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1. 发明授权

US4767613A Terpolymers, their use in hair treatment agents and hair treatment agents containing these terpolymers 失效
标题翻译：三元共聚物，它们在毛发处理剂中的应用和含有这些三元共聚物的毛发处理剂
公开(公告)号：US4767613A
公开(公告)日：1988-08-30
申请号：US076874
申请日：1987-07-23
申请人： Adolf Nuber , Axel Sanner , Ferdinand Straub , Friedrich Vogel
发明人： Adolf Nuber , Axel Sanner , Ferdinand Straub , Friedrich Vogel
IPC分类号： A61K8/00 , A61K8/31 , A61K8/34 , A61K8/35 , A61K8/36 , A61K8/41 , A61K8/81 , A61Q5/06 , C08F8/44 , C08F26/10 , C08F220/04 , C08F220/06 , C08F220/10 , C08F220/12 , C08F220/18 , C08F226/10 , B05D3/14 , C08F26/08
CPC分类号： C08F226/10 , A61K8/8182 , A61Q5/06 , C08F220/18 , Y10S424/01
摘要： A terpolymer of vinylpyrolidone, tert-butyl (meth)acrylate and acrylic or methacrylic acid, its use in hair treatment agents, and hair cosmetics compositions which contain these agents.
摘要翻译：乙烯基吡咯烷酮，（甲基）丙烯酸叔丁酯和丙烯酸或甲基丙烯酸的三元共聚物，其在毛发处理剂中的用途，以及含有这些试剂的头发化妆品组合物。

2. 发明授权

US4748989A Copolymers, use thereof as hair fixatives and hair fixatives containing same 失效
标题翻译：共聚物，其用作头发固定剂和含有它们的固定剂
公开(公告)号：US4748989A
公开(公告)日：1988-06-07
申请号：US79944
申请日：1987-07-31
申请人： Adolf Nuber , Axel Sanner , Friedrich Vogel , Dietrich Mass
发明人： Adolf Nuber , Axel Sanner , Friedrich Vogel , Dietrich Mass
IPC分类号： A61K8/00 , A61K8/34 , A61K8/41 , A61K8/81 , A61Q5/06 , C08F20/26 , C08F26/10 , C08F220/00 , C08F220/04 , C08F220/06 , C08F220/10 , C08F220/12 , C08F220/26 , C08F220/28 , C08F220/54 , C08F220/56 , C08F226/10 , A45D7/00
CPC分类号： C08F226/10 , A61K8/8182 , A61Q5/06 , C08F220/54
摘要： Copolymers of vinylpyrrolidone, acrylamides which are monoalkylated or dialkylated on the N atom and alkyl or hydroxyalkyl esters of (meth)acrylic acid, with or without (meth)acrylic acid, or (meth)acrylic acid are used as and in hair fixatives.
摘要翻译：乙烯基吡咯烷酮，在N原子上单烷基化或二烷基化的丙烯酰胺和（甲基）丙烯酸的烷基或羟烷基酯与（甲基）丙烯酸或（甲基）丙烯酸的共聚物用作和固定剂。

3. 发明授权

US4841066A Preparation of 3-methyl-1-vinylimidazolium chlorides 失效
标题翻译： 3-甲基-1-乙烯基咪唑氯化物的制备
公开(公告)号：US4841066A
公开(公告)日：1989-06-20
申请号：US49314
申请日：1987-05-13
申请人： Hans-Helmut Goertz , Ferdinand Straub , Axel Sanner , Albrecht Kolb , Hans-Juergen Raubenheimer , Friedrich Vogel
发明人： Hans-Helmut Goertz , Ferdinand Straub , Axel Sanner , Albrecht Kolb , Hans-Juergen Raubenheimer , Friedrich Vogel
IPC分类号： C07D233/58 , C07D521/00 , C08F26/00 , C08F26/06
CPC分类号： C07D231/12 , C07D233/56 , C07D249/08 , C08F26/06
摘要： 3-Methyl-1-vinylimidazolium chlorides are prepared by quaternizing N-vinylimidazoles in aqueous solution with methyl chloride and are used for the preparation of water-soluble homo- or copolymers.
摘要翻译： 3-甲基-1-乙烯基咪唑鎓氯化物通过用甲基氯季铵化N-乙烯基咪唑在水溶液中制备，并用于制备水溶性均聚物或共聚物。

4. 发明授权

US4789713A Preparation of terpolymers 失效
标题翻译：三元共聚物的制备
公开(公告)号：US4789713A
公开(公告)日：1988-12-06
申请号：US91847
申请日：1987-09-01
申请人： Axel Sanner , Friedrich Vogel
发明人： Axel Sanner , Friedrich Vogel
IPC分类号： C08F2/18 , C08F2/00 , C08F2/20 , C08F2/38 , C08F6/00 , C08F20/52 , C08F220/04 , C08F220/06 , C08F220/10 , C08F220/12 , C08F220/54 , C08F220/56
CPC分类号： C08F220/54 , C08F6/003
摘要： A terpolymer of acrylic acid, ethyl acrylate and N-tert-butylacrylamide is prepared by suspension polymerization.
摘要翻译：通过悬浮聚合制备丙烯酸，丙烯酸乙酯和N-叔丁基丙烯酰胺的三元共聚物。

5. 发明授权

US4908413A Preparation of copolymers of monoalkyl maleates and vinyl alkyl ethers 失效
标题翻译：制备马来酸单烷基酯和乙烯基烷基醚的共聚物
公开(公告)号：US4908413A
公开(公告)日：1990-03-13
申请号：US251754
申请日：1988-10-03
申请人： Hans-Helmut Goertz , Ferdinand Straub , Friedrich Vogel , Franz Frosch , Paul Naegele , Hans-Juergen Raubenheimer
发明人： Hans-Helmut Goertz , Ferdinand Straub , Friedrich Vogel , Franz Frosch , Paul Naegele , Hans-Juergen Raubenheimer
IPC分类号： C08F2/06 , C08F4/04 , C08F8/14 , C08F222/16
CPC分类号： C08F222/16 , C08F8/14
摘要： Copolymers of monoalkyl maleates and vinyl alkyl ethers are prepared by free radical copolymerization of maleic anhydride and a vinyl alkyl ether followed by reaction with an alkanol, by a process in which the vinyl alkyl ether component is present in excess in the reaction mixture in each phase of the polymerization, the free radical copolymerization is carried out in acetone and the acetone is removed by distillation during or after ester formation at up to 70.degree. C.
摘要翻译：单烷基马来酸酯和乙烯基烷基醚的共聚物是通过马来酸酐和乙烯基烷基醚的自由基共聚反应制备的，随后与链烷醇反应，其中乙烯基烷基醚组分在每相中的反应混合物中过量存在的聚合反应中，自由基共聚在丙酮中进行，在高达70℃的酯形成过程中或之后通过蒸馏除去丙酮。

6. 发明授权

US4659837A Method for the preparation of 1,3-disubstituted 4,5-cis-dicarboxy-2-imidazolidones 失效
标题翻译：制备1,3-二取代的4,5-顺 - 二羧基-2-咪唑啉酮的方法
公开(公告)号：US4659837A
公开(公告)日：1987-04-21
申请号：US450286
申请日：1982-12-16
申请人： Walter Trautmann , Friedrich Vogel
发明人： Walter Trautmann , Friedrich Vogel
IPC分类号： C07D233/32
CPC分类号： C07D233/32
摘要： A process for the preparation of 1,3-disubstituted 4,5-cis-dicarboxy-2-imidazolidones useful as intermediates in the preparation of Vitamin H (biotin), said intermediates have the general formula ##STR1## in which R is an aliphatic hydrocarbon radical having 1 to 8 carbon atoms, an aralkyl radical or an aromatic hydrocarbon radical, preferably an allyl radical or a benzyl radical, comprising reacting a defined diaminosuccinic acid with phosgene in the presence of an alkali metal hydroxide.
摘要翻译：用作制备维生素H（生物素）的中间体的1,3-二取代的4,5-顺 - 二羧基-2-咪唑烷酮的制备方法，所述中间体具有通式“IMAGE”，其中R是脂族包括具有1-8个碳原子的烃基，芳烷基或芳族烃基，优选烯丙基或苄基，包括在碱金属氢氧化物存在下使限定的二氨基琥珀酸与光气反应。

7. 发明授权

US4859756A Polymers of oxyalkylated unsaturated quaternary ammonium salts, their preparation and their use 失效
标题翻译：烷氧基化不饱和季铵盐的聚合物及其制备及其应用
公开(公告)号：US4859756A
公开(公告)日：1989-08-22
申请号：US226198
申请日：1988-07-29
申请人： Hans-Helmut Goertz , Alfred Oftring , Friedrich Vogel
发明人： Hans-Helmut Goertz , Alfred Oftring , Friedrich Vogel
IPC分类号： B01D21/01 , A61K8/72 , A61K8/81 , A61Q5/12 , C02F1/54 , C07C51/58 , C07D233/60 , C08F20/36 , C08F20/52 , C08F20/60 , C08F26/00 , C08F26/02 , C08F120/36 , C08F120/60 , C08F126/02 , H01B1/12
CPC分类号： C02F1/54 , A61K8/8152 , A61K8/817 , A61Q5/12 , C07C51/58 , C08F20/36 , C08F20/60 , C08F26/02 , H01B1/122 , A61K2800/526 , A61K2800/5426
摘要： Polymers are obtained by polymerization of water-soluble monomers which contain one or more polymerizable olefinic double bonds and a quaternary nitrogen atom which is substituted by one or more hydroxyalkyl groups and are present in the form of halide-free salts, with or without further comonomers.
摘要翻译：聚合物通过含有一个或多个可聚合烯属双键的水溶性单体和被一个或多个羟烷基取代的季氮原子聚合而获得，并且以无卤盐形式存在，具有或不含有其它共聚单体。

8. 发明授权

US4595783A Magnesium chloride or phosphonium halide derivatives of 3,7,11-trimethyl-dodeca-2,6(10)-diene(triene)-1-ol 失效
标题翻译： 3,7,11-三甲基 - 十二烷-2,6（10） - 二烯（三烯）-1-醇的氯化镁或卤化鏻衍生物
公开(公告)号：US4595783A
公开(公告)日：1986-06-17
申请号：US646271
申请日：1984-08-31
申请人： Friedrich Vogel , Joachim Paust , Axel Nuerrenbach
发明人： Friedrich Vogel , Joachim Paust , Axel Nuerrenbach
IPC分类号： C07C17/16 , C07D311/72 , C07F3/02 , C07F9/143 , C07F9/54
CPC分类号： C07F9/5428 , C07C17/16 , C07D311/72 , C07F3/02 , C07F9/143
摘要： The invention relates to intermediate compounds having the general formula I ##STR1## in which R.sup.1 is H, an alkyl, arylalkyl or an aliphatic acyl radical, preferably a benzyl or acetyl group and wherein X and Y together span an additional bond between the X and Y carrying C atoms (Ia) or in which Y is OH and X is H (Ib) and in which the dotted line can represent an additional bond particularly[2R,1'Z,3'E,7'E]-6-benzyloxy-2,5,7,8-tetramethyl-2-(4',8',12'-trimethyl-trideca-1',3',7'-trien-1'-yl)chroman and6-benzyloxy-2,5,7,8-tetramethyl-2-(1'-hydroxy-4',8',12'-trimethyl-trideca-3',7'-diene-1'-yl)chroman, as well as compounds and methods of preparing compounds having the general formula II ##STR2## in which Z is one of the groups ##STR3## wherein R.sup.2 is an alkyl group with 1 to 4 carbon atoms preferably CH.sub.3 or C.sub.2 H.sub.5particularly (3,7,11-trimethyl-trideca-2,6,10-trien-1-yl)triphenylphosphonium chloride and (3,7,11-trimethyl-trideca-2,6,10-trien-1-yl) phosphoric acid dimethylester as well as methods for the preparation of (2R,4'RS,8'Rs)-.alpha.-tocopherol and (all-rac)-.alpha.-tocopherol via the new intermediate product.
摘要翻译：本发明涉及具有通式I（I）的中间体化合物，其中R 1为H，烷基，芳烷基或脂族酰基，优选苄基或乙酰基，并且其中X和Y一起跨越 X和Y携带C原子（Ia）或其中Y是OH，X是H（Ib），其中虚线可以代表额外的键，特别是[2R，1'Z，3'E，7'E] -6-苄氧基-2,5,7,8-四甲基-2-（4'，8'，12'-三甲基十三碳烯-1'，3'，7'-三烯-1'-基）苯并二氢吡喃酮和 6-苄氧基-2,5,7,8-四甲基-2-（1'-羟基-4'，8'，12'-三甲基 - 三环-10a-3'，7'-二烯-1'-基）苯并二氢吡喃，以及制备具有通式II（II）的化合物的化合物和方法，其中Z是组ClMg之一; BrMg; （IIa）（IIc）（IIc）其中R2是具有1至4个碳原子的烷基，优选为CH3或C2H5（3,7,11-三甲基 - 十三烷-2,6,10-三烯（3,7,11-三甲基 - 十三碳-2,6,10-三烯-1-基）磷酸二甲酯以及制备（2R，4'RS，8 'Rs） - α-生育酚和（全消旋） - α-生育酚通过新的中间产物。

9. 发明授权

US4515975A Chroman derivatives and their preparation 失效
标题翻译：色原衍生物及其制备
公开(公告)号：US4515975A
公开(公告)日：1985-05-07
申请号：US439625
申请日：1982-11-04
申请人： Friedrich Vogel , Joachim Paust
发明人： Friedrich Vogel , Joachim Paust
IPC分类号： C07D311/22 , C07D311/58 , C07D311/70 , C07D311/72
CPC分类号： C07D311/58 , C07D311/22 , C07D311/70 , Y02P20/55
摘要： Chroman derivatives of the general formula I ##STR1## where A--B is --CH.sub.2 --CH.sub.2 --(Ia), --CH.dbd.CH--(Ib), --CHOH--CH.sub.2 --(Ic) or --CO--CH.sub.2 --(Id), R.sup.1 is --CH.sub.2 --O--R' or ##STR2## where R' is C.sub.1 -C.sub.4 -alkyl or arylmethyl and R" and R'" are each C.sub.1 -C.sub.4 -alkyl, which can also be bonded to form a five-membered or six-membered cyclic acetal, R.sup.2 is C.sub.1 -C.sub.4 -alkyl and R.sup.3 is H or a protective group.
摘要翻译：其中AB是-CH 2 -CH 2 - （Ia），-CH = CH-（Ib），-CHOH-CH 2 - （Ic）或-CO-CH 2 - （Id）的通式I的色原衍生物 R 1是-CH 2 -OR'或其中R'是C 1 -C 4 - 烷基或芳基甲基，R“和R”'各自是C 1 -C 4 - 烷基，其也可键合形成五元或六元环缩醛，R2为C1-C4-烷基，R3为H或保护基。

10. 发明授权

US10675177B2 Cooling mat comprising expandable elements for cooling a body or body part for medical or performance-enhancing purposes (COOL APP) 有权
公开(公告)号：US10675177B2
公开(公告)日：2020-06-09
申请号：US15115817
申请日：2015-01-26
申请人： Friedrich Vogel , Jakob Vogel , Rudolf Faworka
发明人： Friedrich Vogel , Jakob Vogel , Rudolf Faworka
IPC分类号： A61F7/10 , F25D3/08 , A61F7/00
摘要： Disclosed is a device for cooling a body or body part for medical or performance-enhancing purposes, said device consisting of one or more cooling elements (11), said cooling element (11) being provided with a cover (1) that is filled with meltable cooling solid (2). The disclosed device is characterized in that an additional apparatus for displacing the already melted portion (8) of the cooling solid (2) from the contact surface (7) to the body is provided inside the cover (1), the expandable member (4, 6) being preferably designed in the form of a filled member (4) of a spring element (6) or of a foamed article. Also disclosed is an additional device which is characterized in that a layer (16) of thermochromic material indicates when a threshold temperature is exceeded, said layer (16) being applied to the bottom side of the expandable member and thus being pressed against the remaining solid portion of the cooling solid, the cover (1) being transparent in this case.

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