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    • 3. 发明授权
    • Optical article exhibiting a large first hyperpolarizability
    • 具有大的第一超极化性的光学制品
    • US5501821A
    • 1996-03-26
    • US19815
    • 1993-02-19
    • Craig S. WillandDouglas R. RobelloEdward J. UrankarAbraham Ulman
    • Craig S. WillandDouglas R. RobelloEdward J. UrankarAbraham Ulman
    • G02F1/361F21V9/00
    • G02F1/3613G02F1/361G02F1/3617
    • An optical article, for the transmission of electromagnetic radiation. The optical article includes a medium, which exhibits a second-order electric susceptibility greater than 10.sup.-9 electrostatic units. The medium includes polar aligned dipole subunits. Each dipole subunit has a plurality of noncentrosymmetric molecular dipoles and a connector system. Each molecular dipole has an electron donor moiety, an electron acceptor moiety, and a linking moiety. The linking moiety has a pair of covalent bonds to the connector system. Each molecular dipole has a conjugated .pi. bonding system extending from the electron donor moiety along the linking moiety to the electron acceptor moiety to permit oscillation of the molecular dipole between a ground state and an excited state, which states differ in polarity. The connector system joins the linking moieties to complete a solitary ring or a system of fused rings, which retain the molecular dipoles in substantially parallel relative relation.
    • 一种用于传输电磁辐射的光学制品。 光学制品包括介质,其表现出大于10-9静电单位的二次电磁化率。 介质包括极性对准的偶极子单元。 每个偶极子单元具有多个非中心对称分子偶极子和连接器系统。 每个分子偶极子具有电子供体部分,电子受体部分和连接部分。 连接部分与连接器系统具有一对共价键。 每个分子偶极具有从电子供体部分沿着连接部分延伸到电子受体部分的共轭π键合体系,以允许分子偶极子在基态和激发态之间的振荡,其状态极性不同。 连接器系统连接连接部分以完成孤立环或稠环系统,其将分子偶极保持为基本平行的相对关系。