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1. 发明授权

US5856431A Process and materials for inducing pre-tilt in liquid crystals and liquid crystal displays 失效
标题翻译：用于在液晶和液晶显示器中诱发预倾角的工艺和材料
公开(公告)号：US5856431A
公开(公告)日：1999-01-05
申请号：US966161
申请日：1997-11-07
申请人： Wayne M. Gibbons , Paul J. Shannon , Shao-Tang Sun
发明人： Wayne M. Gibbons , Paul J. Shannon , Shao-Tang Sun
IPC分类号： C08G73/10 , G02F1/1337 , G02F1/13
CPC分类号： C08G73/10 , C08G73/1039 , C08G73/1085 , G02F1/133723 , G02F1/133788 , Y10T428/1018 , Y10T428/1023 , Y10T428/1027 , Y10T428/31721
摘要： A process for inducing pre-tilt in alignment of a liquid crystal medium comprising exposing at least one optical alignment layer, comprising anisotropically absorbing molecules and hydrophobic moieties, to polarized light; the polarized light having a wavelength within the absorption band of said anisotropically absorbing molecules; wherein the exposed anisotropically absorbing molecules induce alignment of the liquid crystal medium at an angle + and -.theta. with respect to the direction of the polarization of the incident light beam and along the surface of the optical alignment layer, and induce a pre-tilt at an angle .PHI. with respect to the surface of the optical alignment layer and applying a liquid crystal medium to said optical alignment layer, is described. The invention also is directed to liquid crystal display elements made by the process of the invention and to novel polyimide compositions that are useful as optical alignment layers in the invention.
摘要翻译：用于诱导液晶介质对准的预倾斜的方法，包括将包含各向异性吸收分子和疏水部分的至少一个光学取向层暴露于偏振光; 所述偏振光具有在所述各向异性吸收分子的吸收带内的波长; 其中所述暴露的各向异性吸收分子相对于所述入射光束的偏振方向和沿着所述光学取向层的表面以角度+和 - θ的角度引起所述液晶介质的对准，并且引起所述液晶介质的预倾斜描述了相对于光学取向层的表面的角度PHI并将液晶介质施加到所述光学取向层。本发明还涉及通过本发明的方法制备的液晶显示元件和可用作本发明中的光学取向层的新型聚酰亚胺组合物。

2. 发明授权

US5714304A Nonlinear optical media of organosilicon crosslinked polymer 失效
标题翻译：有机硅交联聚合物的非线性光学介质
公开(公告)号：US5714304A
公开(公告)日：1998-02-03
申请号：US458412
申请日：1995-06-02
申请人： Wayne M. Gibbons , Robert Paul Grasso , Michael Kevin O'Brien , Paul Joseph Shannon , Shao-Tang Sun
发明人： Wayne M. Gibbons , Robert Paul Grasso , Michael Kevin O'Brien , Paul Joseph Shannon , Shao-Tang Sun
IPC分类号： C08G77/06 , C08G77/38 , C08G77/50 , C08L83/14 , C09B23/14 , C09B29/01 , C09B31/043 , C09B51/00 , C09B69/10 , G02F1/35 , G02F1/355 , G02F1/361 , G03F7/075 , G03C1/492 , G02B6/10 , G03C1/494 , G03C1/725 , G03C1/76
CPC分类号： G02F1/3619 , C08G77/50 , C08L83/14 , C09B23/148 , C09B29/0003 , C09B31/043 , C09B51/00 , C09B69/10 , G02F1/3617 , Y10T428/1014 , Y10T428/31663
摘要： Organosilicon polymers, including crosslinked polymers and crosslinkable prepolymers, of cyclic polysiloxanes, organic dyes, and, optionally, polyenes. The dyes include those with delocalized Pi electron systems linking electron donor groups and electron acceptor groups, and with at least two carbon--carbon double bond-containing pendant groups attached to at least two different sites from among the indicated delocalized Pi electron systems, donor groups, and acceptor groups.
摘要翻译：有机硅聚合物，包括交联聚合物和可交联预聚物，环状聚硅氧烷，有机染料和任选的多烯。染料包括具有连接电子给体基团和电子受体基团的离域Pi电子系统的染料，以及连接至所指示的离域Pi电子系统中的至少两个不同位点的至少两个含碳 - 碳双键的侧基，供体基团和受体组。

3. 发明授权

US5073294A Process of preparing compositions having multiple oriented mesogens 失效
标题翻译：制备具有多个靶向成分的组合物的方法
公开(公告)号：US5073294A
公开(公告)日：1991-12-17
申请号：US605724
申请日：1990-10-29
申请人： Paul J. Shannon , Shao-Tang Sun , Brian J. Swetlin
发明人： Paul J. Shannon , Shao-Tang Sun , Brian J. Swetlin
IPC分类号： C08F2/00 , C07C255/54 , C07C255/55 , C08F2/48 , C08F20/26 , C08F20/30 , C08F20/34 , C08F20/36 , C08F20/38 , C08F220/36 , C09K19/12 , C09K19/20 , C09K19/22 , C09K19/38 , G02F1/1337
CPC分类号： C09K19/38 , C07C255/54 , C07C255/55 , C09K19/12 , C09K19/2007 , C09K19/3852 , G02F1/133711 , C09K2019/0448 , G02F1/133788 , G02F2001/133757 , G02F2001/133765
摘要： A liquid crystal polymer film or fiber comprising polymeric liquid crystals having aligned multiple oriented mesogens and a process for preparing such a polymeric liquid crystal film or fiber comprising aligning in a multi-oriented state a nematic or smectic monomeric mesophase (liquid crystal monomer) and photopolymerizing the mesophase, are disclosed. The film or fiber may be adhered to a substrate, part of a liquid crystal display cell, or a free standing polymeric film or fiber. According to a preferred process, the mesophase is aligned in a multi-oriented state using linearly polarized light.

4. 发明授权

US5965691A Materials for aligning liquid crystals 失效
标题翻译：液晶校准材料
公开(公告)号：US5965691A
公开(公告)日：1999-10-12
申请号：US886560
申请日：1997-07-01
申请人： Wayne M. Gibbons , Paul J. Shannon , Shao-Tang Sun
发明人： Wayne M. Gibbons , Paul J. Shannon , Shao-Tang Sun
IPC分类号： C08G73/10 , G02F1/1337 , C08G69/26
CPC分类号： C08G73/1042 , C08G73/10 , C08G73/1039 , C08G73/1085 , G02F1/133723 , G02F1/133753 , G02F1/133788 , G02F2001/133742 , Y10S359/90 , Y10T428/1005 , Y10T428/1018 , Y10T428/1023 , Y10T428/31721
摘要： A process for aligning liquid crystals adjacent to a surface of an optical alignment layer comprising: exposing at least one optical alignment layer, comprising anisotropically absorbing molecules, to polarized light; the polarized light having a wavelength within the absorption band of said anisotropically absorbing molecules; wherein the exposed anisotropically absorbing molecules induce alignment of a liquid crystal medium at an angle + and - with respect to the direction of the polarization of the incident light beam and along the surface of the optical alignment layer; and applying a liquid crystal medium to said optical alignment layer; wherein said anisotropically absorbing molecules consist essentially of diaryl ketones, is described. The invention also is directed to a liquid crystal optical storage medium, a liquid crystal display element, and a liquid crystal diffractive optical element made by the process of the invention and to novel polyimide compositions that are useful as optical alignment layers in the process of the invention.
摘要翻译：一种用于使与液晶相邻的光学取向层的表面对准的方法，包括：将至少一个包括各向异性吸收分子的光学取向层暴露于偏振光; 所述偏振光具有在所述各向异性吸收分子的吸收带内的波长; 其中所述暴露的各向异性吸收分子相对于所述入射光束的偏振方向和沿着所述光学取向层的表面以+和 - 的角度引起液晶介质的对准; 以及向所述光取向层施加液晶介质; 其中所述的各向异性吸收分子基本上由二芳基酮组成。本发明还涉及通过本发明的方法制造的液晶光学存储介质，液晶显示元件和液晶衍射光学元件，以及在该方法中可用作光学取向层的新型聚酰亚胺组合物发明。

5. 发明授权

US5929201A Fluorinated amine products 失效
标题翻译：氟化胺产品
公开(公告)号：US5929201A
公开(公告)日：1999-07-27
申请号：US859403
申请日：1997-05-20
申请人： Wayne M. Gibbons , Paul J. Shannon , Shao-Tang Sun
发明人： Wayne M. Gibbons , Paul J. Shannon , Shao-Tang Sun
IPC分类号： C08G73/10 , G02F1/1337 , C08G69/26 , G02F1/13
CPC分类号： G02F1/133788 , C08G73/10 , C08G73/1039 , C08G73/1085 , G02F1/133723
摘要： The present invention relates to amine compositions and the preparation of polyimides. The polyimides can be used for inducing alignment of a liquid crystal medium with polarized light and liquid crystal display elements.
摘要翻译：本发明涉及胺组合物和聚酰亚胺的制备。聚酰亚胺可用于诱导液晶介质与偏振光和液晶显示元件的对准。

6. 发明授权

US5846452A Liquid crystal optical storage medium with gray scale 失效
标题翻译：具有灰度级的液晶光存储介质
公开(公告)号：US5846452A
公开(公告)日：1998-12-08
申请号：US417610
申请日：1995-04-06
申请人： Wayne M. Gibbons , Scott T. Schnelle , Paul J. Shannon , Shao-Tang Sun
发明人： Wayne M. Gibbons , Scott T. Schnelle , Paul J. Shannon , Shao-Tang Sun
IPC分类号： G02F1/13 , C08F20/30 , C08F20/36 , C09K19/38 , G02F1/1337 , G11B7/0055 , G11B7/24 , G11B7/25 , C09K19/56
CPC分类号： G11B7/00555 , G02F1/133753 , G11B7/25 , G02F1/133788 , Y10T428/1059
摘要： An optical storage medium with gray scale capability comprising: a plurality of facing substrates in series; alignment layers disposed on one or both sides of the substrates to give alignment layer pair(s) wherein at least one of the alignment layers of each of the alignment layer pair(s) is an optical alignment layer, and wherein the optical alignment layer(s) comprise anisotropically absorbing molecules or moieties; liquid crystal layers disposed between the alignment layer pair(s); wherein, each of the liquid crystal layer(s) comprises three or more alignment regions having three or more different alignment states; and, wherein the different alignment states are controlled by exposure of optical alignment layer(s) with polarized light of a wavelength or wavelengths within the absorption band of the anisotropically absorbing molecules or moieties therein, is described. The invention is also directed to compact disc, erasable compact discs, photographic storage devices, and storage displays.
摘要翻译：一种具有灰度能力的光学存储介质，包括：串联的多个相对的基板; 对准层设置在基板的一侧或两侧以提供取向层对，其中每个取向层对的至少一个取向层是光学取向层，并且其中光学取向层（ s）包含各向异性吸收分子或部分; 设置在取向层对之间的液晶层; 其中，每个液晶层包括具有三个或更多个不同取向状态的三个或更多个取向区域; 并且其中通过用各向异性吸收分子或其部分的吸收带内的波长或波长的偏振光的光学取向层的曝光来控制不同的取向状态。本发明还涉及光盘，可擦除光盘，摄影存储设备和存储显示器。

7. 发明授权

US5298588A Organosilicon polymers, and dyes, exhibiting nonlinear optical response 失效
标题翻译：有机硅聚合物和染料显示非线性光学响应
公开(公告)号：US5298588A
公开(公告)日：1994-03-29
申请号：US96389
申请日：1993-07-26
申请人： Wayne M. Gibbons , Robert P. Grasso , Michael K. O'Brien , Paul J. Shannon , Shao-Tang Sun
发明人： Wayne M. Gibbons , Robert P. Grasso , Michael K. O'Brien , Paul J. Shannon , Shao-Tang Sun
IPC分类号： C08G77/06 , C08G77/38 , C08G77/50 , C08L83/14 , C09B23/14 , C09B29/01 , C09B31/043 , C09B51/00 , C09B69/10 , G02F1/35 , G02F1/355 , G02F1/361 , G03F7/075 , C08G77/08
CPC分类号： G02F1/3619 , C08G77/50 , C08L83/14 , C09B23/148 , C09B29/0003 , C09B31/043 , C09B51/00 , C09B69/10 , G02F1/3617 , Y10T428/1014 , Y10T428/31663
摘要： Organosilicon polymers, including crosslinked polymers and crosslinkable prepolymers, of cyclic polysiloxanes, organic dyes, and, optionally, polyenes. The dyes include those with delocalized Pi electron systems linking electron donor groups and electron acceptor groups, and with at least two carbon-carbon double bond-containing pendant groups attached to at least two different sites from among the indicated delocalized Pi electron systems, donor groups, and acceptor groups.
摘要翻译：有机硅聚合物，包括交联聚合物和可交联预聚物，环状聚硅氧烷，有机染料和任选的多烯。染料包括具有连接电子给体基团和电子受体基团的离域Pi电子系统的染料，以及连接至所指示的离域Pi电子系统中的至少两个不同位点的至少两个含碳 - 碳双键的侧基，供体基团和受体组。

8. 发明授权

US06200655B1 Process for materials for aligning liquid crystals and liquid crystal optical elements 失效
标题翻译：用于对准液晶和液晶光学元件的工艺和材料
公开(公告)号：US06200655B1
公开(公告)日：2001-03-13
申请号：US09238683
申请日：1999-01-25
申请人： Wayne M. Gibbons , Paul J. Shannon , Shao-Tang Sun
发明人： Wayne M. Gibbons , Paul J. Shannon , Shao-Tang Sun
IPC分类号： C09K1952
CPC分类号： C08G73/1042 , C08G73/10 , C08G73/1039 , C08G73/1085 , G02F1/133723 , G02F1/133753 , G02F1/133788 , G02F2001/133742 , Y10S359/90 , Y10T428/1005 , Y10T428/1018 , Y10T428/1023 , Y10T428/31721
摘要： A process for aligning liquid crystals adjacent to a surface of an optical alignment layer comprising: exposing at least one optical alignment layer, comprising anisotropically absorbing molecules, to polarized light; the polarized light having a wavelength within the absorption band of said anisotropically absorbing molecules; wherein the exposed anisotropically absorbing molecules induce alignment of a liquid crystal medium at an angle + and − with respect to the direction of the polarization of the incident light beam and along the surface of the optical alignment layer; and applying a liquid crystal medium to said optical alignment layer; wherein said anisotropically absorbing molecules consist essentially of diary ketones, is described. The invention also is directed to a liquid crystal optical storage medium, a liquid crystal display element, and a liquid crystal diffractive optical element made by the process of the invention and to novel polyimide compositions that are useful as optical alignment layers in the process of the invention.
摘要翻译：一种用于使与液晶相邻的光学取向层的表面对准的方法，包括：将至少一个包括各向异性吸收分子的光学取向层暴露于偏振光; 所述偏振光具有在所述各向异性吸收分子的吸收带内的波长; 其中所述暴露的各向异性吸收分子相对于所述入射光束的偏振方向和沿着所述光学取向层的表面以+和 - 的角度引起液晶介质的对准; 以及向所述光取向层施加液晶介质; 其中所述各向异性吸收分子基本上由日志组成。本发明还涉及通过本发明的方法制造的液晶光学存储介质，液晶显示元件和液晶衍射光学元件，以及在该方法中可用作光学取向层的新型聚酰亚胺组合物发明。

9. 发明授权

US5856430A Process and materials for inducing pre-tilt in liquid crystals and liquid crystal displays 失效
公开(公告)号：US5856430A
公开(公告)日：1999-01-05
申请号：US825609
申请日：1997-03-31
申请人： Wayne M. Gibbons , Paul J. Shannon , Shao-Tang Sun
发明人： Wayne M. Gibbons , Paul J. Shannon , Shao-Tang Sun
IPC分类号： C08G73/10 , G02F1/1337
CPC分类号： C08G73/10 , C08G73/1039 , C08G73/1085 , G02F1/133723 , G02F1/133788 , Y10T428/1018 , Y10T428/1023 , Y10T428/1027 , Y10T428/31721
摘要： A process for inducing pre-tilt in alignment of a liquid crystal medium comprising exposing at least one optical alignment layer, comprising anisotropically absorbing molecules and hydrophobic moieties, to polarized light; the polarized light having a wavelength within the absorption band of said anisotropically absorbing molecules; wherein the exposed anisotropically absorbing molecules induce alignment of the liquid crystal medium at an angle + and -.theta. with respect to the direction of the polarization of the incident light beam and along the surface of the optical alignment layer, and induce a pre-tilt at an angle .PHI. with respect to the surface of the optical alignment layer and applying a liquid crystal medium to said optical alignment layer, is described. The invention also is directed to liquid crystal display elements made by the process of the invention and to novel polyimide compositions that are useful as optical alignment layers in the invention.

10. 发明授权

US5807498A Process and materials for aligning liquid crystals and liquid crystal optical elements 失效
标题翻译：用于对准液晶和液晶光学元件的工艺和材料
公开(公告)号：US5807498A
公开(公告)日：1998-09-15
申请号：US624945
申请日：1996-03-29
申请人： Wayne M. Gibbons , Paul J. Shannon , Shao-Tang Sun
发明人： Wayne M. Gibbons , Paul J. Shannon , Shao-Tang Sun
IPC分类号： C08G73/10 , G02F1/1337 , C09K19/56 , C09K19/00 , C09K19/52
CPC分类号： C08G73/1042 , C08G73/10 , C08G73/1039 , C08G73/1085 , G02F1/133723 , G02F1/133753 , G02F1/133788 , G02F2001/133742 , Y10S359/90 , Y10T428/1005 , Y10T428/1018 , Y10T428/1023 , Y10T428/31721
摘要： A process for aligning liquid crystals adjacent to a surface of an optical alignment layer comprising: exposing at least one optical alignment layer, comprising anisotropically absorbing molecules, to polarized light; the polarized light having a wavelength within the absorption band of said anisotropically absorbing molecules; wherein the exposed anisotropically absorbing molecules induce alignment of a liquid crystal medium at an angle +and-.theta. with respect to the direction of the polarization of the incident light beam and along the surface of the optical alignment layer; and applying a liquid crystal medium to said optical alignment layer; wherein said anisotropically absorbing molecules consist essentially of diaryl ketones, is described. The invention also is directed to a liquid crystal optical storage medium, a liquid crystal display element, and a liquid crystal diffractive optical element made by the process of the invention and to novel polyimide compositions that are useful as optical alignment layers in the process of the invention.
摘要翻译：一种用于使与液晶相邻的光学取向层的表面对准的方法，包括：将至少一个包括各向异性吸收分子的光学取向层暴露于偏振光; 所述偏振光具有在所述各向异性吸收分子的吸收带内的波长; 其中所述暴露的各向异性吸收分子相对于所述入射光束的偏振方向并且沿着所述光学取向层的表面，以与角度θ成θ角的方向引起液晶介质的对准; 以及向所述光取向层施加液晶介质; 其中所述各向异性吸收分子基本上由二芳基酮组成。本发明还涉及通过本发明的方法制造的液晶光学存储介质，液晶显示元件和液晶衍射光学元件，以及在该方法中可用作光学取向层的新型聚酰亚胺组合物发明。

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