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1. 发明授权

US4227023A Process for the selective ortho-alkylation of phenolic compounds 失效
标题翻译：酚类化合物的选择性邻烷基化方法
公开(公告)号：US4227023A
公开(公告)日：1980-10-07
申请号：US966356
申请日：1978-12-04
申请人： Motoo Kawamata , Tadamitsu Kiyoura , Kazushi Ohshima , Yasuo Kogure , Akihide Kudoh , Makoto Kotani
发明人： Motoo Kawamata , Tadamitsu Kiyoura , Kazushi Ohshima , Yasuo Kogure , Akihide Kudoh , Makoto Kotani
IPC分类号： B01J21/00 , B01J23/00 , B01J23/34 , C07B61/00 , C07C27/00 , C07C37/16 , C07C39/06 , C07C67/00 , C07C37/14
CPC分类号： B01J23/34 , C07C37/16
摘要： This invention relates to a process for the selective ortho-alkylation of a phenolic compound having at least one ortho-positioned a hydrogen atom by catalytically reacting the phenolic compound with an alcohol in the vapor phase. In this process, the reaction of the phenolic compound with the alcohol is carried out at a temperature of from 300.degree. to 550.degree. C. in the presence of a mixed oxide catalyst of manganese, silicon, and one or more additives selected from the group consisting of magnesium oxide, calcium oxide, strontium oxide, and barium oxide. The catalyst used in this invention exhibits not only excellent catalytic activity in the selective ortho-alkylation of phenols but also continuous stability of the activity, good shapability, and good mechanical strength.
摘要翻译：本发明涉及一种通过使酚类化合物与气相中的醇催化反应，使具有至少一个邻位氢原子的酚类化合物进行选择性邻位烷基化的方法。在该方法中，酚类化合物与醇的反应在300℃至550℃的温度下，在锰，硅和一种或多种选自以下的添加剂的混合氧化物催化剂存在下进行：由氧化镁，氧化钙，氧化锶和氧化钡组成。用于本发明的催化剂不仅在酚的选择性邻烷基化中具有优异的催化活性，而且具有活性的连续稳定性，良好的成型性和良好的机械强度。

2. 发明授权

US4375566A Process for producing ortho-alkylated phenols from anisoles 失效
标题翻译：从苯甲醚生产邻烷基化酚的方法
公开(公告)号：US4375566A
公开(公告)日：1983-03-01
申请号：US264391
申请日：1981-05-18
申请人： Motoo Kawamata , Kazushi Ohshima , Mitsuo Onofusa , Akihide Kudoh , Makoto Kotani , Takeshi Tsuda
发明人： Motoo Kawamata , Kazushi Ohshima , Mitsuo Onofusa , Akihide Kudoh , Makoto Kotani , Takeshi Tsuda
IPC分类号： C07C37/00 , B01J23/00 , C07B61/00 , C07C27/00 , C07C37/055 , C07C37/06 , C07C37/16 , C07C39/06 , C07C39/07 , C07C67/00
CPC分类号： C07C37/055 , C07C37/16 , C07C37/48
摘要： A process for producing selectively o-alkylated phenols wherein an anisole having at least one ortho positioned hydrogen atom is contacted with a mixed oxide catalyst in the vapor phase.
摘要翻译：一种生产选择性邻烷基化酚的方法，其中具有至少一个邻位氢原子的苯甲醚与气相中的混合氧化物催化剂接触。

3. 发明授权

US4208537A Process for the selective ortho-alkylation of phenolic compounds 失效
标题翻译：酚类化合物的选择性邻烷基化方法
公开(公告)号：US4208537A
公开(公告)日：1980-06-17
申请号：US964262
申请日：1978-11-27
申请人： Motoo Kawamata , Kazushi Ohshima , Akihide Kudoh , Makoto Kotani
发明人： Motoo Kawamata , Kazushi Ohshima , Akihide Kudoh , Makoto Kotani
IPC分类号： B01J23/26 , B01J23/86 , C07C37/16
CPC分类号： B01J23/862 , B01J23/26 , C07C37/16
摘要： The selective alkylation of a phenolic compound having a hydrogen atom in at least one of the ortho positions is achieved by reacting the phenolic compound with an alcohol in the vapor phase in the presence of a catalyst containing mixed oxides of chromium and tin. The catalyst can additionally contain iron oxide, sulfate radical, or a combination thereof.
摘要翻译：在至少一个邻位具有氢原子的酚类化合物的选择性烷基化是通过在含有铬和锡的混合氧化物的催化剂的存在下使气相中的酚类化合物与醇反应来实现的。催化剂还可含有氧化铁，硫酸根或其组合。

4. 发明授权

US4390737A Process for the ortho-alkylation of phenolic compounds 失效
标题翻译：酚类化合物的邻烷基化方法
公开(公告)号：US4390737A
公开(公告)日：1983-06-28
申请号：US316781
申请日：1981-10-30
申请人： Akihide Kudoh , Motoo Kawamata , Kazushi Ohshima , Makoto Kotani , Takeshi Tsuda , Satoshi Morita
发明人： Akihide Kudoh , Motoo Kawamata , Kazushi Ohshima , Makoto Kotani , Takeshi Tsuda , Satoshi Morita
IPC分类号： B01J23/00 , B01J23/32 , C07B61/00 , C07C27/00 , C07C37/16 , C07C39/06 , C07C67/00
CPC分类号： B01J23/32 , C07C37/16
摘要： This invention relates to a process for the selective ortho-alkylation of a phenolic compound having at least one ortho-positioned hydrogen atom by catalytically reacting the phenolic compound with an alcohol in the vapor phase. In this process, the reaction of the phenolic compound with the alcohol is carried out at a temperature of from 300.degree. to 550.degree. C. in the presence of a catalyst containing manganese oxide, silicon oxide and one or more additives selected from group (A) consisting of germanium oxide, tin oxide and lead oxide, or a catalyst containing manganese oxide, silicon oxide, one or more additives selected from the aforesaid group (A), and one or more additives selected from group (B) consisting of alkali metal oxides and alkaline earth metal oxides. The catalyst used in this invention exhibits not only excellent catalytic activity in the selective ortho-alkylation of phenols, continuous stability of the activity, good shapability, and good mechanical strength but also effective utilization of alcohols.
摘要翻译：本发明涉及一种通过使酚类化合物与气相中的醇催化反应，使具有至少一个邻位氢原子的酚类化合物选择性正烷基化的方法。在该方法中，酚类化合物与醇的反应在含有氧化锰，氧化硅和选自组（A）的一种或多种添加剂的催化剂存在下，在300-550℃的温度下进行。），或者含有氧化锰，氧化硅，选自上述组（A）的一种或多种添加剂的一种或多种添加剂和选自由碱金属（B）组成的组分（B））的一种或多种添加剂组成的催化剂，由氧化锗，氧化锡和氧化铅组成的催化剂，氧化物和碱土金属氧化物。用于本发明的催化剂不仅在酚的选择性邻烷基化中具有优异的催化活性，活性的连续稳定性，良好的成型性和良好的机械强度，而且还有效地利用醇。

5. 发明授权

US4388478A Process for the ortho-alkylation of phenolic compounds 失效
标题翻译：酚类化合物的邻烷基化方法
公开(公告)号：US4388478A
公开(公告)日：1983-06-14
申请号：US316800
申请日：1981-10-30
申请人： Akihide Kudoh , Motoo Kawamata , Kazushi Ohshima , Makoto Kotani , Takeshi Tsuda , Fukuichi Aoki
发明人： Akihide Kudoh , Motoo Kawamata , Kazushi Ohshima , Makoto Kotani , Takeshi Tsuda , Fukuichi Aoki
IPC分类号： B01J23/00 , B01J23/32 , B01J23/34 , C07B61/00 , C07C27/00 , C07C37/16 , C07C39/06 , C07C67/00
CPC分类号： B01J23/32 , C07C37/16
摘要： This invention relates to a process for the selective ortho-alkylation of a phenolic compound having at least one ortho-positioned hydrogen atom by catalytically reacting the phenolic compound with an alcohol in the vapor phase. In this process, the reaction of the phenolic compound with the alcohol is carried out at a temperature of from 300.degree. to 550.degree. C. in the presence of a catalyst containing manganese oxide and one or more additives selected from group (A) consisting of germanium oxide, tin oxide and lead oxide, or a catalyst containing manganese oxide, one or more additives selected from the aforesaid group (A), and one or more additives selected from group (B) consisting of alkali metal oxides and alkaline earth metal oxides. The catalyst used in this invention exhibits not only excellent catalytic activity in the selective ortho-alkylation of phenols, continuous stability of the activity, good shapeability and good mechanical strength but also effective utilization of alcohols.
摘要翻译：本发明涉及一种通过使酚类化合物与气相中的醇催化反应，使具有至少一个邻位氢原子的酚类化合物选择性正烷基化的方法。在该方法中，酚类化合物与醇的反应在含有氧化锰和一种或多种选自（A）组成的催化剂的催化剂存在下，在300〜550℃的温度下进行。或者含有氧化锰的催化剂，选自上述组（A）的一种或多种添加剂和选自由碱金属氧化物和碱土金属氧化物组成的组（B）的一种或多种添加剂。用于本发明的催化剂不仅在酚的选择性邻烷基化中表现出优异的催化活性，活性的连续稳定性，良好的成型性和良好的机械强度，而且有效地利用醇。

6. 发明授权

US4361709A Process for the production of o-alkylated phenols 失效
标题翻译：邻烷基化酚的制备方法
公开(公告)号：US4361709A
公开(公告)日：1982-11-30
申请号：US265600
申请日：1981-05-20
申请人： Motoo Kawamata , Kazushi Ohshima , Mitsuo Onofusa , Akihide Kudoh , Makoto Kotani , Takeshi Tsuda
发明人： Motoo Kawamata , Kazushi Ohshima , Mitsuo Onofusa , Akihide Kudoh , Makoto Kotani , Takeshi Tsuda
IPC分类号： B01J23/00 , C07B61/00 , C07C27/00 , C07C37/16 , C07C39/06 , C07C39/07 , C07C67/00 , C07C37/11
CPC分类号： C07C37/16
摘要： A process for the production of alkyl phenols having at least one o-alkyl radical comprising catalytically reacting a phenolic compound having at least one o-positioned hydrogen atom with an alcohol in the vapor phase in the presence of a manganese oxide containing catalyst modified with a compound of at least one of the alkali metals.
摘要翻译：一种制备具有至少一个邻 - 烷基基团的烷基酚的方法，该方法包括在含有氧化锰的催化剂的存在下，使具有至少一个邻位氢原子的酚化合物与醇在气相中催化反应至少一种碱金属的化合物。

7. 发明授权

US4469506A Production process of ferromagnetic iron powder 失效
标题翻译：铁磁铁粉的生产工艺
公开(公告)号：US4469506A
公开(公告)日：1984-09-04
申请号：US460381
申请日：1983-01-24
申请人： Haruo Sekiguchi , Kimiteru Tagawa , Kazushi Ohshima , Nobuhiro Fukuda
发明人： Haruo Sekiguchi , Kimiteru Tagawa , Kazushi Ohshima , Nobuhiro Fukuda
IPC分类号： B22F1/02 , H01F1/06 , C22C1/04
CPC分类号： H01F1/065 , B22F1/02
摘要： Disclosed herein is a process for producing ferromagnetic iron powder, which process comprises adding and mixing boron oxide or a borate with .alpha.-FeOOH or .alpha.-Fe.sub.2 O.sub.3 without dissolving the former, heating the thus-obtained mixture to 350.degree. C. or higher in a non-reducing atmosphere and then reducing the thus-heated mixture.
摘要翻译：本文公开了一种生产铁磁性铁粉的方法，该方法包括在不溶解前者的情况下将氧化硼或硼酸盐与α-FeOOH或α-Fe2O3加入并混合，将所得混合物加热至350℃或更高非还原气氛，然后还原如此加热的混合物。

8. 发明授权

US4342589A Process for preparing iron compound particles for use in magnetic recording 失效
标题翻译：制备用于磁记录的铁化合物颗粒的方法
公开(公告)号：US4342589A
公开(公告)日：1982-08-03
申请号：US230024
申请日：1981-01-30
申请人： Kazushi Ohshima , Mitsuro Matsunaga , Haruo Sekiguchi , Kazuhiro Imaoka , Fujio Hayashi
发明人： Kazushi Ohshima , Mitsuro Matsunaga , Haruo Sekiguchi , Kazuhiro Imaoka , Fujio Hayashi
IPC分类号： C01G49/02 , B22F9/22 , C01G49/00 , G11B5/706 , H01F1/06 , H01F1/11 , C22B5/02 , H01F1/00
CPC分类号： G11B5/70642 , H01F1/065
摘要： Disclosed is a process for preparing fine needle-like, ferromagnetic iron compound particles for use in magnetic recording in which needle-like iron oxyhydroxide fine particles prepared by simultaneously co-precipitating or cladding iron compound particles with an element of group II of the Periodic Table and manganese at atomic weight ratios of the element of group II of the Periodic Table and manganese to iron of from 0.001/100 to 10/100 and 0.005/100 to 10/100 respectively are reduced and/or oxidized under heating.
摘要翻译：公开了一种制备用于磁记录的细针状铁磁性铁化合物颗粒的方法，其中通过同时共同沉淀或包覆铁化合物颗粒与元素周期表第II族元素制备的针状羟基氧化铁细颗粒并且元素周期表第Ⅱ族元素和锰与铁的原子重量比分别为0.001 / 100〜10/100和0.005 / 100〜10/100的锰在加热下还原和/或氧化。

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