚嵌段的分段嵌段共聚物： - [HB-SB] n - （I）其中：HB或硬嵌段代表聚酰胺嵌段; SB或软块代表聚醚嵌段和聚酯嵌段的混合物; n表示所述共聚物的-HB-SB-单元数，其特征在于聚醚嵌段（缩写为PE嵌段）的百分比严格大于所述共聚物的15重量％，所述聚酯嵌段（缩写为PES 块）的玻璃化转变温度Tg低于10℃

8. 发明授权

US09914804B2 Method for synthesising a block copolymer alloy having improved antistatic properties 有权
公开(公告)号：US09914804B2
公开(公告)日：2018-03-13
申请号：US13147505
申请日：2010-02-02
申请人： Frederic Malet , Eric Gamache , Perrine Babin , Benoit Andre , Michael Werth
发明人： Frederic Malet , Eric Gamache , Perrine Babin , Benoit Andre , Michael Werth
IPC分类号： C08G69/40 , C08L87/00 , C08L101/00 , C08K5/00 , C08L77/12
CPC分类号： C08G69/40 , C08K5/0075 , C08L77/12 , C08L87/005 , C08L101/00 , C08L2666/24
摘要： The invention relates to a method for synthesising a block copolymer alloy including at least one rigid polyamide block PA, including the steps of: a) producing said block copolymer; b) adding, during step a) and to at least a portion of said block copolymer, 0.1 to 30 wt % of at least one organic salt in the molten state relative to the total weight of the alloy, so that the alloy thus obtained has improved antistatic properties and identical mechanical properties when compared to the same polymer produced without adding an organic salt. The invention also relates to a block copolymer alloy having improved antistatic properties and obtained by said method, to the use thereof in a polymer matrix, and to a composition containing same.

9. 发明申请

US20130202831A1 PEBA-BASED COMPOSITION AND USE THEREOF FOR THE MANUFACTURE OF A TRANSPARENT ARTICLE HAVING HIGH-VELOCITY IMPACT RESISTANCE 审中-公开
标题翻译：基于PEBA的组合物及其用于具有高速冲击电阻的透明物品的制造
公开(公告)号：US20130202831A1
公开(公告)日：2013-08-08
申请号：US13823752
申请日：2011-09-27
申请人： Sophie Chhun , Benjamin Saillard , Frederic Malet , Jerome Allanic
发明人： Sophie Chhun , Benjamin Saillard , Frederic Malet , Jerome Allanic
IPC分类号： C08L77/06 , B29C45/00 , C08G81/00
CPC分类号： C08L77/06 , B29C45/0001 , C08G69/40 , C08G81/00 , C08L2205/02 , Y10T428/1352 , Y10T428/139
摘要： A copolymer containing polyether (PE) block(s) and polyamide (PE) block(s) issued for the manufacture of a transparent article having high-velocity impact resistance, and impact strength. In said copolymer: PA blocks comprise more than 50 mol % of an equimolar combination of at least one cycloaliphatic diamine and of at least one aliphatic dicarboxylic acid having from 12 to 36 carbon atoms, represent 20 to 90% by weight, out of the total weight of the copolymer, have a number-average molecular weight of 1000 to 10 000 g/mol, and the PE blocks represent 10 to 80% by weight, out of the total weight of the copolymer, and have a number-average molecular weight of 200-1000 g/mol.
摘要翻译：含有聚醚（PE）嵌段和聚酰胺（PE）嵌段的共聚物，用于制造具有高速冲击强度的透明制品和冲击强度。在所述共聚物中：PA嵌段包含超过50摩尔％的至少一种脂环族二胺和至少一种具有12至36个碳原子的脂族二羧酸的等摩尔组合，占总重量的20至90重量％共聚物的重量的数均分子量为1000〜10000g / mol，PE嵌段占共聚物总重量的10〜80重量％，数均分子量为200-1000g / mol。

10. 发明申请

US20150048541A1 METHOD FOR EXTRUDING A POLYMER IN THE PRESENCE OF WATER 有权
标题翻译：在水中挤出聚合物的方法
公开(公告)号：US20150048541A1
公开(公告)日：2015-02-19
申请号：US13976640
申请日：2011-12-23
申请人： Frederic Malet , Jean-Jacques Flat , Francois Touchaleaume , Jacques Devaux , Patricia Krawczak , Michel Sclavons , Jeremie Soulestin
发明人： Frederic Malet , Jean-Jacques Flat , Francois Touchaleaume , Jacques Devaux , Patricia Krawczak , Michel Sclavons , Jeremie Soulestin
IPC分类号： B29C47/00
CPC分类号： B29C47/0071 , B29C47/0004 , B29C47/0011 , B29C47/0019 , B29C47/0023 , B29C47/1045 , B29C47/1063 , B29C47/762 , B29C47/805 , B29K2077/00 , B29K2105/0005 , B29K2105/16 , C08G63/916 , C08G69/40
摘要： The invention relates to a method for converting a polycondensed elastomeric thermoplastic polymer, including a step of extruding the polycondensed elastomeric thermoplastic polymer in the presence of water. The polycondensed elastomeric thermoplastic polymer is in particular chosen from copolymer block amides, copolyethers or copolyester block urethanes, copolyether block esters and the mixtures thereof, and is preferably a copolyether block amide.
摘要翻译：本发明涉及一种用于转化聚缩聚弹性体热塑性聚合物的方法，包括在水存在下挤出缩聚的弹性体热塑性聚合物的步骤。聚缩聚弹性体热塑性聚合物特别地选自共聚物嵌段酰胺，共聚醚或共聚酯嵌段聚氨酯，共聚醚嵌段酯及其混合物，并且优选为共聚醚嵌段酰胺。

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