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    • 9. 发明授权
    • Thermoplastic molding material
    • 热塑性成型材料
    • US4788253A
    • 1988-11-29
    • US627
    • 1987-04-17
    • Juergen HambrechtBurghard SchmittJohann SwobodaGeorg WassmuthClaus BernhardRudolf Stephan
    • Juergen HambrechtBurghard SchmittJohann SwobodaGeorg WassmuthClaus BernhardRudolf Stephan
    • C08L25/08C08L25/12C08L51/00C08L33/08
    • C08L25/08C08L25/12C08L51/003C08L51/00
    • The invention relates to a thermoplastic molding material of an elastomeric polymer A, a shell B grafted to the polymer A, and a copolymer C as rigid matrix. The amount of polymer A is 1 to 25 percent by weight based on the weight of A+B+C. It has a glass transition temperature, Tg, of less than 0.degree. C. and an average particle size of 200 to 750 nanometers (d.sub.50 value of the integral mass distribution) and is composed of: 50 to 99.9 percent by weight of at least one alkylacrylate with 1 to 8 carbon atoms in the alkyl radical and 0.1 to 5 percent by weight of a polyfunctional monomer which has a crosslinking action. Grafting shell B represents 5 to 40 percent by weight based on A+B+C and is composed of at least one of the monomers of the group of(b.sub.1) vinylaromatic monomers, and(b.sub.2) the ethylenically unsaturated monomers.Grafting shell B is prepared in two stages with 30 to 70 percent by weight of the monomers b.sub.1 being used in the first stage, and 30 to 70 percent by weight of a mixture of monomers b.sub.1 and b.sub.2 in a weight ratio of 90:10 to 60:40 being used in the second stage.Copolymer C is added in an amount of 35 to 94 percent by weight based on A+B+C and consists of a vinylaromatic monomer and an ethylenically unsaturated monomer.The molding material may contain commonly used additives in effective amounts and is used for the preparation of molded parts.
    • 本发明涉及弹性体聚合物A的热塑性模塑材料,接枝到聚合物A上的壳B和作为刚性基质的共聚物C. 基于A + B + C的重量,聚合物A的量为1〜25重量%。 玻璃化转变温度Tg小于0℃,平均粒度为200〜750纳米(d50整体质量分布值),由以下组成:50〜99.9重量%的至少1个 在烷基中具有1至8个碳原子的丙烯酸烷基酯和具有交联作用的多官能单体0.1至5重量%。 接枝壳B以A + B + C为5〜40重量%,由(b1)乙烯基芳族单体组中的至少一种单体和(b2)烯属不饱和单体构成。 接枝壳B分两步制备,在第一阶段使用的单体b1为30〜70重量%,单体b1和b2的混合物的重量比为90:10〜30重量%,重量比为90:10〜 60:40在第二阶段使用。 共聚物C的添加量为35〜94重量%,基于A + B + C,由乙烯基芳族单体和烯属不饱和单体构成。 成型材料可以含有有效量的常用添加剂,并用于制备模制件。