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1. 发明授权

US06608006B2 Methods of drilling well bores using invertible oil external-water internal drilling fluids 有权
标题翻译：使用可逆油外水内部钻井液钻井井的方法
公开(公告)号：US06608006B2
公开(公告)日：2003-08-19
申请号：US09952410
申请日：2001-09-14
申请人： Robert S. Taylor , Suzanne Arnold , Tommy R. Gardner , Karen L. King
发明人： Robert S. Taylor , Suzanne Arnold , Tommy R. Gardner , Karen L. King
IPC分类号： C09K706
CPC分类号： C09K8/28 , C09K8/36 , C09K8/64 , Y10S507/921
摘要： Methods of drilling well bores using an invertible oil external-water internal emulsion drilling fluid and then inverting the drilling fluid to a water external-oil internal emulsion are provided. The methods basically comprise the steps of contacting the oil external-water internal emulsion with an aqueous acid solution containing an anionic sulfonate surfactant for preventing aqueous acid solution-crude oil emulsions and crude oil sludging and a chemical for preventing the anionic sulfonate surfactant from reacting with the emulsifier in the oil external-water internal emulsion.
摘要翻译：提供了使用可逆油外水内部乳液钻井液钻孔井的方法，然后将钻井液倒置为水外油内部乳液。所述方法基本上包括以下步骤：使油外水内部乳液与含有阴离子磺酸盐表面活性剂的酸性水溶液接触，以防止酸性水溶液 - 原油乳液和原油淤渣以及用于防止阴离子磺酸盐表面活性剂与乳化剂在油外水内乳液中。

2. 发明授权

US5674817A Controlling iron in aqueous well fracturing fluids 失效
$Controlling iron in aqueous well fracturing fluids$
标题翻译：在水井压裂液中控制铁
公开(公告)号：US5674817A
公开(公告)日：1997-10-07
申请号：US949659
申请日：1992-11-19
申请人： Michael M. Brezinski , Tommy R. Gardner , Weldon M. Harms , James L. Lane, Jr. , Karen L. King
发明人： Michael M. Brezinski , Tommy R. Gardner , Weldon M. Harms , James L. Lane, Jr. , Karen L. King
IPC分类号： E21B43/12 , C09K8/528 , C09K8/62 , E21B43/00
CPC分类号： C09K8/528 , C09K8/62 , Y10S507/933
摘要： Methods and compositions for controlling iron in aqueous well fracturing fluids are disclosed. In accordance with the methods, ferric iron contained in a fracturing fluid is prevented from precipitating or otherwise disadvantageously reacting by adding a thioalkyl acid or derivative thereof to the fracturing fluid. The thioalkyl acid or derivative reduces ferric ion to ferrous ion which remains in solution at pH levels below about 7.5.
摘要翻译：公开了用于控制含水井压裂液中铁的方法和组合物。根据该方法，通过将硫代烷基酸或其衍生物加入到压裂液中，防止压裂液中所含的三价铁沉淀或以其他方式不利地发生反应。硫代烷基酸或衍生物将铁离子还原成亚铁离子，其保留在溶液中，pH值低于约7.5。

3. 发明授权

US5034140A Well acidizing compositions and method 失效
标题翻译：良好的酸化组合物和方法
公开(公告)号：US5034140A
公开(公告)日：1991-07-23
申请号：US441802
申请日：1989-11-27
申请人： Tommy R. Gardner , Walter R. Dill , William G. F. Ford , Karen L. King
发明人： Tommy R. Gardner , Walter R. Dill , William G. F. Ford , Karen L. King
IPC分类号： C09K8/74
CPC分类号： C09K8/74 , Y10S507/933
摘要： A concentrate which forms an acid internal microemulsion well treatment composition when added to an acid treatment fluid. The concentrate comprises in the range of from about 20% to about 98% by weight of a hydrocarbon carrier fluid, in the range of from about 1% to about 50% by weight of an alkyl alcohol having from 4 to 18 carbon atoms and in the range of from about 1% to about 50% by weight of an emulsifying agent comprising at least one compound selected from the group consisting of sulfate esters, phosphate esters, alkyl aromatic sulfonic acids, amine salts having ester or amide linkages, quaternary ammonium compounds having ester of amide linkages, propoxylated fatty acids, and propoxylated alcohols. Also disclosed are an acid internal microemulsion well treatment composition and a method of treating a subterranean formation to increase the production of hydrocarbons therefrom.
摘要翻译：当加入到酸处理液中时，形成酸性内部微乳液井处理组合物的浓缩物。浓缩物包含约20％至约98％重量的烃载体流体，在约1％至约50％重量的具有4至18个碳原子的烷基醇的范围内，约1％至约50％重量的包含至少一种选自硫酸酯，磷酸酯，烷基芳族磺酸，具有酯或酰胺键的胺盐的化合物的乳化剂的范围，季铵化合物具有酰胺键的酯，丙氧基化的脂肪酸和丙氧基化的醇。还公开了一种酸性内部微乳液井处理组合物和一种处理地下层以增加其生产烃的方法。

4. 发明授权

US4324669A Foamed high viscosity aqueous inorganic acid solutions and methods of using the same 失效
标题翻译：发泡高粘度水性无机酸溶液及其使用方法
公开(公告)号：US4324669A
公开(公告)日：1982-04-13
申请号：US95860
申请日：1979-11-19
申请人： Lewis R. Norman , Tommy R. Gardner
发明人： Lewis R. Norman , Tommy R. Gardner
IPC分类号： C01B7/01 , C09K8/70 , E21B43/27
CPC分类号： C01B7/01 , C09K8/703 , Y10S507/933
摘要： Foamed high viscosity aqueous inorganic acid solutions and methods of treating subterreanean well formations using such solutions are provided. The foamed acid solutions are comprised of water, at least one water soluble inorganic acid, a gelling-foaming agent comprised of a solution of a water soluble organic solvent and an ethoxylated fatty amine or a mixture of such amines and an inert gas.
摘要翻译：提供发泡高粘度水性无机酸溶液和使用这种溶液处理亚曲斯坦井形成的方法。发泡酸溶液由水，至少一种水溶性无机酸，由水溶性有机溶剂和乙氧基化脂肪胺的溶液或这些胺和惰性气体的混合物组成的胶凝发泡剂组成。

5. 发明授权

US4207193A Methods and compositions for removing asphaltenic and paraffinic containing deposits 失效
标题翻译：用于去除含沥青和含石蜡的沉积物的方法和组合物
公开(公告)号：US4207193A
公开(公告)日：1980-06-10
申请号：US889694
申请日：1978-03-24
申请人： William G. F. Ford , Tommy R. Gardner
发明人： William G. F. Ford , Tommy R. Gardner
IPC分类号： C11D3/43 , E21B43/25 , E21B43/28
CPC分类号： C11D3/43 , Y10S507/93 , Y10S507/931
摘要： Asphaltenic and paraffinic containing deposits are removed by contacting the deposits with an aqueous dispersion of a hydrocarbon solvent, an amine and a nonionic alkylated aryl polyether alcohol.
摘要翻译：通过使沉积物与烃溶剂，胺和非离子烷基化芳基聚醚醇的水分散体接触来除去含有沥青质和含石蜡的沉积物。

6. 发明授权

US5489394A Solvent compositions and methods 失效
标题翻译：溶剂组成和方法
公开(公告)号：US5489394A
公开(公告)日：1996-02-06
申请号：US437709
申请日：1995-05-09
申请人： William G. F. Ford , Tommy R. Gardner
发明人： William G. F. Ford , Tommy R. Gardner
IPC分类号： C11D3/18 , C23G5/024 , C11D1/66 , C11D1/02 , C11D3/44
CPC分类号： C11D3/18 , C23G5/024
摘要： The present invention relates to improved environmentally friendly solvent compositions for materials such as pipe dope, thread lubricants and the like and methods of utilizing such compositions. The nonaqueous solvent compositions are basically comprised of an emulsion of a surface active agent for breaking up and dispersing the materials, and D-limonene and a mixture of other terpenes including dipentene for dissolving the materials and glacial acetic acid.
摘要翻译：本发明涉及用于诸如管道涂料，螺纹润滑剂等的材料的改进的环境友好的溶剂组合物以及利用这些组合物的方法。非水溶剂组合物基本上由用于分解和分散材料的表面活性剂的乳液，以及D-柠檬烯和包括用于溶解材料的二戊烯的其它萜烯混合物和冰醋酸组成。

7. 发明授权

US4585065A Methods of increasing hydrocarbon production from subterranean formations 失效
标题翻译：从地下地层增加碳氢化合物生产的方法
公开(公告)号：US4585065A
公开(公告)日：1986-04-29
申请号：US671545
申请日：1984-11-15
申请人： Glenn S. Penny , Walter R. Dill , Tommy R. Gardner
发明人： Glenn S. Penny , Walter R. Dill , Tommy R. Gardner
IPC分类号： C09K8/60 , C09K8/62 , C09K8/86 , E21B43/26
CPC分类号： C09K8/86 , C09K8/60 , C09K8/62 , Y10S507/922
摘要： The present invention relates to a method of treating a carbonate-containing subterranean formation to increase the production of hydrocarbons therefrom. The subterranean formation is contacted with an aqueous solution of a composition represented by the formula: ##STR1## wherein a is a whole number or fraction thereof in the range of from about 4 to about 18;wherein b is a whole number or fraction thereof in the range of from about 0 to about 30;wherein c is a whole number or fraction thereof in the range of from about 0 to about 3;wherein d is independently a whole number or fraction thereof in the range of from about 0 to about 3;wherein e is a whole number or fraction thereof in the range of from about 1 to about 3;R is independently selected from the group consisting of hydrogen and a methyl group whereby mixtures containing both groups may result; andX.sup.+ is an exchangeable cation; andZ is a nucleophile containing species containing at least one member selected from the group consisting of oxygen and nitrogen wherein the nitrogen is in the form of NR.sup.1 H wherein R.sup.1 is independently selected from the group consisting of hydrogen and methyl radicals or admixtures thereof whereby the composition is caused to be absorbed onto the solid surfaces present in the subterranean formation and substantially reduces the tendency of such surfaces from becoming water or hydrocarbon wet.
摘要翻译：本发明涉及一种处理含碳酸盐的地下层以增加烃的生成的方法。地下地层与由下式表示的组合物的水溶液接触：其中a为约4至约18的整数或其分数; 其中b为约0至约30的整数或其分数; 其中c为约0至约3的整数或其分数; 其中d独立地为约0至约3的整数或其分数; 其中e为约1至约3的整数或其分数; R独立地选自氢和甲基，由此可能导致含有两个基团的混合物; X +是可交换阳离子; Z是含有至少一个选自氧和氮的成员的含亲核试剂的物质，其中氮是NR1H的形式，其中R1独立地选自氢和甲基或其混合物，由此组合物被吸收到存在于地层中的固体表面上，并且基本上降低了这些表面变成水或烃湿润的倾向。

8. 发明授权

US06225261B1 Composition and method for controlling precipitation when acidizing wells 失效
标题翻译：酸化井控制沉淀物的组成和方法
公开(公告)号：US06225261B1
公开(公告)日：2001-05-01
申请号：US08073370
申请日：1993-06-07
申请人： Michael M. Brezinski , Tommy R. Gardner , Karen L. King , James L. Lane, Jr.
发明人： Michael M. Brezinski , Tommy R. Gardner , Karen L. King , James L. Lane, Jr.
IPC分类号： C09K300
CPC分类号： C09K8/528 , C09K8/74 , Y10S507/923 , Y10S507/932 , Y10S507/937
摘要： A composition and method for acidizing a formation in the presence of ferric ion, free sulfur and/or sulfides is disclosed. The composition employs a ferric ion reducing agent and a sulfide reactant separately or in combination. The ferric ion reducing agent is a thioalkyl acid. The sulfide reactant compounds include &agr;-diketones and saturated and &agr;-unsaturated cyclic ketones. In another aspect, the reducing activity of the thioalkyl acid is accelerated by the presence of a catalytic quantity of a compound or mixture of compounds which yield in acid solution cuprous ion, cupric ion or combinations thereof with iodide ion.
摘要翻译：公开了一种在铁离子，游离硫和/或硫化物存在下酸化地层的组合物和方法。该组合物分别或组合使用三价铁离子还原剂和硫化物反应物。铁离子还原剂是硫代烷基酸。硫化物反应物化合物包括α-二酮和饱和和α-不饱和环酮。在另一方面，硫代烷基酸的还原活性通过催化量的化合物或化合物的混合物的存在而加速，其在酸性溶液中产生亚铜离子，铜离子或其与碘离子的组合。

9. 发明授权

US5622919A Composition and method for controlling precipitation when acidizing wells 失效
标题翻译：酸化井控制沉淀物的组成和方法
公开(公告)号：US5622919A
公开(公告)日：1997-04-22
申请号：US556679
申请日：1995-11-13
申请人： Michael M. Brezinski , Tommy R. Gardner , Karen L. King , James L. Lane, Jr.
发明人： Michael M. Brezinski , Tommy R. Gardner , Karen L. King , James L. Lane, Jr.
IPC分类号： C09K8/528 , C09K8/74 , C09K7/00 , E21B37/06
CPC分类号： C09K8/74 , C09K8/528 , Y10S585/95
摘要： A composition and method for acidizing a formation in the presence of ferric ion, free sulfur and/or sulfides is disclosed. The composition employs a ferric ion reducing agent and a sulfide reactant separately or in combination. The ferric ion reducing agent is a thioalkyl acid. The sulfide reactant compounds include .alpha.-diketones and saturated and .alpha.-unsaturated cyclic ketones. In another aspect, the reducing activity of the thioalkyl acid is accelerated by the presence of a catalytic quantity of a compound or mixture of compounds which yield in acid solution cuprous ion, cupric ion or combinations thereof with iodide ion.
摘要翻译：公开了一种在铁离子，游离硫和/或硫化物存在下酸化地层的组合物和方法。该组合物分别或组合使用三价铁离子还原剂和硫化物反应物。铁离子还原剂是硫代烷基酸。硫化物反应物化合物包括α-二酮和饱和和α-不饱和环酮。在另一方面，硫代烷基酸的还原活性通过催化量的化合物或化合物的混合物的存在而加速，其在酸性溶液中产生亚铜离子，铜离子或其与碘离子的组合。

10. 发明授权

US5008026A Well treatment compositions and method 失效
标题翻译：井处理组合物和方法
公开(公告)号：US5008026A
公开(公告)日：1991-04-16
申请号：US464277
申请日：1990-01-12
申请人： Tommy R. Gardner , Walter R. Dill , William G. F. Ford , Karen L. King
发明人： Tommy R. Gardner , Walter R. Dill , William G. F. Ford , Karen L. King
IPC分类号： C09K8/72
CPC分类号： C09K8/72 , Y10S507/933
摘要： A concentrate which forms an acid and/or water external microemulsion when added to a treatment fluid. The concentrate comprises an alkyl alcohol having in the range of from 4 to 18 carbon atoms, an emulsifying agent, a mutual solvent selected from the group consisting of glycol ethers and alkyoxylates of glycol ethers, and a co-solvent selected from the group consisting of polyethylene glycol, primary alcohols and alkyoxylates of alkyl alcohols. Also disclosed are an acid and/or water external microemulsion well treatment composition and a method of treating a subterranean formation to increase the production of hydrocarbons therefrom.
摘要翻译：当加入到处理流体中时，形成酸和/或水外部微乳液的浓缩物。所述浓缩物包含具有4至18个碳原子的烷基醇，乳化剂，选自二醇醚的二醇醚和烷氧基化物的互溶剂和选自以下的共溶剂：聚乙二醇，伯醇和烷基醇的烷氧基化物。还公开了一种酸和/或水外部微乳液井处理组合物和一种处理地下层以增加烃的生产的方法。

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