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1. 发明授权

US08946317B2 Composition for hard tissue repair 有权
标题翻译：组织硬组织修复
公开(公告)号：US08946317B2
公开(公告)日：2015-02-03
申请号：US13508451
申请日：2010-11-18
申请人： Noriaki Asada , Shinya Aoki , Hiroshi Naruse , Shoichi Miyakoshi , Masami Arata
发明人： Noriaki Asada , Shinya Aoki , Hiroshi Naruse , Shoichi Miyakoshi , Masami Arata
IPC分类号： A61F2/00 , A61L27/54 , A61L27/16 , C08F265/06 , A61L24/00 , A61L24/06
CPC分类号： A61L27/54 , A61L24/0015 , A61L24/06 , A61L27/16 , A61L2300/404 , A61L2430/02 , C08F265/06 , C08L33/06 , C08L33/12
摘要： The composition for hard tissue repair of the present invention is characterized by comprising 5 to 98.95 parts by weight of a monomer (A), 1 to 75 parts by weight of a (meth)acrylate polymer (B) and 0.05 to 20 parts by weight of a polymerization initiator composition (C) containing an organoboron compound (c1), with the proviso that the total amount of the components (A), (B) and (C) is 100 parts by weight. The composition undergoes small-scale heat generation during curing and can ensure a sufficient working time.
摘要翻译：本发明的硬组织修复用组合物的特征在于，含有5〜98.95重量份单体（A），1〜75重量份（甲基）丙烯酸酯聚合物（B）和0.05〜20重量份含有有机硼化合物（c1）的聚合引发剂组合物（C），前提条件是组分（A），（B）和（C）的总量为100重量份。组合物在固化期间经历小规模的发热并且可以确保足够的工作时间。

2. 发明授权

US5294366A Carboxylate compounds, liquid crystal compositions containing said compounds and liquid crystal element 失效
标题翻译：羧酸酯化合物，含有所述化合物的液晶组合物和液晶元素
公开(公告)号：US5294366A
公开(公告)日：1994-03-15
申请号：US758413
申请日：1991-09-04
申请人： Toyozi Shimizu , Hideo Yamaoka , Shinichi Nishiyama , Shoichi Miyakoshi , Tooru Yamanaka , Nobuyuki Doi
发明人： Toyozi Shimizu , Hideo Yamaoka , Shinichi Nishiyama , Shoichi Miyakoshi , Tooru Yamanaka , Nobuyuki Doi
IPC分类号： C09K19/32 , C07C69/76 , C09K19/20 , G02F1/13
CPC分类号： C09K19/322
摘要： In accordance with the present invention, there are provided carboxylate compounds and liquid compositions thereof represented by the following formula (A) ##STR1## wherein R.sup.1 represents one group selected from the group consisting of alkyl group having 6 to 18 carbon atoms, alkoxy group having 6 to 18 carbon atoms and halogenated alkyl group of 6 to 18 carbon atoms, C* represents an asymmetric carbon atom, and R.sup.2 represents a group represented by the following formula (A)--(CH.sub.2).sub.m --CH.sub.3 or (B)--(CH.sub.2).sub.n --COOR.sub.3 wherein m represents an integer of 2 to 6, n represents an integer of 0 to 5, and R.sup.3 represents alkyl group having 1 to 10 carbon atoms.
摘要翻译：根据本发明，提供了由下式（A）表示的羧酸酯化合物及其液体组合物（*化学结构*）（A），其中R 1表示选自6至18个碳原子数为6〜18的烷氧基，碳原子数为6〜18的卤代烷基，C *表示不对称碳原子，R2表示由下式（A）表示的基团 - （CH2）m-CH3 或（B） - （CH 2）n -COOR 3，其中m表示2至6的整数，n表示0至5的整数，并且R 3表示具有1至10个碳原子的烷基。

3. 发明授权

US09314546B2 Adhesive composition for soft tissues, adhesive composition for wound dressing or wound dressing composition 有权
标题翻译：用于软组织的粘合剂组合物，用于伤口敷料或伤口敷料组合物的粘合剂组合物
公开(公告)号：US09314546B2
公开(公告)日：2016-04-19
申请号：US13508009
申请日：2010-11-18
申请人： Noriaki Asada , Shinya Aoki , Hiroshi Naruse , Shoichi Miyakoshi , Masami Arata
发明人： Noriaki Asada , Shinya Aoki , Hiroshi Naruse , Shoichi Miyakoshi , Masami Arata
IPC分类号： A61L24/00 , A61L15/58 , A61L15/00 , A61L15/44 , A61L26/00 , C08L33/06 , A61L24/04
CPC分类号： A61L24/043 , A61L15/00 , A61L15/44 , A61L15/58 , A61L26/0014 , C08L33/06
摘要： The adhesive composition for soft tissues, the adhesive composition for wound dressing or the wound dressing agent composition of the present invention is an adhesive composition for soft tissues, an adhesive composition for wound dressing or a wound dressing agent composition, comprising a monomer (A), a polymer (B) and a polymerization initiator composition (C) containing an organoboron compound, and is characterized by having a viscosity of 0.4 to 75,000 cp within 30 seconds after mixing of the components (A), (B) and (C). The composition of the present invention not only has low toxicity, low harmfulness and high adhesive strength but also is excellent in workability during application and is capable of forming films of excellent properties.
摘要翻译：本发明的软组织用粘合剂组合物，伤口敷料用粘合剂组合物或伤口敷料剂组合物是软组织用粘合剂组合物，伤口敷料用粘合剂组合物或伤口敷料剂组合物，其含有单体（A），聚合物（B）和含有有机硼化合物的聚合引发剂组合物（C），其特征在于组分（A），（B）和（C）混合后30秒内的粘度为0.4至75,000cp，。本发明的组合物不仅毒性低，危害性低，粘合强度高，而且涂布时的加工性也优异，能够形成优异的膜。

4. 发明申请

US20120225012A1 COMPOSITION FOR HARD TISSUE REPAIR 有权
标题翻译：硬组织修复组合物
公开(公告)号：US20120225012A1
公开(公告)日：2012-09-06
申请号：US13508451
申请日：2010-11-18
申请人： Noriaki Asada , Shinya Aoki , Hiroshi Naruse , Shoichi Miyakoshi , Masami Arata
发明人： Noriaki Asada , Shinya Aoki , Hiroshi Naruse , Shoichi Miyakoshi , Masami Arata
IPC分类号： A61L24/06 , A61K39/395 , A61K38/11 , A61K39/00 , A61K31/137 , A61P31/00 , A61P31/04 , A61P31/12 , A61P29/00 , A61P3/04 , A61P19/02 , A61P25/06 , A61P1/08 , A61P35/00 , A61P11/06 , A61P25/08 , A61P25/24 , A61P7/12 , A61P1/12 , A61P25/16 , A61P17/04 , A61P25/18 , A61P1/06 , A61P9/00 , A61P9/06 , A61P9/12 , A61P7/10 , A61P9/08 , A61P37/06 , A61P21/02 , A61P37/04 , A61K51/00 , A61P25/20 , A61P7/04 , A61P1/16 , A61P25/00 , A61K38/02 , A61K38/17 , A61K31/7088 , A61K31/715 , A61K47/32
CPC分类号： A61L27/54 , A61L24/0015 , A61L24/06 , A61L27/16 , A61L2300/404 , A61L2430/02 , C08F265/06 , C08L33/06 , C08L33/12
摘要： The composition for hard tissue repair of the present invention is characterized by comprising 5 to 98.95 parts by weight of a monomer (A), 1 to 75 parts by weight of a (meth)acrylate polymer (B) and 0.05 to 20 parts by weight of a polymerization initiator composition (C) containing an organoboron compound (c1), with the proviso that the total amount of the components (A), (B) and (C) is 100 parts by weight. The composition undergoes small-scale heat generation during curing and can ensure a sufficient working time.
摘要翻译：本发明的硬组织修复用组合物的特征在于，含有5〜98.95重量份单体（A），1〜75重量份（甲基）丙烯酸酯聚合物（B）和0.05〜20重量份含有有机硼化合物（c1）的聚合引发剂组合物（C），前提条件是组分（A），（B）和（C）的总量为100重量份。组合物在固化期间经历小规模的发热并且可以确保足够的工作时间。

5. 发明授权

US5356561A Carboxylate compounds, liquid crystal compositions and liquid crystal elements containing said compounds and method of optical modulation using said elements 失效
标题翻译：含有所述化合物的羧酸酯化合物，液晶组合物和液晶元素以及使用所述元素进行光学调制的方法
公开(公告)号：US5356561A
公开(公告)日：1994-10-18
申请号：US813032
申请日：1991-12-24
申请人： Toyoji Shimizu , Shinichi Nishiyama , Nobuyuki Doi , Shoichi Miyakoshi , Tooru Yamanaka , Katsuo Taniguchi , Hideo Hama
发明人： Toyoji Shimizu , Shinichi Nishiyama , Nobuyuki Doi , Shoichi Miyakoshi , Tooru Yamanaka , Katsuo Taniguchi , Hideo Hama
IPC分类号： C07C69/757 , C07C69/773 , C07C69/90 , C09K19/02 , C09K19/32 , C07C69/76
CPC分类号： C09K19/0266 , C07C69/757 , C07C69/90 , C09K19/322 , C09K2019/325
摘要： In accordance with the present invention, there are provided carboxylate compounds represented by the following formula [A] and liquid crystal material comprising said compounds ##STR1## wherein R is a group selected from the group consisting of alkyl, alkoxy and halogenated alkyl group of 3-20 carbon atoms, X and Y represent each a group selected from the group consisting of --COO--, --OCO--, --CH.sub.2 CH.sub.2 --, --CH.sub.2 O--, --OCH.sub.2 --, --S--S--, ##STR2## or a single bond, A and B represent each a group selected from the group consisting of specific divalent aromatic and alicyclic group such as phenylene, cyclohexylene and tetrahydronaphthalene and R* is an optically active group of 4-20 carbon atoms containing at least one asymmetric carbon atom (hydrogen atoms attached to the carbon atoms of said optically active group may be substituted with halogen atoms), and m and n are each an integer of 0-2, with the proviso that both m and n do not become 0 at the same time.
摘要翻译：根据本发明，提供由下式[A]表示的羧酸酯化合物和包含所述化合物[A]的液晶材料，其中R是选自烷基，烷氧基和卤代烷基 3-20个碳原子的基团，X和Y各自表示选自-COO - ， - OCO - ， - CH 2 CH 2 - ， - CH 2 O - ， - OCH 2 - ，-SS-，或单键，A和B分别表示选自亚苯基，亚环己基和四氢萘中的特定二价芳族和脂环族的基团，R *是含有至少一个不对称碳原子的4-20个碳原子的光学活性基团（与所述光学活性基团的碳原子连接的氢原子可以被卤素原子取代），m和n分别为0-2的整数，条件是m和n两者不同时成为0 。

6. 发明授权

US5246622A Liquid crystal racemic mixture, liquid crystal composition and liquid crystal element, process for manufacturing liquid crystal element, and uses of liquid crystal element 失效
标题翻译：液晶混合液体，液晶组合物和液晶元件，制造液晶元件的方法和液晶元件的使用
公开(公告)号：US5246622A
公开(公告)日：1993-09-21
申请号：US731978
申请日：1991-07-18
申请人： Toyoji Shimizu , Katsuo Taniguchi , Shinichi Nishiyama , Shoichi Miyakoshi , Tooru Yamanaka , Nobuyuki Doi , Hideo Hama
发明人： Toyoji Shimizu , Katsuo Taniguchi , Shinichi Nishiyama , Shoichi Miyakoshi , Tooru Yamanaka , Nobuyuki Doi , Hideo Hama
IPC分类号： C09K19/02 , C09K19/28 , C09K19/30 , C09K19/32
CPC分类号： C09K19/0266 , C09K19/28 , C09K19/3068 , C09K19/322 , C09K2019/325
摘要： The liquid crystal racemic mixture of the invention is represented by the formula [I]:Z--(X.A).sub.m (Y.B).sub.n COOR.sup.1 [I]wherein R1 is a specific group of alkyl, alkoxy or halogenated alkyl, X and Y are either one of the following group: --COO--, --OCO--, --CH.sub.2 CH.sub.2 --, --CH.sub.2 O--, --OCH.sub.2 --, --COCH.sub.2 --, --CH.sub.2 CO-- and --S--S--, or a single bond, A and B are each a specific bivalent group such as 1,4-phenylene group, Z is a group selected from the group consisting of ##STR1## (wherein R.sub.2 is an alkyl group, an alkoxy group or a halogenated alkyl group), and m and n are an integer of 0 to 2 (m and N not being simultaneously 0). The liquid crystal composition of the invention comprises the racemic mixture as described above. Moreover, the liquid crystal element of the invention comprises a liquid crystal material containing the liquid crystal racemic mixture as described above.

7. 发明申请

US20120219544A1 ADHESIVE COMPOSITION FOR SOFT TISSUES, ADHESIVE COMPOSITION FOR WOUND DRESSING OR WOUND DRESSING COMPOSITION 有权
标题翻译：用于软组织的胶粘组合物，用于绕线或粘合组合物的胶粘组合物
公开(公告)号：US20120219544A1
公开(公告)日：2012-08-30
申请号：US13508009
申请日：2010-11-18
申请人： Noriaki Asada , Shinya Aoki , Hiroshi Naruse , Shoichi Miyakoshi , Masami Arata
发明人： Noriaki Asada , Shinya Aoki , Hiroshi Naruse , Shoichi Miyakoshi , Masami Arata
IPC分类号： C09J133/12 , A61K38/02 , A61K31/715 , A61P17/02 , A61K39/395 , A61K39/00 , A61K38/11 , A61K47/32 , A61K48/00
CPC分类号： A61L24/043 , A61L15/00 , A61L15/44 , A61L15/58 , A61L26/0014 , C08L33/06
摘要： The adhesive composition for soft tissues, the adhesive composition for wound dressing or the wound dressing agent composition of the present invention is an adhesive composition for soft tissues, an adhesive composition for wound dressing or a wound dressing agent composition, comprising a monomer (A), a polymer (B) and a polymerization initiator composition (C) containing an organoboron compound, and is characterized by having a viscosity of 0.4 to 75,000 cp within 30 seconds after mixing of the components (A), (B) and (C). The composition of the present invention not only has low toxicity, low harmfulness and high adhesive strength but also is excellent in workability during application and is capable of forming films of excellent properties.
摘要翻译：本发明的软组织用粘合剂组合物，伤口敷料用粘合剂组合物或伤口敷料剂组合物是软组织用粘合剂组合物，伤口敷料用粘合剂组合物或伤口敷料剂组合物，其含有单体（A），聚合物（B）和含有有机硼化合物的聚合引发剂组合物（C），其特征在于组分（A），（B）和（C）混合后30秒内的粘度为0.4至75,000cp，。本发明的组合物不仅毒性低，危害性低，粘合强度高，而且涂布时的加工性也优异，能够形成优异的膜。

8. 发明授权

US5143644A Carboxylic acid ester compounds, and their related matters and method of producing the same 失效
标题翻译：羧酸酯化合物及其相关事宜及其生产方法
公开(公告)号：US5143644A
公开(公告)日：1992-09-01
申请号：US505592
申请日：1990-04-06
申请人： Hideo Yamaoka , Toyoji Shimizu , Fujihisa Matsunaga , Shinichi Nishiyama , Toru Yamanaka , Shoichi Miyakoshi
发明人： Hideo Yamaoka , Toyoji Shimizu , Fujihisa Matsunaga , Shinichi Nishiyama , Toru Yamanaka , Shoichi Miyakoshi
IPC分类号： C09K19/32
CPC分类号： C09K19/322
摘要： This invention relates to carboxylic acid ester compounds or liquid crystal compounds represented by the following formula [A], liquid crystal compositions and liquid crystal elements using these compounds, the method of producing said liquid crystal elements, and other uses. ##STR1## wherein R represents one radical selected from the group consisting of an alkyl group having 6-18 carbon atoms, an alkoxy group having 6-18 carbon atoms, and a halogenated alkyl group having 6-18 carbon atoms, X represents --CF.sub.3 or --CH.sub.2 --CH.sub.3, m is an integral number of 1-10 when X is --CF.sub.3, and an integral number of 2-10 when X is --CH.sub.2 --CH.sub.3, and C* represents an asymmetric carbon atom.

9. 发明授权

US5459177A Adhesive for soft tissue and kit thereof 失效
标题翻译：软组织粘合剂及其试剂盒
公开(公告)号：US5459177A
公开(公告)日：1995-10-17
申请号：US207167
申请日：1994-03-08
申请人： Shoichi Miyakoshi , Takashi Inoue , Masaki Shimono
发明人： Shoichi Miyakoshi , Takashi Inoue , Masaki Shimono
IPC分类号： C09J4/06 , C08F22/10 , C08K3/38 , C08L33/06
CPC分类号： C09J4/06
摘要： An adhesive for soft tissue comprising at least one member selected from (meth)acrylic esters each containing an acid anhydride group represented by the specific formula (I) and derivatives of the (meth)acrylic esters represented by the specific formula (Ia), a (meth)acylate, a poly(meth)acrylate derived from a (meth)acrylate and a polymerization initiator; and a kit of an adhesive for soft tissue, comprising containers and, placed therein, the above ingredients. The adhesive for soft tissue and kit thereof according to the present invention are advantageous in that when the adhesive is applied to a wound on a soft tissue, at least one member selected from the above (meth)acrylic esters represented by the formula (I) and/or the derivatives thereof represented by the formula (Ia) together with a (meth)acrylate, contained in the adhesive, polymerizes irrespective of the presence of blood or body fluid, so that the adhesive undergoes strong bonding (conjugation) with the soft tissue and that further, the adhesive ensures low cytotoxicity to thereby ensure effective utilization in the treatment of a wound on a soft tissue, especially an integument, of an organism.
摘要翻译：一种用于软组织的粘合剂，其包含选自（甲基）丙烯酸酯中的至少一种，各自含有由特定式（I）表示的酸酐基和由特定式（Ia）表示的（甲基）丙烯酸酯的衍生物，（甲基）丙烯酸酯，聚（甲基）丙烯酸酯衍生的聚（甲基）丙烯酸酯和聚合引发剂; 以及用于软组织的粘合剂套件，其包含容器并且放置在其中的上述成分。根据本发明的软组织粘合剂及其试剂盒的优点在于，当将粘合剂施加到软组织上的伤口时，选自由式（I）表示的上述（甲基）丙烯酸酯中的至少一种，和/或其由式（Ia）表示的衍生物与粘合剂中所含的（甲基）丙烯酸酯一起聚合，而不管血液或体液的存在如何，使得粘合剂与柔软的粘合剂（共轭）并且进一步地，粘合剂确保低细胞毒性，从而确保有效利用在生物体的软组织，特别是皮肤上的伤口的治疗。

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