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    • 2. 发明授权
    • Polymerizable phosphazene derivatives: a process for preparing them and
their uses
    • 可聚合磷腈衍生物:其制备方法及其用途
    • US5912321A
    • 1999-06-15
    • US840839
    • 1997-04-17
    • Thomas RaithWolfgang Nuding
    • Thomas RaithWolfgang Nuding
    • C07F9/24C07F9/06C07F9/6593C08F30/02C09D4/00C09D143/02C09J4/00C09J143/02C08G79/02
    • C07F9/65815C07F9/067C08F30/02C09D4/00
    • This invention relates to a polymerizable phosphazene derivative with a general structural formula.brket open-st.NP(A).sub.a (B).sub.b).brket close-st..sub.xwherein the groups A and B are bonded to phosphorus atoms through --O--, --S--, --NH--, or --NR-- (with R=C.sub.1 -C.sub.6) alkyl), and wherein A stands more precisely for a vinyl ether group or a styrene ether group, and B stands more precisely for a hydrocarbon group. The invention also relates to procedures for synthesizing such phosphazene derivatives. The phosphazenes derivatives of the invention can be cured by a process that is initiated cationically, which leads to a large number of advantages. The phosphazene derivatives of the invention can, in particular, be used as curable binders for paints, coatings, fillers, mastics, adhesives, moldings, or films. Paints or coatings comprising the phosphazene derivatives of the invention show especially high mechanical resistance and scratch resistance.
    • 本发明涉及通式为+ 547 NP(A)a(B)b)+548×的聚合磷腈衍生物,其中基团A和B通过-O - , - S - , - NH - 或-NR-(其中R = C 1 -C 6)烷基),并且其中A更精确地代表乙烯基醚基团或苯乙烯醚基团,并且B更精确地代表烃基。 本发明还涉及合成这种磷腈衍生物的方法。 本发明的磷腈衍生物可以通过阳离子引发的方法固化,这导致许多优点。 本发明的磷腈衍生物特别可以用作油漆,涂料,填料,胶粘剂,粘合剂,模制品或薄膜的可固化粘合剂。 包含本发明的磷腈衍生物的涂料或涂料显示出特别高的机械性能和耐擦伤性。
    • 4. 发明授权
    • Compositions having a phosphazene derivative and a cross-linking agent
    • 具有磷腈衍生物和交联剂的组合物
    • US5994497A
    • 1999-11-30
    • US964409
    • 1997-11-04
    • Thomas RaithWolfgang Nuding
    • Thomas RaithWolfgang Nuding
    • C09K3/00C07F9/6593C08G18/78C08G59/02C08G77/30C08G79/02C09D201/00C09J201/00
    • C07F9/65815Y02P20/55
    • The invention relates to hardenable compositions which contain as the essential constituent, in the non-hardened condition, at least one phosphazene derivative of the general formula [NP--(X--Y--Z).sub.2 ].sub.n, and at least one cross-linking agent with at least two functional groups which are selected among the Z radicals and which can react with the functional Z radicals of the phosphazene derivative is provided, whereinX radicals are from the group --O--, --S--, --NH-- or --NR--, preferably oxygen,Y are aliphatic, cycloaliphatic, aromatic and/or heteroaromatic hydrocarbon groups,Z are functional radicals from the group --OH, --NH.sub.2, --NCO, --COOH, --CHO, --CH.dbd.CH.sub.2, allyl, N-methylol, acrylate, methacrylate, silyl, glycidyl or epoxy or preliminary stages of the radicals from this group or radicals from this group which are blocked by protective groups, preferably acrylate or methacylrate radicals andn is an integer of at least 3 and no more than 10;The NP radicals of the above formula are preferably combined to a phosphazene ring, n being 3 or 4. The phophazene derivatives can be used for the production of hardenable lacquers, coating agents or fillers, knifing fillers, adhesives, preforms or foils.
    • 本发明涉及在非硬化条件下含有至少一种通式[NP-(XYZ)2] n的磷腈衍生物和至少一种具有至少一种交联剂的交联剂作为必要组分的可硬化组合物 提供了选自Z基团并且可以与磷腈衍生物的官能Z基团反应的两个官能团,其中X基团来自基团-O - , - S - , - NH-或-NR-,优选 氧,Y是脂族,脂环族,芳族和/或杂芳族烃基,Z是基团-OH,-NH 2,-NCO,-COOH,-CHO,-CH = CH 2,烯丙基,N-羟甲基,丙烯酸酯 甲基丙烯酸酯,甲硅烷基,缩水甘油基或环氧基或该基团的基团的初级阶段或该基团的基团,其被保护基优选丙烯酸酯或甲酰基自由基封端,n为至少3且不大于10的整数; 上式的NP基团优选与磷腈环组合,n为3或4.菲吡烯衍生物可用于生产可硬化漆,涂料或填料,切割填料,粘合剂,预成型件或箔。
    • 5. 发明授权
    • Polymerizable phosphazene derivatives: a process for preparing them and
their uses
    • 可聚合磷腈衍生物:其制备方法及其用途
    • US6060583A
    • 2000-05-09
    • US257250
    • 1999-02-25
    • Thomas RaithWolfgang Nuding
    • Thomas RaithWolfgang Nuding
    • C07F9/24C07F9/06C07F9/6593C08F30/02C09D4/00C09D143/02C09J4/00C09J143/02C08J3/00
    • C07F9/65815C07F9/067C08F30/02C09D4/00
    • This invention relates to a polymerizable phosphazene derivative with a general structural formula[.brket open-st.NP(A).sub.a (B).sub.b).brket close-st.]xwherein the groups A and B are bonded to phosphorus atoms through --O--, --S--, --NH--, or --NR-- (with R=C.sub.1 -C.sub.6) alkyl), and wherein A stands more precisely for a vinyl ether group or a styrene ether group, and B stands more precisely for a hydrocarbon group. The invention also relates to procedures for synthesizing such phosphazene derivatives. The phosphazenes derivatives of the invention can be cured by a process that is initiated cationically, which leads to a large number of advantages. The phosphazene derivatives of the invention can, in particular, be used as curable binders for paints, coatings, fillers, mastics, adhesives, moldings, or films. Paints or coatings comprising the phosphazene derivatives of the invention show especially high mechanical resistance and scratch resistance.
    • 本发明涉及具有通式[+547NP(A)a(B)b)+ 548] x的聚合磷腈衍生物,其中基团A和B通过-O - , - S-, -NH-或-NR-(其中R = C1-C6)烷基),并且其中A更精确地代表乙烯基醚基团或苯乙烯醚基团,并且B更精确地代表烃基。 本发明还涉及合成这种磷腈衍生物的方法。 本发明的磷腈衍生物可以通过阳离子引发的方法固化,这导致许多优点。 本发明的磷腈衍生物特别可以用作油漆,涂料,填料,胶粘剂,粘合剂,模制品或薄膜的可固化粘合剂。 包含本发明的磷腈衍生物的涂料或涂料显示出特别高的机械性能和耐擦伤性。
    • 6. 发明授权
    • Polymerizable phosphazene derivatives: a process for preparing them and
their uses
    • 可聚合磷腈衍生物:其制备方法及其用途
    • US6020081A
    • 2000-02-01
    • US257241
    • 1999-02-25
    • Thomas RaithWolfgang Nuding
    • Thomas RaithWolfgang Nuding
    • C07F9/24C07F9/06C07F9/6593C08F30/02C09D4/00C09D143/02C09J4/00C09J143/02B32B9/04
    • C07F9/65815C07F9/067C08F30/02C09D4/00
    • This invention relates to a polymerizable phosphazene derivative with a general structural formula.brket open-st.NP(A).sub.a (B).sub.b).brket close-st..sub.xwherein the groups A and B are bonded to phosphorus atoms through --O--, --S--, --NH--, or --NR-- (with R=C.sub.1 -C.sub.6) alkyl), and wherein A stands more precisely for a vinyl ether group or a styrene ether group, and B stands more precisely for a hydrocarbon group. The invention also relates to procedures for synthesizing such phosphazene derivatives. The phosphazenes derivatives of the invention can be cured by a process that is initiated cationically, which leads to a large number of advantages. The phosphazene derivatives of the invention can, in particular, be used as curable binders for paints, coatings, fillers, mastics, adhesives, moldings, or films. Paints or coatings comprising the phosphazene derivatives of the invention show especially high mechanical resistance and scratch resistance.
    • 本发明涉及通式为+ 547NP(A)a(B)b)+548×的聚合磷腈衍生物,其中A和B基通过-O - , - S - , - NH- ,或-NR-(其中R = C1-C6)烷基),并且其中A更精确地代表乙烯基醚基团或苯乙烯醚基团,并且B更精确地代表烃基。 本发明还涉及合成这种磷腈衍生物的方法。 本发明的磷腈衍生物可以通过阳离子引发的方法固化,这导致许多优点。 本发明的磷腈衍生物特别可以用作油漆,涂料,填料,胶粘剂,粘合剂,模制品或薄膜的可固化粘合剂。 包含本发明的磷腈衍生物的涂料或涂料显示出特别高的机械性能和耐擦伤性。