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    • 6. 发明授权
    • Process for forming a semiconductor device
    • 用于形成半导体器件的工艺
    • US5888588A
    • 1999-03-30
    • US828638
    • 1997-03-31
    • Rajan NagabushnamOlubunmi AdetutuYeong-Jyh Tom Lii
    • Rajan NagabushnamOlubunmi AdetutuYeong-Jyh Tom Lii
    • C23C16/34H01L21/28H01L29/49C23C16/00H01L21/285
    • C23C16/34H01L21/28061H01L29/4941
    • A semiconductor device (10) includes a gate electrode (61) having a silicon/tungsten nitride/tungsten silicon nitride/tungsten silicide composition. The tungsten nitride film (21) and tungsten suicide film (23) are formed using chemical vapor deposition (CVD). The tungsten nitride film is formed using a tungsten halide and N.sub.2 R.sup.1 R.sup.2, where each of R.sup.1 and R.sup.2 is hydrogen, an alkyl group, an alkenyl group, or an alkynyl group. The tungsten nitride film (21) is an etch stop when patterning the tungsten silicide film (23). The CVD tungsten nitride film (21) helps to improve gate dielectric integrity and reduces interface traps when compared to a sputtered tungsten nitride film (21). Also, N.sub.2 R.sup.1 R.sup.2 can be used to remove halogens that are adsorbed onto walls of a reaction chamber than is cleaned between depositions of substrates.
    • 半导体器件(10)包括具有硅/氮化钨/氮化钨/硅化钨组合物的栅电极(61)。 使用化学气相沉积(CVD)形成氮化钨膜(21)和硅化钨膜(23)。 氮化钨膜使用卤化钨和N 2 R 1 R 2形成,其中R 1和R 2各自为氢,烷基,烯基或炔基。 当图案化硅化钨膜(23)时,氮化钨膜(21)是蚀刻停止层。 与溅射的氮化钨膜(21)相比,CVD氮化钨膜(21)有助于提高栅极电介质完整性并减少界面陷阱。 此外,N2R1R2可用于除去吸附到反应室壁上的卤素,而不是在底物沉积之间清洗的卤素。