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1. 发明授权

US4767613A Terpolymers, their use in hair treatment agents and hair treatment agents containing these terpolymers 失效
标题翻译：三元共聚物，它们在毛发处理剂中的应用和含有这些三元共聚物的毛发处理剂
公开(公告)号：US4767613A
公开(公告)日：1988-08-30
申请号：US076874
申请日：1987-07-23
申请人： Adolf Nuber , Axel Sanner , Ferdinand Straub , Friedrich Vogel
发明人： Adolf Nuber , Axel Sanner , Ferdinand Straub , Friedrich Vogel
IPC分类号： A61K8/00 , A61K8/31 , A61K8/34 , A61K8/35 , A61K8/36 , A61K8/41 , A61K8/81 , A61Q5/06 , C08F8/44 , C08F26/10 , C08F220/04 , C08F220/06 , C08F220/10 , C08F220/12 , C08F220/18 , C08F226/10 , B05D3/14 , C08F26/08
CPC分类号： C08F226/10 , A61K8/8182 , A61Q5/06 , C08F220/18 , Y10S424/01
摘要： A terpolymer of vinylpyrolidone, tert-butyl (meth)acrylate and acrylic or methacrylic acid, its use in hair treatment agents, and hair cosmetics compositions which contain these agents.
摘要翻译：乙烯基吡咯烷酮，（甲基）丙烯酸叔丁酯和丙烯酸或甲基丙烯酸的三元共聚物，其在毛发处理剂中的用途，以及含有这些试剂的头发化妆品组合物。

2. 发明授权

US4748989A Copolymers, use thereof as hair fixatives and hair fixatives containing same 失效
标题翻译：共聚物，其用作头发固定剂和含有它们的固定剂
公开(公告)号：US4748989A
公开(公告)日：1988-06-07
申请号：US79944
申请日：1987-07-31
申请人： Adolf Nuber , Axel Sanner , Friedrich Vogel , Dietrich Mass
发明人： Adolf Nuber , Axel Sanner , Friedrich Vogel , Dietrich Mass
IPC分类号： A61K8/00 , A61K8/34 , A61K8/41 , A61K8/81 , A61Q5/06 , C08F20/26 , C08F26/10 , C08F220/00 , C08F220/04 , C08F220/06 , C08F220/10 , C08F220/12 , C08F220/26 , C08F220/28 , C08F220/54 , C08F220/56 , C08F226/10 , A45D7/00
CPC分类号： C08F226/10 , A61K8/8182 , A61Q5/06 , C08F220/54
摘要： Copolymers of vinylpyrrolidone, acrylamides which are monoalkylated or dialkylated on the N atom and alkyl or hydroxyalkyl esters of (meth)acrylic acid, with or without (meth)acrylic acid, or (meth)acrylic acid are used as and in hair fixatives.
摘要翻译：乙烯基吡咯烷酮，在N原子上单烷基化或二烷基化的丙烯酰胺和（甲基）丙烯酸的烷基或羟烷基酯与（甲基）丙烯酸或（甲基）丙烯酸的共聚物用作和固定剂。

3. 发明授权

US4795802A Removal of vinylpyrrolidone from vinylpyrrolidone polymers 失效
标题翻译：从乙烯基吡咯烷酮聚合物中除去乙烯基吡咯烷酮
公开(公告)号：US4795802A
公开(公告)日：1989-01-03
申请号：US82140
申请日：1987-08-06
申请人： Adolf Nuber , Axel Sanner , Dieter Urban
发明人： Adolf Nuber , Axel Sanner , Dieter Urban
IPC分类号： B01D15/00 , C08F6/00 , C08F6/10 , C08F26/10
CPC分类号： C08F6/003
摘要： Vinylpyrrolidone is removed from its polymers by a process in which an aqueous or alcoholic solution of the polymer is treated with an adsorbent, the adsorbents used preferably being active carbon, zeolites and especially acidic ion exchangers.
摘要翻译：通过其中聚合物的水溶液或醇溶液用吸附剂处理的方法从其聚合物中除去乙烯基吡咯烷酮，吸附剂优选用作活性炭，沸石，特别是酸性离子交换剂。

4. 发明授权

US5122582A Preparation of copolymers which form clear aqueous solutions 失效
标题翻译：形成清晰的水溶液的共聚物的制备
公开(公告)号：US5122582A
公开(公告)日：1992-06-16
申请号：US586153
申请日：1990-09-21
申请人： Birgit Potthoff-Karl , Adolf Nuber , Willy Hinz , Axel Sanner
发明人： Birgit Potthoff-Karl , Adolf Nuber , Willy Hinz , Axel Sanner
IPC分类号： C08F6/10 , C08F2/04 , C08F2/10 , C08F6/00 , C08F26/10 , C08F218/02 , C08F218/04 , C08F226/10
CPC分类号： C08F226/10 , C08F218/04 , C08F6/003
摘要： The preparation of copolymers which form clear aqueous solutions fromA) 45 to 90% by weight N-vinylpyrrolidone,B) 10 to 55% by weight of a vinyl ester andC) 0 to 10% by weight of other copolymerizable monomersby radical polymerization in an organic solvent in the presence of a radical initiator, and removal of the organic solvent and other volatiles by distillation, entails allowing the polymerization to proceed until the N-vinylpyrrolidone content in the reaction mixture is from 5 to 1% by weight of the N-vinylpyrrolidone amount employed, substantially removing the organic solvent and other volatiles by distillation, adding water to the mixture, again adding a radical initiator and leaving the aqueous solution at from 50.degree. to 100.degree. C. for from 1 to 10 hours, and then removing volatile organic constituents virtually completely by a steam distillation.
摘要翻译：制备由A）45-90％（重量）N-乙烯基吡咯烷酮形成透明水溶液的共聚物，B）10-55％（重量）乙烯基酯和C）0-10％（重量）其它可共聚单体通过自由基聚合在有机溶剂中，在自由基引发剂的存在下，通过蒸馏除去有机溶剂和其它挥发物，需要进行聚合，直到反应混合物中的N-乙烯基吡咯烷酮含量为重量的5〜1％所用的N-乙烯基吡咯烷酮用量，通过蒸馏基本上除去有机溶剂和其它挥发物，向混合物中加入水，再加入自由基引发剂，并将水溶液在50至100℃下离心1至10小时; 然后通过蒸汽蒸馏实质上完全去除挥发性有机成分。

5. 发明授权

US4786699A Preparation of polyvinylpyrrolidone 失效
标题翻译：聚乙烯吡咯烷酮的制备
公开(公告)号：US4786699A
公开(公告)日：1988-11-22
申请号：US144744
申请日：1988-01-19
申请人： Adolf Nuber , Siegfried Lang , Axel Sanner , Gerd Schroeder
发明人： Adolf Nuber , Siegfried Lang , Axel Sanner , Gerd Schroeder
IPC分类号： C08F4/00 , C08F4/28 , C08F4/34 , C08F26/00 , C08F26/10 , C08F20/44
CPC分类号： C08F26/10
摘要： Polyvinylpyrrolidone having a Fikentscher K value of from 14 to 95 is prepared at from 50.degree. to 95.degree. C. in aqueous solution with hydrogen peroxide as starter, the solution being maintained at pH 7-11 by means of NaOH, KOH, their carbonates or bicarbonates.
摘要翻译：具有14至95的Fikentscher K值的聚乙烯吡咯烷酮在50℃至95℃的水溶液中以过氧化氢作为起始剂制备，溶液通过NaOH，KOH，其碳酸盐或碳酸氢盐

6. 发明授权

US4816534A Preparation of vinylpyrrolidone polymers 失效
标题翻译：乙烯基吡咯烷酮聚合物的制备
公开(公告)号：US4816534A
公开(公告)日：1989-03-28
申请号：US132036
申请日：1987-12-14
申请人： Adolf Nuber , Walter Denzinger , Axel Sanner
发明人： Adolf Nuber , Walter Denzinger , Axel Sanner
IPC分类号： C08F2/10 , C08F2/38 , C08F4/28 , C08F4/34 , C08F26/10
CPC分类号： C08F26/10
摘要： Hydrazine-free vinlypyrrolidone polymers which dissolve in water and organic solvents to give a clear solution are prepared by polymerization using di-tert-butyl peroxide in an aqueous medium.
摘要翻译：通过在水性介质中使用二叔丁基过氧化物进行聚合，制备溶于水和有机溶剂得到澄清溶液的无肼无溶剂吡咯烷酮聚合物。

7. 发明授权

US5496591A Radiation-curable binders 失效
标题翻译：可辐射固化的粘合剂
公开(公告)号：US5496591A
公开(公告)日：1996-03-05
申请号：US239860
申请日：1994-05-09
申请人： Reinhard Lang , Erich Beck , Edmund Keil , Adolf Nuber , Harro Petersen , Hans Renz , Horst Schmidt , Wolfram Weiss
发明人： Reinhard Lang , Erich Beck , Edmund Keil , Adolf Nuber , Harro Petersen , Hans Renz , Horst Schmidt , Wolfram Weiss
IPC分类号： C08F299/02 , C08F290/00 , C08F290/14 , C08G12/40 , C08G12/42 , C08G14/12 , C09D161/34 , C08J7/04
CPC分类号： C08G14/12 , C08F290/14 , C09D161/34
摘要： Radiation-curable binders which are obtained by reactingA) an amine/formaldehyde condensate having a molar ratio of formaldehyde to amino groups of from 1:1 to 2:1 withB) one or more esters, having a free hydroxyl group, of acrylic acid or of methacrylic acid with polyalcohols which contain from two to four alcoholic hydroxyl groups, from 0.1 to 0.3 hydroxyl equivalent of component B) being used per methylol equivalent of component A),in the presence of a strong acid are suitable for use in coating materials.
摘要翻译：通过使A）甲醛与氨基的摩尔比为1：1至2：1的胺/甲醛缩合物与B）一种或多种具有游离羟基的丙烯酸酯反应得到的可辐射固化粘合剂酸或甲基丙烯酸与含有2至4个醇羟基的多元醇，0.1至0.3个羟基当量的组分B）相对于组分A）的羟甲基当量）在强酸存在下使用适用于涂层材料

8. 发明授权

US5602191A Preparation of radiation-curable acrylates that are storage stable with isocyanate crosslinking agents 失效
标题翻译：用异氰酸酯交联剂保存稳定的辐射固化丙烯酸酯的制备
公开(公告)号：US5602191A
公开(公告)日：1997-02-11
申请号：US455621
申请日：1995-05-31
申请人： Wolfgang Reich , Erich Beck , Edmund Keil , Ulrich Erhardt , Adolf Nuber
发明人： Wolfgang Reich , Erich Beck , Edmund Keil , Ulrich Erhardt , Adolf Nuber
IPC分类号： C08F20/26 , C07C67/26 , C07C67/60 , C08F2/46 , C08F2/48 , C08F290/00 , C08F299/02 , C08G59/17 , C08G63/47
CPC分类号： C08G63/47 , C07C67/26 , C07C67/60
摘要： Radiation-curable acrylates are prepared by a process in which the hydroxy compound is reacted with acrylic acid or methacrylic acid in a first stage and, in a second stage, the reaction product of the first stage is reacted with an epoxide compound in the presence of, as a catalyst, a quaternary ammonium or phosphonium compound of the general formula ##STR1## where X.sup.- is an opposite ion and R.sup.1 to R.sup.4 independently of one another are each C.sub.1 -C.sub.18 -alkyl which may be substituted by one or two phenyl groups or are each C.sub.6 -C.sub.12 -aryl which may be substituted by one or two C.sub.1 -C.sub.6 -alkyl groups.
摘要翻译：可辐射固化的丙烯酸酯通过在第一阶段中羟基化合物与丙烯酸或甲基丙烯酸反应的方法制备，并且在第二阶段中，使第一阶段的反应产物与环氧化合物在作为催化剂，通式为“IMAGE”I或“IMAGE”II的季铵或鏻化合物，其中X + E，crc - + EE是相反的离子，R1至R4彼此独立地为C1-C18 - 烷基，其可以被一个或两个苯基取代，或各自可被一个或两个C 1 -C 6 - 烷基取代的C 6 -C 12 - 芳基。

9. 发明授权

US5516860A Preparation of radiation-curable acrylates 失效
标题翻译：辐射固化丙烯酸酯的制备
公开(公告)号：US5516860A
公开(公告)日：1996-05-14
申请号：US432063
申请日：1995-05-01
申请人： Wolfgang Reich , Ulrich Jager , Erich Beck , Edmund Keil , Ulrich Erhardt , Adolf Nuber
发明人： Wolfgang Reich , Ulrich Jager , Erich Beck , Edmund Keil , Ulrich Erhardt , Adolf Nuber
IPC分类号： C08F299/02 , C08F290/00 , C08G59/17 , C08G59/56 , C08G63/58 , C08G63/91 , C08L63/00 , C08F283/00
CPC分类号： C08L63/00 , C08G59/1466 , C08G59/56 , C08G63/58 , C08G63/918 , Y10S525/922
摘要： Radiation-curable acrylates are prepared by a process in which, in a 1st stage, a hydroxy compound is reacted with acrylic acid or methacrylic acid and, in or before a 2nd stage, the reaction product of the 1st stage is then reacted with an epoxy compound and compounds having one or more primary or secondary amino groups are added in the 2nd stage and the reaction in the 2nd stage is continued, after the addition of these compounds, until the acid number of the reaction mixture has decreased by at least 3 mg KOH/g of reaction mixture from the time of the addition of these compounds.
摘要翻译：可辐射固化的丙烯酸酯通过以下方法制备，其中在第一阶段中，羟基化合物与丙烯酸或甲基丙烯酸反应，并且在第二阶段或之前，使第一阶段的反应产物与环氧化合物和具有一个或多个伯或仲氨基的化合物在第二阶段中加入，并且在加入这些化合物之后继续进行第二阶段的反应，直到反应混合物的酸值降低至少3mg 从加入这些化合物时的KOH / g反应混合物。

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