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    • 2. 发明申请
    • Methods of making an antistatic agent
    • 制造抗静电剂的方法
    • US20050228194A1
    • 2005-10-13
    • US10966774
    • 2004-10-15
    • Theodorus HoeksChiel LeendersRobert van de Grampel
    • Theodorus HoeksChiel LeendersRobert van de Grampel
    • C07C303/32C07C309/06C07F9/54C07C39/02C07F9/02
    • C07C303/32C08K5/50Y10S524/912C07C309/06
    • A method for making the phosphonium sulfonate salt of generic formula (1): wherein each X is independently a halogen or hydrogen, provided that the molar ratio of halogen to hydrogen is greater than about 0.90; p is 0 or 1 and q and r are integers of 0 to about 7 provided that q+r is less than 8 and that if p is not zero then r is greater than zero; and each R is the same or different hydrocarbon radical containing 1 to about 18 carbon atoms, the method comprising combining in an aqueous medium a compound of generic formula (2): wherein M is Li or Na, and X, q, p, and r are as defined above, with a stoichiometric excess of a compound of the generic formula (3): (R)4P-Z  (3) wherein Z is a halogen and R is as defined above; and separating the product of formula (1) from the medium.
    • 制备通式(1)的鏻磺酸盐的方法:其中每个X独立地为卤素或氢,条件是卤素与氢的摩尔比大于约0.90; p为0或1,q和r为0至约7的整数,条件是q + r小于8,如果p不为零,则r大于零; 并且每个R是含有1至约18个碳原子的相同或不同的烃基,该方法包括在水性介质中混合通式(2)的化合物:其中M是Li或Na,X,q,p和 r如上所定义,化学计量过量的通式(3)的化合物:<?in-line-formula description =“In-line Formulas”end =“lead”→(R) PZ(3)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中Z是卤素,R如上定义; 和将式(1)的产物与介质分离。
    • 3. 发明申请
    • METHOD OF MAKING A THERMOPLASTIC COMPOSITION CONTAINING AN ANTISTATIC AGENT
    • 制备含有抗静电剂的热塑性组合物的方法
    • US20080081857A1
    • 2008-04-03
    • US11869338
    • 2007-10-09
    • Theodorus HoeksChiel LeendersRobert van de Grampel
    • Theodorus HoeksChiel LeendersRobert van de Grampel
    • C08G64/00C08K5/51
    • C07C303/32C08K5/50Y10S524/912C07C309/06
    • A method for preparing a thermoplastic composition containing an antistatic agent is described. The antistatic agent is a phosphonium sulfonate salt of generic formula (1) wherein each X is independently a halogen or hydrogen, provided that the molar ratio of halogen to hydrogen is greater than about 0.90; p is 0 or 1 and q and r are integers of 0 to about 7 provided that q+r is less than 8 and that if p is not zero then r is greater than zero; and each R is the same or different hydrocarbon radical containing 1 to about 18 carbon atoms. The phosphonium sulfonate salt is prepared by a method that includes combining in an aqueous medium sodium hydroxide and/or lithium hydroxide, a compound of the generic formula (4) wherein X, q, p, and r are as defined above, and a compound of the generic formula (3) (R)4P-Z  (3) wherein Z is a halogen and R is as defined above; and separating the phosphonium sulfonate of formula (1) from the aqueous medium. The phosphonium sulfonate salt is then combined with a thermoplastic resin.
    • 描述了制备含有抗静电剂的热塑性组合物的方法。 抗静电剂是通式(1)的鏻磺酸盐,其中每个X独立地是卤素或氢,条件是卤素与氢的摩尔比大于约0.90; p为0或1,q和r为0至约7的整数,条件是q + r小于8,如果p不为零,则r大于零; 并且每个R是含有1至约18个碳原子的相同或不同的烃基。 鏻磺酸盐通过包括在水性介质氢氧化钠和/或氢氧化锂中组合其中X,q,p和r如上定义的通式(4)的化合物和化合物 通用公式(3)<?in-line-formula description =“In-line Formulas”end =“lead”?>(R)(3) formula description =“In-line Formulas”end =“tail”?>其中Z是卤素,R如上定义; 并将式(1)的磺酸鏻与水性介质分离。 然后将鏻磺酸盐与热塑性树脂组合。
    • 7. 发明申请
    • Methods of making an antistatic agent
    • 制造抗静电剂的方法
    • US20060100327A1
    • 2006-05-11
    • US10983878
    • 2004-11-08
    • Theodorus HoeksChiel LeendersRobert van de Grampel
    • Theodorus HoeksChiel LeendersRobert van de Grampel
    • C08K5/49
    • C07C303/32C07F9/5407C07C309/06C07C309/10
    • Disclosed are methods for making the phosphonium sulfonate salt of generic formula (1): wherein each X is independently a halogen or hydrogen, provided that the molar ratio of halogen to hydrogen is greater than about 0.90; p is 0 or 1 and q and r are integers of 0 to about 7 provided that q+r is less than 8 and that if p is 1 then r is greater than zero; and each R is the same or different hydrocarbon radical containing 1 to about 18 carbon atoms, the method comprising the steps of combining in an aqueous medium, a compound of the generic formula (2): wherein M is K, and X, q, p, and r are as defined above, with a compound of the generic formula (3): (R)4P-Z  (3) wherein Z is a halogen and R is as defined above; and separating the phosphonium sulfonate of formula (1) from the aqueous medium. Also disclosed is an antistatic composition comprising phosphonium sulfonate (1), and articles prepared therefrom.
    • 公开了制备通式(1)的鏻磺酸盐的方法:其中每个X独立地是卤素或氢,条件是卤素与氢的摩尔比大于约0.90; p为0或1,q和r为0至约7的整数,条件是q + r小于8,如果p为1,则r大于零; 并且每个R是含有1至约18个碳原子的相同或不同的烃基,该方法包括以下步骤:在水性介质中混合通式(2)的化合物:其中M是K,X,q, p和r如上所定义,与通式(3)的化合物:<?in-line-formula description =“In-line Formulas”end =“lead”?(R) PZ(3)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中Z是卤素,R如上所定义; 并将式(1)的磺酸鏻与水性介质分离。 还公开了包含磺酸鏻(1)和由其制备的制品的抗静电组合物。