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    • 1. 发明授权
    • Process for the manufacture of functional PFPE derivative
    • 制备功能性PFPE衍生物的方法
    • US08975445B2
    • 2015-03-10
    • US13262692
    • 2010-04-02
    • Prakash WadgaonkarShamal MenonClaudio Adolfo Pietro Tonelli
    • Prakash WadgaonkarShamal MenonClaudio Adolfo Pietro Tonelli
    • C08G65/325C08G65/00C08G65/323C08G65/333C08G65/337
    • C08G65/007C08G65/325C08G65/33303C08G65/337C10M2213/06
    • A process for the manufacture of a functional (per)fluoropolyether derivative comprising at least one triazole group, such process comprising: (1) reacting a (per)fluoropolyether hydroxyl derivative having at least one hydroxyl group [derivative (PFPE-OH)] with an activating agent, to yield an activated (per)fluoropolyether hydroxyl derivative comprising at least one activated hydroxyl group [derivative (a-PFPE-OH)];(2) reacting said activated (per)fluoropolyether hydroxyl derivative [derivative (a-PFPE-OH)] with at least one azide salt to yield a functional (per)fluoropolyether derivative comprising at least one azido group [derivative (PFPE-N3)] ; and (3) reacting said functional (per)fluoropolyether derivative comprising at least one azido group [derivative (PFPE-N3)] with a hydrocarbon compound having a terminal alkyne group to yield a functional (per)fluoropolyether derivative comprising at least one triazole group [derivative (PFPE-azole)].
    • 一种制备包含至少一个三唑基团的官能(全)氟代聚醚衍生物的方法,该方法包括:(1)使具有至少一个羟基(衍生物(PFPE-OH))的(全)氟聚醚羟基衍生物与[ 产生活性(全)含氟聚醚羟基衍生物,其包含至少一种活化羟基[衍生物(a-PFPE-OH)]);(2)使所述活化的(全)氟聚醚羟基衍生物[衍生物(a-PFPE-OH) -OH)]与至少一种叠氮化物盐反应,得到包含至少一个叠氮基[衍生物(PFPE-N 3)]的官能(全)氟代聚醚衍生物; 和(3)使包含至少一个叠氮基[衍生物(PFPE-N 3)]的所述官能(全)氟聚醚衍生物与具有末端炔基的烃化合物反应,得到包含至少一个三唑基团的官能(全)氟聚醚衍生物 [衍生物(PFPE-唑)]。
    • 6. 发明申请
    • Process for the manufacture of functional PFPE derivative
    • 制备功能性PFPE衍生物的方法
    • US20120028858A1
    • 2012-02-02
    • US13262692
    • 2010-04-02
    • Prakash WadgaonkarShamal MenonClaudio Adolfo Pietro Tonelli
    • Prakash WadgaonkarShamal MenonClaudio Adolfo Pietro Tonelli
    • C10M133/44C09K3/00C07D249/04
    • C08G65/007C08G65/325C08G65/33303C08G65/337C10M2213/06
    • A process for the manufacture of a functional (per)fluoropolyether derivative comprising at least one triazole group, such process comprising: (1) reacting a (per)fluoropolyether hydroxyl derivative having at least one hydroxyl group [derivative (PFPE-OH)] with an activating agent, to yield an activated (per)fluoropolyether hydroxyl derivative comprising at least one activated hydroxyl group [derivative (a-PFPE-OH)]; (2) reacting said activated (per)fluoropolyether hydroxyl derivative [derivative (a-PFPE-OH)] with at least one azide salt to yield a functional (per)fluoropolyether derivative comprising at least one azido group [derivative (PFPE-N3)]; and (3) reacting said functional (per)fluoropolyether derivative comprising at least one azido group [derivative (PFPE-N3)] with a hydrocarbon compound having a terminal alkyne group to yield a functional (per)fluoropolyether derivative comprising at least one triazole group [derivative (PFPE-azole)].
    • 一种制备包含至少一个三唑基团的官能(全)氟代聚醚衍生物的方法,该方法包括:(1)使具有至少一个羟基(衍生物(PFPE-OH))的(全)氟聚醚羟基衍生物与[ 活化剂,以产生包含至少一种活化羟基的活性(全)氟聚醚羟基衍生物[衍生物(a-PFPE-OH)]; (2)使所述活化的(全)氟聚醚羟基衍生物[衍生物(a-PFPE-OH)]与至少一种叠氮化物盐反应,得到包含至少一个叠氮基[衍生物(PFPE-N 3))的官能(全)氟聚醚衍生物 ]; 和(3)使包含至少一个叠氮基[衍生物(PFPE-N 3)]的所述官能(全)氟聚醚衍生物与具有末端炔基的烃化合物反应,得到包含至少一个三唑基团的官能(全)氟聚醚衍生物 [衍生物(PFPE-唑)]。