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1. 发明授权

US5679808A Tertiary non-linear optical material 失效
标题翻译：三次非线性光学材料
公开(公告)号：US5679808A
公开(公告)日：1997-10-21
申请号：US307707
申请日：1995-01-26
申请人： Akira Mizoguchi , Yasuhiro Hattori , Michiru Kubata
发明人： Akira Mizoguchi , Yasuhiro Hattori , Michiru Kubata
IPC分类号： C09K9/02 , G02F1/35 , G02F1/355 , G02F1/361 , C07C50/24 , C07C50/00 , C07C40/703
CPC分类号： G02F1/3619 , G02F1/361 , G02F1/3611
摘要： The present invention discloses a tertiary non-linear optical material comprising a quinone derivative expressed by any one of the general formulas: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are as defined above, or the formula: ##STR2## The tertiary non-linear material enables the co-existence of large tertiary non-linear optical susceptibility and high-speed response.
摘要翻译： PCT No.PCT / JP94 / 00177 Sec。 371日期1995年1月26日 102（e）日期1995年1月26日PCT 1994年2月4日PCT PCT。 WO94 / 18601 PCT出版物日期：1994年8月18日本发明公开了一种三次非线性光学材料，其包含由以下通式之一表示的醌衍生物：其中R1， R2，R3，R4，R5和R6如上所定义，或下式：（4）第三非线性材料能够共存大的三次非线性光学敏感性和高速响应。

2. 发明授权

US5385116A Method for producing organic crystal film 失效
标题翻译：有机晶体膜的制造方法
公开(公告)号：US5385116A
公开(公告)日：1995-01-31
申请号：US35704
申请日：1993-03-23
申请人： Yasuhiro Hattori , Akira Mizoguchi , Michiru Kubata
发明人： Yasuhiro Hattori , Akira Mizoguchi , Michiru Kubata
IPC分类号： B29C33/42 , B29C37/00 , B29D7/01 , C30B7/00 , C30B11/00 , C30B29/54
CPC分类号： B29C33/42 , B29C37/0053 , B29D7/01 , C30B11/00 , C30B29/58 , C30B7/00 , C30B7/005 , B29K2105/0002 , B29K2105/0067 , B29K2105/0073 , B29K2995/0013 , B29K2995/0018 , B29K2995/0041 , B29K2995/0074 , Y10S117/902 , Y10S117/919
摘要： A method for producing a crystal film of an organic compound from a molten liquid or solution of the organic compound on a substrate or between a pair of substrates, the substrate or at least one of the pair of substrates having on a part of the surface thereof a three-dimensional geometrical structure capable of controlling the direction of the crystal growth of the organic compound, and the other part of the surface thereof than the part having a three-dimensional geometrical structure being smooth. The resulting crystal film comprises a sufficiently large single crystal for application to a practical element with its orientation controlled in an arbitrarily selected direction.
摘要翻译：一种从熔融液体或有机化合物的溶液在基板上或一对基板之间制造有机化合物的晶体膜的方法，所述基板或所述一对基板中的至少一个在其一部分表面上能够控制有机化合物的晶体生长方向的三维几何结构，其表面的另一部分比具有三维几何结构的部分光滑。所得到的晶体膜包括足够大的单晶，用于实际元件，其取向以任意选择的方向控制。

3. 发明授权

US5097527A Fiber type wavelength converter and module 失效
标题翻译：光纤类型波长转换器和模块
公开(公告)号：US5097527A
公开(公告)日：1992-03-17
申请号：US675803
申请日：1991-03-27
申请人： Michiru Kubata , Takafumi Uemiya , Naota Uenishi , Yasuhiro Hattori
发明人： Michiru Kubata , Takafumi Uemiya , Naota Uenishi , Yasuhiro Hattori
IPC分类号： G02F1/35 , C09K9/02 , G02F1/355 , G02F1/361 , G02F1/37 , G02F1/383
CPC分类号： G02F1/383
摘要： A fiber type wavelength converter comprising a cladding made of a thin glass tube an inner wall of which is coated with a coupling agent, and a core which is contained in the cladding and made of a single crystal of methyl 4-hydroxybenzoate, which can convert a fundamental wave to a second harmonic effectively.

4. 发明申请

US20130045400A1 REDOX FLOW BATTERY 有权
标题翻译： REDOX流量电池
公开(公告)号：US20130045400A1
公开(公告)日：2013-02-21
申请号：US13583585
申请日：2011-03-08
申请人： Yongrong Dong , Toshio Shigematsu , Takahiro Kumamoto , Michiru Kubata
发明人： Yongrong Dong , Toshio Shigematsu , Takahiro Kumamoto , Michiru Kubata
IPC分类号： H01M4/36 , H01M2/38
CPC分类号： H01M8/188 , H01M2/40 , H01M8/04186 , H01M8/18 , H01M8/184 , Y02E60/528
摘要： Provided are a redox flow battery (RF battery) in which a positive electrode electrolyte and a negative electrode electrolyte are supplied to a battery cell including a positive electrode, a negative electrode, and a membrane, to charge and discharge the battery, and a method of operating the RF battery. The positive electrode electrolyte contains a manganese ion, or both of a manganese ion and a titanium ion. The negative electrode electrolyte contains at least one type of metal ion selected from a titanium ion, a vanadium ion, a chromium ion, a zinc ion, and a tin ion. The RF battery can have a high electromotive force and can suppress generation of a precipitation of MnO2 by containing a titanium ion in the positive electrode electrolyte, or by being operated such that the positive electrode electrolyte has an SOC of not more than 90%.
摘要翻译：本发明提供一种氧化还原液流电池（RF电池），其中将正极电解质和负极电解质供给到包括正极，负极和膜的电池的电池中，以对电池进行充电和放电，操作RF电池。正极电解质含有锰离子或锰离子和钛离子两者。负极电解质含有选自钛离子，钒离子，铬离子，锌离子和锡离子中的至少一种金属离子。 RF电池可以具有高的电动势，并且可以通过在正极电解质中含有钛离子来抑制MnO 2的析出，或者通过使正极电解质的SOC不大于90％来进行操作。

5. 发明授权

US06613298B2 Trivalent and tetravalent mixed vanadium compound producing method and vanadium electrolyte producing method 有权
公开(公告)号：US06613298B2
公开(公告)日：2003-09-02
申请号：US09896105
申请日：2001-07-02
申请人： Yasuyuki Tanaka , Ken Horikawa , Muneo Mita , Nobuyuki Tokuda , Michiru Kubata
发明人： Yasuyuki Tanaka , Ken Horikawa , Muneo Mita , Nobuyuki Tokuda , Michiru Kubata
IPC分类号： C01G3100
CPC分类号： H01M8/188 , C01G31/00 , H01M4/9016 , Y02E60/528
摘要： The present invention provides method of producing a trivalent and tetravalent mixed vanadium compound having excellent solubility with sulfuric acid directly from a tetravalent or pentavalent vanadium compound by using a reducing agent,and a method of producing a vanadium electrolyte. For example, a vanadium compound mainly containing a pentavalent vanadium compound; sulfur and concentrated sulfuric acid in molar ratios with respect to (one mol of vanadium atom in the pentavalent vanadium compound) 0.35 to 0.4:1.2 to 1.9 are kneaded into paste form, and the paste-form mixture is calcined at a temperature of not less than 150° C. to less than 440° C. so that a trivalent and tetravalent mixed vanadium compound is obtained, and a redox flow battery-use vanadium electrolyte is obtained by dissolving the trivalent and tetravalent mixed vanadium compound in a sulfuric acid solution.

6. 发明申请

US20120045680A1 REDOX FLOW BATTERY 有权
标题翻译： REDOX流量电池
公开(公告)号：US20120045680A1
公开(公告)日：2012-02-23
申请号：US13148880
申请日：2010-09-10
申请人： Yongrong Dong , Toshio Shigematsu , Takahiro Kumamoto , Michiru Kubata
发明人： Yongrong Dong , Toshio Shigematsu , Takahiro Kumamoto , Michiru Kubata
IPC分类号： H01M4/36 , H01M4/48 , H01M10/02 , H01M4/60 , H01M4/583 , H01M2/14 , H01M4/38 , H01M4/50
CPC分类号： H01M8/188 , H01M2/40 , H01M8/04186 , H01M8/18 , H01M8/184 , Y02E60/528
摘要： A redox flow battery having a high electromotive force and capable of suppressing generation of a precipitation is provided. In a redox flow battery 100, a positive electrode electrolyte and a negative electrode electrolyte are supplied to a battery cell including a positive electrode 104, a negative electrode 105, and a membrane 101 interposed between the electrodes 104 and 105, to charge and discharge the battery. The positive electrode electrolyte contains a manganese ion, or both of a manganese ion and a titanium ion. The negative electrode electrolyte contains at least one type of metal ion selected from a titanium ion, a vanadium ion, a chromium ion, a zinc ion, and a tin ion. The redox flow battery 100 can suppress generation of a precipitation of MnO2, and can be charged and discharged well by containing a titanium ion in the positive electrode electrolyte, or by being operated such that the positive electrode electrolyte has an SOC of not more than 90%. In addition, the redox flow battery 100 can have a high electromotive force equal to or higher than that of a conventional vanadium-based redox flow battery.
摘要翻译：提供具有高电动势并且能够抑制降水产生的氧化还原液流电池。在氧化还原液流电池100中，将正极电解质和负极电解质供给到包括正极104，负极105和介于电极104和105之间的膜101的电池单元，以对电池。正极电解质含有锰离子或锰离子和钛离子两者。负极电解质含有选自钛离子，钒离子，铬离子，锌离子和锡离子中的至少一种金属离子。氧化还原液流电池100可以抑制MnO 2的析出的产生，并且可以通过在正极电解质中含有钛离子，或者通过使正极电解质的SOC不大于90的SOC被充分地充放电％。此外，氧化还原液流电池100可以具有等于或高于常规钒基氧化还原液流电池的高电动势。

7. 发明授权

US07258947B2 Electrolyte for redox flow battery, and redox flow battery 有权
标题翻译：电解液用于氧化还原电池，氧化还原电池
公开(公告)号：US07258947B2
公开(公告)日：2007-08-21
申请号：US10479710
申请日：2002-04-30
申请人： Michiru Kubata , Hiroyuki Nakaishi , Nobuyuki Tokuda
发明人： Michiru Kubata , Hiroyuki Nakaishi , Nobuyuki Tokuda
IPC分类号： H01M6/00
CPC分类号： H01M8/188 , H01M2300/0008 , H01M2300/0011 , Y02E60/528 , Y02P70/56
摘要： The present invention provides electrolyte that can suppress reduction of battery efficiencies and capacities with increased cycles of charge/discharge of the battery, a method for producing the same, and a redox flow battery using the same electrolyte. The redox flow battery uses the electrolyte having a NH4 content of not more than 20 ppm and a relation of Si concentration (ppm)×electrolyte quantity (m3)/electrode area (m2) of less than 5 ppm·m3/m2. By limiting a quantity of contaminants in the electrolyte, a clogging of carbon electrodes to cause reduction of the battery performances with increased charge/discharge operations can be suppressed.
摘要翻译：本发明提供电解质，其可以通过增加电池的充电/放电循环，其制造方法和使用相同电解质的氧化还原液电池来抑制电池效率和容量的降低。氧化还原液流电池使用NH 4 S含量不大于20ppm的电解质和Si浓度（ppm）x电解质量（m 3+）的电极面积/电极面积（m 2）小于5ppm.m 3 / m 2。通过限制电解质中的污染物量，可以抑制碳电极的堵塞，从而在增加充电/放电操作时引起电池性能的降低。

8. 发明授权

US09118064B2 Redox flow battery 有权
标题翻译：氧化还原液流电池
公开(公告)号：US09118064B2
公开(公告)日：2015-08-25
申请号：US13583585
申请日：2011-03-08
申请人： Yongrong Dong , Toshio Shigematsu , Takahiro Kumamoto , Michiru Kubata
发明人： Yongrong Dong , Toshio Shigematsu , Takahiro Kumamoto , Michiru Kubata
IPC分类号： H01M4/36 , H01M2/38 , H01M8/18 , H01M8/04 , H01M2/40
CPC分类号： H01M8/188 , H01M2/40 , H01M8/04186 , H01M8/18 , H01M8/184 , Y02E60/528
摘要： Provided are a redox flow battery (RF battery) in which a positive electrode electrolyte and a negative electrode electrolyte are supplied to a battery cell including a positive electrode, a negative electrode, and a membrane, to charge and discharge the battery, and a method of operating the RF battery. The positive electrode electrolyte contains a manganese ion, or both of a manganese ion and a titanium ion. The negative electrode electrolyte contains at least one type of metal ion selected from a titanium ion, a vanadium ion, a chromium ion, a zinc ion, and a tin ion. The RF battery can have a high electromotive force and can suppress generation of a precipitation of MnO2 by containing a titanium ion in the positive electrode electrolyte, or by being operated such that the positive electrode electrolyte has an SOC of not more than 90%.
摘要翻译：本发明提供一种氧化还原液流电池（RF电池），其中将正极电解质和负极电解质供给到包括正极，负极和膜的电池的电池中，以对电池进行充电和放电，操作RF电池。正极电解质含有锰离子或锰离子和钛离子两者。负极电解质含有选自钛离子，钒离子，铬离子，锌离子和锡离子中的至少一种金属离子。 RF电池可以具有高的电动势，并且可以通过在正极电解质中含有钛离子来抑制MnO 2的析出，或者通过使正极电解质的SOC不大于90％来进行操作。

9. 发明授权

US08288030B2 Redox flow battery 有权
标题翻译：氧化还原液流电池
公开(公告)号：US08288030B2
公开(公告)日：2012-10-16
申请号：US13148880
申请日：2010-09-10
申请人： Yongrong Dong , Toshio Shigematsu , Takahiro Kumamoto , Michiru Kubata
发明人： Yongrong Dong , Toshio Shigematsu , Takahiro Kumamoto , Michiru Kubata
IPC分类号： H01M4/24
CPC分类号： H01M8/188 , H01M2/40 , H01M8/04186 , H01M8/18 , H01M8/184 , Y02E60/528
摘要： A redox flow battery having a high electromotive force and capable of suppressing generation of a precipitation is provided. In a redox flow battery 100, a positive electrode electrolyte and a negative electrode electrolyte are supplied to a battery cell including a positive electrode 104, a negative electrode 105, and a membrane 101 interposed between the electrodes 104 and 105, to charge and discharge the battery. The positive electrode electrolyte contains a manganese ion, or both of a manganese ion and a titanium ion. The negative electrode electrolyte contains at least one type of metal ion selected from a titanium ion, a vanadium ion, a chromium ion, a zinc ion, and a tin ion. The redox flow battery 100 can suppress generation of a precipitation of MnO2, and can be charged and discharged well by containing a titanium ion in the positive electrode electrolyte, or by being operated such that the positive electrode electrolyte has an SOC of not more than 90%. In addition, the redox flow battery 100 can have a high electromotive force equal to or higher than that of a conventional vanadium-based redox flow battery.
摘要翻译：提供具有高电动势并且能够抑制降水产生的氧化还原液流电池。在氧化还原液流电池100中，将正极电解质和负极电解质供给到包括正极104，负极105和介于电极104和105之间的膜101的电池单元，以对电池。正极电解质含有锰离子或锰离子和钛离子两者。负极电解质含有选自钛离子，钒离子，铬离子，锌离子和锡离子中的至少一种金属离子。氧化还原液流电池100可以抑制MnO 2的析出的产生，并且可以通过在正极电解质中含有钛离子，或者通过使正极电解质的SOC不大于90的SOC被充分地充放电％。此外，氧化还原液流电池100可以具有等于或高于常规钒基氧化还原液流电池的高电动势。

10. 发明授权

US06872376B2 Modified vanadium compound, producing method thereof, redox flow battery electrolyte composite and redox flow battery electrolyte producing method 有权
标题翻译：改性钒化合物，其制备方法，氧化还原液电池电解质复合材料和氧化还原液电池电解液的制备方法
公开(公告)号：US06872376B2
公开(公告)日：2005-03-29
申请号：US10000127
申请日：2001-12-04
申请人： Yasuyuki Tanaka , Muneo Mita , Ken Horikawa , Nobuyuki Tokuda , Masayuki Furuya , Michiru Kubata
发明人： Yasuyuki Tanaka , Muneo Mita , Ken Horikawa , Nobuyuki Tokuda , Masayuki Furuya , Michiru Kubata
IPC分类号： C01G31/00 , H01M8/18 , C01B17/96
CPC分类号： C01G31/00 , H01M8/188 , Y02E60/528
摘要： A modified vanadium compound characterized in that vanadium sulfate (III), or a mixed vanadium compound of vanadium sulfate (III) and vanadyl sulfate (IV) contains excessive sulfuric acid other than sulfate group composing the vanadium sulfate (III) or the vanadyl sulfate (IV), and when the modified vanadium compound is used, a redox flow battery electrolyte can be prepared easily.
摘要翻译：一种改性钒化合物，其特征在于硫酸钒（III）或硫酸钒（III）和硫酸氧钒（IV）的混合钒化合物含有除了构成硫酸钒（III）或硫酸氧钒的硫酸根以外的过量硫酸 IV），并且当使用改性的钒化合物时，可以容易地制备氧化还原液流电池电解质。

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