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    • 7. 发明授权
    • Polymer compositions having improved homogeneity and odour, a method for making them and pipes made thereof
    • 具有改进的均匀性和气味的聚合物组合物,制造它们的方法和由其制成的管
    • US08530580B2
    • 2013-09-10
    • US12995978
    • 2009-05-25
    • Mats BäckmanCarl-Gustaf EkAnneli PakkanenMagnus Palmlöf
    • Mats BäckmanCarl-Gustaf EkAnneli PakkanenMagnus Palmlöf
    • C08L23/08C08F4/6592
    • C08L23/06C08L23/0815C08L2205/02Y10T428/139C08L2666/06
    • The present invention deals with polymer compositions suitable for making pipes. The compositions comprise a multimodal copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms wherein the multimodal ethylene copolymer has a density of from 924 to 960 kg/m3, a melt index MFR5 of from 0.5 to 6.0 g/10 min, a melt index MFR2 of from 0.1 to 2.0 g/10 min and a shear thinning index SHI2.7/210 of from 2 to 50. The compositions further have a level of volatile compounds of at most 100 ppm by weight and/or a homogeneity rating of at most 3. In addition the multimodal copolymer comprises: (A) from 35 to 60% by weight, based on the combined amount of components (A) and (B), of a low molecular weight ethylene polymer selected from ethylene homopolymer and a copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms and having a weight average molecular weight of from 5000 to 100000 g/mol and a density of from 945 to 975 kg/m3; and (B) from 40 to 65% by weight, based on the combined amount of components (A) and (B), of a high molecular weight copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms and having a weight average molecular weight of from 100000 to 1000000 g/mol and a density of from 890 to 935 kg/m3.
    • 本发明涉及适于制造管道的聚合物组合物。 组合物包含乙烯和一种或多种具有4至10个碳原子的α-烯烃的多峰共聚物,其中多峰乙烯共聚物的密度为924至960kg / m 3,熔体指数MFR 5为0.5至6.0g / 10分钟,熔体指数MFR 2为0.1至2.0g / 10min,剪切稀化指数SHI2.7 / 210为2至50.组合物还具有至多100重量ppm的挥发性化合物和/ 或均一性等级至多为3.另外,多峰共聚物包含:(A)35至60重量%,基于组分(A)和(B)的组合量,选择低分子量乙烯聚合物 来自乙烯均聚物和乙烯与一种或多种具有4至10个碳原子的α-烯烃的共聚物,其重均分子量为5000至100000g / mol,密度为945至975kg / m 3; 和(B)40至65重量%,基于组分(A)和(B)的组合量,乙烯和一种或多种具有4至10个碳原子的α-烯烃的高分子量共聚物和 重均分子量为100000〜1000000g / mol,密度为890〜935kg / m 3。