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1. 发明授权

US4382065A Fluidized bed apparatus and method of using 失效
标题翻译：流化床装置及其使用方法
公开(公告)号：US4382065A
公开(公告)日：1983-05-03
申请号：US304871
申请日：1981-09-23
申请人： Akinobu Shiga , Masahiro Kakugo , Koji Yamada , Hajime Sadatoshi
发明人： Akinobu Shiga , Masahiro Kakugo , Koji Yamada , Hajime Sadatoshi
IPC分类号： B01J8/34 , B01J8/00 , B01J8/38 , C08F2/38 , C08F10/00 , F27B15/08
CPC分类号： B01J8/386 , B01J8/0065 , C08F10/00
摘要： In a fluidized bed apparatus intended to fluidize solid particles by means of ascending stream gas, the improvement for reducing solid particles entrained from the apparatus, which comprises placing an internal in a free board of the apparatus so that the projected area ratio is not less than 0.8, and the opening proportion to the free board cross-sectional area is within 0.3 to 0.9.
摘要翻译：在旨在通过上升气流使固体颗粒流化的流化床装置中，减少了从装置夹带的固体颗粒的改进，其包括将内部放置在装置的自由板中，使得投影面积比不小于 0.8，与自由板横截面积的开口比例在0.3〜0.9的范围内。

2. 发明授权

US4259461A Process for producing propylene-ethylene block copolymers 失效
标题翻译：制备丙烯 - 乙烯嵌段共聚物的方法
公开(公告)号：US4259461A
公开(公告)日：1981-03-31
申请号：US041462
申请日：1979-05-22
申请人： Akinobu Shiga , Masahiro Kakugo , Yoshiharu Fukui , Koji Yamada , Hajime Sadatoshi , Kazuki Wakamatsu , Hiroshi Yoshioka
发明人： Akinobu Shiga , Masahiro Kakugo , Yoshiharu Fukui , Koji Yamada , Hajime Sadatoshi , Kazuki Wakamatsu , Hiroshi Yoshioka
IPC分类号： C08F297/08
CPC分类号： C08F297/083
摘要： An improved process for producing propylene-ethylene block copolymer is disclosed utilizing a catalyst system comprising (A) a titanium trichloride solid catalyst obtained by reducing titanium tetrachloride with an organoaluminum compound and activating, (B) an organoaluminum compound, and optionally, (C) an electron donor.
摘要翻译：公开了一种用于生产丙烯 - 乙烯嵌段共聚物的改进方法，该催化剂体系包含（A）通过用有机铝化合物还原四氯化钛并活化（B）有机铝化合物和任选的（C）电子供体。

3. 发明授权

US4254237A Process for producing propylene-ethylene block copolymers 失效
标题翻译：制备丙烯 - 乙烯嵌段共聚物的方法
公开(公告)号：US4254237A
公开(公告)日：1981-03-03
申请号：US30523
申请日：1979-04-16
申请人： Akinobu Shiga , Masahiro Kakugo , Hajime Sadatoshi , Kazuki Wakamatsu , Hiroshi Yoshioka
发明人： Akinobu Shiga , Masahiro Kakugo , Hajime Sadatoshi , Kazuki Wakamatsu , Hiroshi Yoshioka
IPC分类号： C08F297/00 , C08F297/08
CPC分类号： C08F297/086
摘要： A process for producing propylene-ethylene block copolymers by a three-step polymerization technique using a stereoregular catalyst, characterized in that the first-step polymerization is carried out by supplying propylene alone or a propylene/ethylene mixture so that the ethylene/propylene reaction ratio is 6/94 or less, thereby polymerizing 60 to 95% by weight of the total polymerization amount, the second-step polymerization is carried out by supplying a propylene/ethylene mixture so that the ethylene/propylene reaction ratio is 15/85 to 79/21, thereby polymerizing 1 to 20% by weight of the total polymerization amount, and the third-step polymerization is carried out by supplying a propylene/ethylene mixture so that the ethylene/propylene reaction ratio is 50/50 to 89/11, thereby polymerizing 4 to 35% by weight of the total polymerization amount, with the ethylene/propylene reaction ratio in the third step made larger than that in the second step. Said process can give propylene-ethylene block copolymers markedly well balanced in impact strength, stiffness, transparency and impact blushing.
摘要翻译：一种通过使用立体规则催化剂的三步聚合技术制备丙烯 - 乙烯嵌段共聚物的方法，其特征在于第一步聚合是通过仅供应丙烯或丙烯/乙烯混合物进行的，以使乙烯/丙烯反应比为6/94以下，由此聚合60〜95重量％的总聚合量，第二步聚合是通过供给丙烯/乙烯混合物进行的，以使乙烯/丙烯反应比为15/85〜79 / 21，由此聚合1至20重量％的总聚合量，第三步聚合通过供应丙烯/乙烯混合物进行，使得乙烯/丙烯反应比为50/50至89/11，从而聚合4〜35重量％的总聚合量，第3步骤中的乙烯/丙烯反应比例大于第2步骤。所述方法可以使丙烯 - 乙烯嵌段共聚物在冲击强度，刚度，透明度和冲击冲刷中显着地平衡。

4. 发明授权

US4820775A Alpha-olefin block copolymer particles and process for the production thereof 失效
标题翻译： α-烯烃嵌段共聚物颗粒及其制备方法
公开(公告)号：US4820775A
公开(公告)日：1989-04-11
申请号：US866369
申请日：1986-05-23
申请人： Akinobu Shiga , Masahiro Kakugo , Hajime Sadatoshi , Hiroyuki Kora , Toshio Sasaki , Junpei Kojima , Kazuki Wakamatsu , Syozo Kawamata
发明人： Akinobu Shiga , Masahiro Kakugo , Hajime Sadatoshi , Hiroyuki Kora , Toshio Sasaki , Junpei Kojima , Kazuki Wakamatsu , Syozo Kawamata
IPC分类号： C08F297/00 , C08F4/16 , C08F4/52 , C08F297/08
CPC分类号： C08F297/083
摘要： A process for the production of .alpha.-olefin block copolymer particles having excellent impact resistance at low temperature and excellent molding and processing characteristics, is disclosed. The process includes a two step gas phase polymerization procedure under specific conditions in the presence of a specific catalyst system.
摘要翻译：公开了一种在低温下具有优异的耐冲击性和优异的成型加工特性的α-烯烃嵌段共聚物颗粒的制备方法。该方法包括在特定催化剂体系存在下的特定条件下的两步气相聚合方法。

5. 发明授权

US4337326A Process for producing propylene-ethylene block copolymers 失效
标题翻译：制备丙烯 - 乙烯嵌段共聚物的方法
公开(公告)号：US4337326A
公开(公告)日：1982-06-29
申请号：US194954
申请日：1980-10-08
申请人： Akinobu Shiga , Masahiro Kakugo , Hajime Sadatoshi , Kazuki Wakamatsu , Hiroshi Yoshioka
发明人： Akinobu Shiga , Masahiro Kakugo , Hajime Sadatoshi , Kazuki Wakamatsu , Hiroshi Yoshioka
IPC分类号： C08F2/00 , C08F297/00 , C08F297/08
CPC分类号： C08F297/086
摘要： A process for producing a propylene-ethylene block copolymer by subjecting propylene and ethylene to three-step polymerization using a stereoregular polymerization catalyst, which comprises in the first step polymerizing propylene alone or a propylene/ethylene mixture so that the average ethylene/propylene reaction ratio is 6/94 or less, thereby polymerizing 60 to 95% by weight of the total polymerization amount, in the second step polymerizing a propylene/ethylene mixture so that the average ethylene/propylene reaction ratio is 25/75 to 67/33, thereby polymerizing 1 to 20% by weight of the total polymerization amount, and in the third step polymerizing a propylene/ethylene mixture so that the average ethylene/propylene reaction ratio is 76/24 to 89/11, thereby polymerizing 4 to 35% by weight of the total polymerization amount, wherein in the second and third steps, ethylene alone is supplied thereby gradually decreasing the amount of propylene in the polymerization system from the first step to the succeeding steps.
摘要翻译：丙烯 - 乙烯嵌段共聚物的制备方法是使用立体规则聚合催化剂对丙烯和乙烯进行三步聚合，其中包括在第一步中聚合单独的丙烯或丙烯/乙烯混合物，使得平均乙烯/丙烯反应比为6/94以下，由此聚合60〜95重量％的总聚合量，在丙烯/乙烯混合物的聚合中，平均乙烯/丙烯的反应比为25/75〜67/33，聚合1至20重量％的总聚合量，并且在第三步中聚合丙烯/乙烯混合物使得平均乙烯/丙烯反应比为76/24至89/11，从而聚合4至35重量％的总聚合量，其中在第二和第三步骤中，仅供应乙烯，从而逐渐降低聚合体系中丙烯的量迈向后续步骤。

6. 发明授权

US4414373A Propylene-ethylene copolymer having improved stretchability 失效
标题翻译：具有改善的拉伸性的丙烯 - 乙烯共聚物
公开(公告)号：US4414373A
公开(公告)日：1983-11-08
申请号：US399146
申请日：1982-07-16
申请人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Yukio Naito , Seiichiro Ima , Katsuyoshi Yamashita
发明人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Yukio Naito , Seiichiro Ima , Katsuyoshi Yamashita
IPC分类号： C08F4/00 , C08F2/00 , C08F4/60 , C08F4/64 , C08F10/00 , C08F10/06 , C08F210/00 , C08F210/06 , C08F210/16
CPC分类号： C08F210/06
摘要： In a process for producing polypropylene comprising polymerizing propylene in the presence of hydrogen and a catalyst system comprising (A) titanium trichloride obtained by reducing titanium tetrachloride with an organoaluminum compound and reacting the reduced solid with an ether represented by the formula:R.sup.1 --O--R.sup.2wherein R.sup.1 and R.sup.2 are defined hereinbefore, and a halogen compound selected from the group consisting of (i) halogen or interhalogen compounds of the formula, X.sup.1 X.sup.2.sub.a (wherein X.sup.1, X.sup.2 and a are defined hereinbefore), (ii) titanium halides, and (iii) organic halogen compounds, simultaneously or successively and (B) an organoaluminum compound, the improvement which comprises supplying ethylene together with propylene to the polymerization system such that the ethylene concentration in the vapor phase of the system based on the total amount of propylene, ethylene and hydrogen in the vapor phase of the system is 0.15 to 1.5 mol % to obtain a propylene-ethylene copolymer having an ethylene content of from 0.1 to 1.0 wt % is disclosed. The propylene-ethylene copolymer is improved in stretchability.
摘要翻译：在制备聚丙烯的方法中，包括在氢气存在下聚合丙烯和催化剂体系，所述催化剂体系包含（A）通过用有机铝化合物还原四氯化钛获得的三氯化钛，并将还原的固体与由下式表示的醚反应：R1-O- 其中R 1和R 2如上定义，卤素化合物选自（ⅰ）卤素或下式的卤代化合物：X1X2a（其中X1，X2和a定义如前），（ⅱ）卤化钛和（iii）有机卤素化合物，同时或相继和（B）有机铝化合物，其改进包括将乙烯与丙烯一起供应到聚合体系中，使得基于丙烯总量的体系的气相中的乙烯浓度，系统的气相中的乙烯和氢为0.15〜1.5摩尔％，得到丙烯 - 乙烯共聚物公开了乙烯含量为0.1〜1.0重量％。丙烯 - 乙烯共聚物的拉伸性提高。

7. 发明授权

US4696979A Process for producing propylene copolymer 失效
标题翻译：制备丙烯共聚物的方法
公开(公告)号：US4696979A
公开(公告)日：1987-09-29
申请号：US686864
申请日：1984-12-27
申请人： Akinobu Shiga , Masahiro Kakugo , Junpei Kozima , Kizuku Wakatsuki
发明人： Akinobu Shiga , Masahiro Kakugo , Junpei Kozima , Kizuku Wakatsuki
IPC分类号： C08L23/10 , C08L23/20 , C08L53/00 , C08L23/14
CPC分类号： C08L23/10 , C08L53/00 , C08L23/20
摘要： A process for producing a propylene copolymer having improved transparency and rigidity, which comprises carrying out (A) the polymerization of a vinyl cycloalkane having at least 6 carbon atoms and (B) the polymerization of propylene either alone or with ethylene in a multiplicity of steps in the presence of a catalyst system composed of a titanium compound and an organoaluminum compound. The content of the vinyl cycloalkane unit in the resulting copolymer is 0.05 to 10,000 weight ppm.
摘要翻译：一种制备具有改善的透明度和刚性的丙烯共聚物的方法，其包括进行（A）聚合具有至少6个碳原子的乙烯基环烷烃和（B）单独或与乙烯在多个步骤中聚合丙烯在由钛化合物和有机铝化合物组成的催化剂体系的存在下。所得共聚物中乙烯基环烷烃单元的含量为0.05至10,000重量ppm。

8. 发明授权

US4367322A Process for producing propylene copolymer 失效
标题翻译：制备丙烯共聚物的方法
公开(公告)号：US4367322A
公开(公告)日：1983-01-04
申请号：US291701
申请日：1981-08-10
申请人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Yukio Naito , Akira Nunose , Masaharu Nishioka
发明人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Yukio Naito , Akira Nunose , Masaharu Nishioka
IPC分类号： C08F4/64 , C08F210/06
CPC分类号： C08F210/06 , Y10S526/916
摘要： In a process for producing propylene copolymer containing about 80 to 99 mol % propylene and about 1 to 20 mol % ethylene and/or an .alpha.-olefin having 4 to 18 carbon atoms using a Ziegler-Natta catalyst, the improvement which comprises said Ziegler-Natta catalyst comprising:(A) titanium trichloride prepared by reducing titanium tetrachloride with an organoaluminum compound and activating the product; and(B) an organoaluminum compound;with the molar ratio of (B)/(A) being about 20 to 100.
摘要翻译：在使用齐格勒 - 纳塔催化剂的丙烯共聚物的制备方法中，所述丙烯共聚物含有约80-99摩尔％的丙烯和约1-20摩尔％的乙烯和/或具有4-18个碳原子的α-烯烃，其改进包括所述齐格勒 - 纳塔催化剂，其包含：（A）通过用有机铝化合物还原四氯化钛制备的三氯化钛并活化该产物; 和（B）有机铝化合物; （B）/（A）的摩尔比为约20至100。

9. 发明授权

US4355144A Process for producing a propylene-ethylene copolymer having improved stretchability 失效
标题翻译：制备具有改善的拉伸性的丙烯 - 乙烯共聚物的方法
公开(公告)号：US4355144A
公开(公告)日：1982-10-19
申请号：US257431
申请日：1981-04-24
申请人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Yukio Naito , Seiichiro Ima , Katsuyoshi Yamashita
发明人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Yukio Naito , Seiichiro Ima , Katsuyoshi Yamashita
IPC分类号： C08F4/00 , C08F2/00 , C08F4/60 , C08F4/64 , C08F10/00 , C08F10/06 , C08F210/00 , C08F210/06 , C08F210/16
CPC分类号： C08F210/06
摘要： In a process for producing polypropylene comprising polymerizing propylene in the presence of hydrogen and a catalyst system comprising (A) titanium trichloride obtained by reducing titanium tetrachloride with an organoaluminum compound and reacting the reduced solid with an ether represented by the formula:R.sup.1 -O-R.sup.2wherein R.sup.1 and R.sup.2 are defined hereinbefore, and a halogen compound selected from the group consisting of (i) halogen or interhalogen compounds of the formula, X.sup.1 X.sup.2.sub.a (wherein X.sup.1, X.sup.2 and a are defined hereinbefore), (ii) titanium halides, and (iii) organic halogen compounds, simultaneously or successively and (B) an organoaluminum compound, the improvement which comprises supplying ethylene together with propylene to the polymerization system such that the ethylene concentration in the vapor phase of the system based on the total amount of propylene, ethylene and hydrogen in the vapor phase of the system is 0.15 to 1.5 mol % to obtain a propylene-ethylene copolymer having an ethylene content of from 0.1 to 1.0 wt % is disclosed. The propylene-ethylene copolymer is improved in stretchability.
摘要翻译：在制备聚丙烯的方法中，包括在氢气存在下聚合丙烯和催化剂体系，所述催化剂体系包含（A）通过用有机铝化合物还原四氯化钛获得的三氯化钛，并将还原的固体与由下式表示的醚反应：R1-O- 其中R 1和R 2如上定义，卤素化合物选自（ⅰ）卤素或下式的卤代化合物：X1X2a（其中X1，X2和a定义如前），（ⅱ）卤化钛和（iii）有机卤素化合物，同时或相继和（B）有机铝化合物，其改进包括将乙烯与丙烯一起供应到聚合体系中，使得基于丙烯总量的体系的气相中的乙烯浓度，系统的气相中的乙烯和氢为0.15〜1.5摩尔％，得到丙烯 - 乙烯共聚物公开了乙烯含量为0.1〜1.0重量％。丙烯 - 乙烯共聚物的拉伸性提高。

10. 发明授权

US4195145A Process for the purification of highly crystalline polyolefins 失效
标题翻译：纯化高结晶性聚烯烃的方法
公开(公告)号：US4195145A
公开(公告)日：1980-03-25
申请号：US959806
申请日：1978-11-13
申请人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Takatoshi Suzuki
发明人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Takatoshi Suzuki
IPC分类号： C08F6/00 , C08F6/02 , C08F6/06 , C08F6/26 , C08F6/28
CPC分类号： C08F6/26 , C08F6/02
摘要： A process for purifying propylene homopolymers or copolymers which comprises:(i) polymerizing or copolymerizing propylene with other unsaturated hydrocarbon monomers in liquid propylene in the presence of a catalyst system consisting essentially of (a) an activated titanium trichloride obtained by reducing titanium tetrachloride with an organo-aluminum compound followed by activation and (b) an organo-aluminum compound;(ii) introducing the resulting polymer slurry into an upper portion of a counter-current washing tower to counter-currently contact the polymer slurry with a C.sub.3 -C.sub.8 alcohol and liquid propylene, whereby said catalyst is deactivated and at the same time the propylene homopolymers or copolymers dissolved in the polymer slurry and the catalyst are removed by washing, wherein said alcohol is used in an amount 0.1 to 50 times by mole based on said organo-aluminum compound (b) and is supplied to the washing tower lower than the point of introduction of said polymer slurry, and said liquid propylene is supplied to a lower portion of the washing tower; and(iii) then after removing volatile monomers by flashing, contacting the powdery propylene homopolymers or copolymers with a gaseous epoxide at a temperature lower than melting point of said polymer or copolymer.
摘要翻译：一种用于纯化丙烯均聚物或共聚物的方法，其包括：（i）在液体丙烯中，在催化剂体系存在下，将丙烯与其它不饱和烃单体聚合或共聚，所述催化剂体系基本上由（a）通过将四氯化钛还原成四氯化钛得到的活化三氯化钛有机铝化合物，然后活化，（b）有机铝化合物; （ii）将所得聚合物浆料引入逆流洗涤塔的上部，以与C3-C8醇和液体丙烯反应地接触聚合物浆料，由此所述催化剂失活，同时丙烯均聚物或溶解在聚合物浆料中的共聚物和催化剂通过洗涤除去，其中所述醇的用量相对于所述有机铝化合物（b）为0.1至50倍摩尔量，并且供应至低于该点的洗涤塔引入所述聚合物浆料，并将所述液态丙烯供应到洗涤塔的下部; 和（iii）然后在通过闪蒸除去挥发性单体之后，在低于所述聚合物或共聚物的熔点的温度下使粉末丙烯均聚物或共聚物与气态环氧化物接触。

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