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    • 3. 发明授权
    • Phosphazene compound, photosensitive resin composition and use thereof
    • 磷腈化合物,感光性树脂组合物及其用途
    • US08063245B2
    • 2011-11-22
    • US10559737
    • 2004-06-03
    • Koji OkadaToshio Yamanaka
    • Koji OkadaToshio Yamanaka
    • C07F9/547
    • C08G79/025C07F9/067C07F9/65812G03F7/027G03F7/032G03F7/037G03F7/0388
    • Disclosed is a phosphazene compound and a photosensitive resin composition. The phosphazene compound is obtained by reacting a phenoxyphosphazene compound (A-1) having a phenolic hydroxyl group and/or a cross-linked phenoxyphosphazene compound (A-2) obtained by cross-linking the phenoxyphosphazene compound (A-1) with an epoxy compound (B) having an unsaturated double bond and/or an isocyanate compound (C), wherein the phosphazene compound has an unsaturated double bond in its molecule. The photosensitive resin composition includes at least: a soluble polyimide resin (G-1) having a carboxyl group and/or a hydroxyl group and is soluble in an organic solvent, as the polyimide resins (G); and a phenoxyphosphazene compound (H-1) having a phenolic hydroxyl group and/or a cross-linked phenoxyphosphazene compound (H-2), which is obtained by cross-linking the phenoxyphosphazene compound (H-1) and has at least one phenolic hydroxyl group, as the phosphazene compound (H), and the photosensitive resin composition further includes a (meth)acrylic compound (L).
    • 公开了磷腈化合物和感光性树脂组合物。 通过使具有酚羟基的苯氧基磷腈化合物(A-1)和/或通过将苯氧基磷腈化合物(A-1)交联而获得的交联的苯氧基磷腈化合物(A-2)与环氧化合物 具有不饱和双键的化合物(B)和/或异氰酸酯化合物(C),其中磷腈化合物在其分子中具有不饱和双键。 作为聚酰亚胺树脂(G),感光性树脂组合物至少包括具有羧基和/或羟基并且可溶于有机溶剂的可溶性聚酰亚胺树脂(G-1)。 和具有酚羟基的苯氧基磷腈化合物(H-1)和/或交联的苯氧基磷腈化合物(H-2),其是通过交联苯氧基磷腈化合物(H-1)而得到的,并具有至少一种酚 羟基作为磷腈化合物(H),感光性树脂组合物还含有(甲基)丙烯酸系化合物(L)。
    • 5. 发明授权
    • Process for producing aryloxy-substituted phosphazene derivatives
    • 制备芳氧基取代的磷腈衍生物的方法
    • US5075453A
    • 1991-12-24
    • US401570
    • 1989-08-29
    • Shinichiro UeyamaKazuhiko FujikawaYasuhiro YoshikawaTetsuhiko OkamotoMasayuki FurukawaTadaichi Nishikawa
    • Shinichiro UeyamaKazuhiko FujikawaYasuhiro YoshikawaTetsuhiko OkamotoMasayuki FurukawaTadaichi Nishikawa
    • C07F9/06C07F9/6581C08G79/02C10M105/74
    • C07F9/65814C07F9/067C08G79/025C10M105/74
    • A process for producing an aryloxy-substituted phosphazene derivative represented by the formula(N.dbd.P).sub.n (OAr).sub.l Cl.sub.m-l R.sup.1.sub.p (III)which comprises reacting a chlorophosphazene derivative represented by the general formula(N.dbd.P).sub.n Cl.sub.m R.sup.1.sub.p (I)with, a hydroxy aryl compound represented by the general formulaHOAr (II)whereR.sup.1 represents hydroxy group, NH.sub.2 group, --OR.sup.4 group, --SR.sup.4 group or ##STR1## group, where R.sup.4, R.sup.5 and R.sup.6 represent independently an alkyl group, an alkenyl group, alkynyl group or an aryl group or one of R.sup.5 or R.sup.6 may be hydrogen or R.sup.5 and R.sup.6 may form, together with a nitrogen atom bonded thereto, a saturated or an unsaturated heterocyclic ring,n is an integer of 3 to 20,m is an integer of 1 to 2n,p is 2n-m,Ar represents substituted or unsubstituted phenyl, substituted or unsubstituted naphthyl, or substituted or unsubstituted N-maleimidophenyl,l is an integer of 1 to m,wherein the reaction is carried out under the presence of an acid acceptor and a pyridine derivative represented by the formula ##STR2## where Q.sup.1 and Q.sup.2 represent identical or different lower alkyl groups or constitute together with a nitrogen atom bonded thereto, a pyrrolidine ring, piperidine ring or morpholine ring.
    • 一种制备由式(N = P)n(OAr)1 Clm-lR1p(III)表示的芳氧基取代的磷腈衍生物的方法,其包括使由通式(N = P)nClmR1p(I)表示的氯代膦腈衍生物 与通式为HOAr(II)表示的羟基芳基化合物,其中R 1表示羟基,NH 2基,-OR 4基团,-SR 4基团或基团,其中R 4,R 5和R 6独立地表示烷基, 烯基,炔基或芳基,或者R 5或R 6中的一个可以是氢或R 5,R 6可以与其键合的氮原子一起形成饱和或不饱和杂环,n为3〜20的整数, m为1〜2n的整数,p为2n-m,Ar表示取代或未取代的苯基,取代或未取代的萘基,或取代或未取代的N-马来酰亚胺基苯基,l为1〜m的整数,其中, 在酸受体和吡啶衍生物代表的存在下 其中Q1和Q2表示相同或不同的低级烷基,或与其键合的氮原子一起构成吡咯烷环,哌啶环或吗啉环。