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    • 2. 发明授权
    • Process for producing pyruvic acid
    • 制备丙酮酸的方法
    • US4247716A
    • 1981-01-27
    • US932938
    • 1978-08-11
    • Tadamitsu Kiyoura
    • Tadamitsu Kiyoura
    • C07C51/235C07C59/19
    • C07C51/235
    • A novel process for producing pyruvic acid is provided in which process hydroxyacetone is oxidized with a molecular oxygen-containing gas in a water-containing or aqueous solvent in the presence of a catalyst. The catalysts useful for the above oxidation reaction are those composed of either at least one metal selected from the group consisting of platinum, palladium, rhodium, ruthenium, and rhenium, or the at least one metal admixed with at least one element selected from the group consisting of silver, tellurium, tin, bismuth, lead and indium or with a compound of the at least one element. The resulting pyruvate can be effectively isolated in the form of a solid by concentrating the reaction solution and adding the concentrate to isopropyl alcohol.
    • 提供了一种制备丙酮酸的新方法,其中在催化剂存在下,在含水或含水溶剂中用含分子氧的气体氧化羟基丙酮。 可用于上述氧化反应的催化剂是由选自铂,钯,铑,钌和铼中的至少一种金属组成的催化剂,或至少一种与至少一种选自以下的元素混合的金属: 由银,碲,锡,铋,铅和铟组成,或与至少一种元素的化合物组成。 通过浓缩反应溶液并将浓缩物加入到异丙醇中,所得丙酮酸盐可以以固体的形式有效地分离。