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1. 发明授权

US4288607A Bis-carbalkoxy compounds and their preparation 失效
标题翻译：双 - 烷氧基化合物及其制备方法
公开(公告)号：US4288607A
公开(公告)日：1981-09-08
申请号：US19944
申请日：1979-03-12
申请人： Gerhard Bier , Dagmar Kottek , Egon N. Petersen , Hermann Richtzenhain , Norbert Vollkommer
发明人： Gerhard Bier , Dagmar Kottek , Egon N. Petersen , Hermann Richtzenhain , Norbert Vollkommer
IPC分类号： C08L67/00 , C07C67/00 , C07C69/80 , C07C69/92 , C07C313/00 , C07C315/04 , C07C317/22 , C08G63/00 , C08G63/676 , C08G63/68 , C08G63/682 , C08K5/00 , C08L67/06 , C07C147/107
CPC分类号： C08K5/0066 , C07C317/22 , C07C69/92 , C08G63/676 , C08G63/6826 , C08G63/6828
摘要： The invention relates to halogenous polyesters with the recurrent general formula ##STR1## in which at least part of the R's, e.g. 1 to 100 mole-%, preferably 100 mole-%, or 2 to 10 mole-%, are of the general formulas ##STR2## and 0 to 99 mole-%, preferably 0 or 90 to 98 mole-%, of the R's correspond to a phenylene radical and/or a naphthylene radical and/or an alkylene radical of 3 to 10 carbon atoms and/or a cycloalkylene radical, and the R's represent an organic moiety which is contained in bivalent saturated alcohols and corresponds to a branched or unbranched saturated alkylene radical of 2 to 10 carbon atoms and/or to a cycloalkylene radical and/or which is derived from an alkyleneterephthalate containing hydroxyl groups, preferably an oligomeric ethyleneterephthalate and/or an oligomeric propyleneterephthalate and/or an oligomeric butyleneterephthalate, wherein Z represents the groups ##STR3## and X represents hydrogen, bromine or chlorine, wherein at least some of the X's are bromine or chlorine, and in which polyesters, in some cases, a portion of the R's are residues of unsaturated dicarboxylic acid derivatives which, together with ethylenically unsaturated comonomers, preferably styrene, are capable of forming peroxide-curable unsaturated polyester resin (UP resin) solutions, and their preparation as well as their use as fire-retardant molding compositions or articles, and also dicarboxylic acid esters some of which can be used in the preparation of the polyesters as well as the preparation of these dicarboxylic acid esters. Preferably the xylene nucleus in (2) is substituted by Br.sub.4.0 to 2.8 and Cl.sub.0 to 1.2.
摘要翻译：本发明涉及具有复发性通式“IMAGE”的卤代聚酯，其中R的至少一部分，例如， 1至100摩尔％，优选100摩尔％或2至10摩尔％的通式为通式（1）和/或（IMAGE）（2）和0至99摩尔％ 0或90至98摩尔％的R对应于亚苯基和/或亚萘基和/或具有3至10个碳原子的亚烷基和/或亚环烷基，并且R代表有机部分，其中包含在二价饱和醇中，并且对应于具有2-10个碳原子的支链或非支链的饱和亚烷基和/或环亚烷基和/或衍生自含有羟基的亚烷基对苯二甲酸酯，优选低聚对苯二甲酸乙二醇酯和/或低聚对苯二甲酸丙二酯和/或低聚对苯二甲酸丁二醇酯，其中Z表示基团，X表示氢，溴或氯，其中至少一些X是溴或氯，并且其中聚酯在一些情况下， R是不饱和d的残基与烯键式不饱和共聚单体，优选苯乙烯一起形成过氧化物可固化的不饱和聚酯树脂（UP树脂）溶液及其制备以及它们作为阻燃成型组合物或制品的用途的二羧酸衍生物，以及二羧酸酸酯，其中一些可用于制备聚酯以及这些二羧酸酯的制备。优选（2）中的二甲苯核被Br4.0至2.8和Cl0至1.2取代。

2. 发明授权

US4224234A Method for preparation of orthosilicic acid tetraalkyl esters 失效
标题翻译：正硅酸四烷基酯的制备方法
公开(公告)号：US4224234A
公开(公告)日：1980-09-23
申请号：US30499
申请日：1979-04-16
申请人： Wilhelm Flick , Hermann Richtzenhain , Volker Hunger , Wilhelm Joch
发明人： Wilhelm Flick , Hermann Richtzenhain , Volker Hunger , Wilhelm Joch
IPC分类号： B01J31/00 , C07F7/04
CPC分类号： C07F7/045
摘要： An improvement in the preparation of orthosilicic acid tetraalkyl esters by reaction of metallic silicon with alcohol in the presence of alkali alcoholate is disclosed, the improvement residing in carrying out the reaction in the co-presence of an ether alcohol or alkanolamine as cocatalyst.
摘要翻译：公开了在碱金属醇盐存在下通过金属硅与醇的反应制备正硅酸四烷基酯的改进，其中在醚醇或链烷醇胺作为助催化剂的共存下进行反应的改进。

3. 发明授权

US4059618A Tetrahalogen xylylene diacrylates, tetrahalogen xylyl acrylates, pentahalogen benzyl acrylates, and substituted acrylates 失效
标题翻译：四卤代苯二甲基二丙烯酸酯，四卤代二甲苯基丙烯酸酯，戊哈拉伯苄基丙烯酸酯和取代的丙烯酸酯
公开(公告)号：US4059618A
公开(公告)日：1977-11-22
申请号：US589958
申请日：1975-06-24
申请人： Georg Blumenfeld , Hermann Richtzenhain , Wilhelm Vogt , Norbert Volkommer
发明人： Georg Blumenfeld , Hermann Richtzenhain , Wilhelm Vogt , Norbert Volkommer
IPC分类号： C07C67/08 , A01N37/06 , C07C69/653 , C07C69/54
CPC分类号： C07C69/653
摘要： Compounds of the formula: ##STR1## WHEREIN: EACH X is chloro or bromoY is methyl or bromon is 0 or 1Each of R and R' is hydrogen or methyl.The compounds are produced by contacting an alkali salt of R'--(CH.dbd.C(R)--COOH with tetrahalogen xylene chloride or xylylene dichloride or pentabromobenzylchloride in a polar solvent. The compounds are useful as comonomers and as cross linking agents in polymerization of unsaturated compounds.
摘要翻译：下式的化合物： WHEREIN：

4. 发明授权

US3932535A Process for the preparation of 2,2-bis-(4-hydroxy-3-chlorophenyl)-propane 失效
标题翻译：制备2,2-双 - （4-羟基-3-氯苯基） - 丙烷的方法
公开(公告)号：US3932535A
公开(公告)日：1976-01-13
申请号：US442939
申请日：1974-02-15
申请人： Gunter Zoche , Hermann Richtzenhain , Roshdy Ismail
发明人： Gunter Zoche , Hermann Richtzenhain , Roshdy Ismail
IPC分类号： C07C37/62 , C07C39/367 , C08G63/682 , C07C37/22
CPC分类号： C07C37/62 , C07C37/84 , C08G63/6826
摘要： Process for the preparation of especially pure 2,2-bis-(4-hydroxy-3-chlorophenyl)-propane (dichlordiane, DCD) by the chlorination of 2,2-bis-(4-hydroxyphenyl)-propane in the presence of solvents that are substantially indifferent to chlorine by prior-art methods; then, for purification, the chlorinated bis-phenol is dissolved in halogenated hydrocarbons and/or halogenated hydrocarbon in which are liquid at 20.degree.C which they are readily soluble in the absence of an aqueous phase but in which they are at most only slightly soluble after the addition of water thereto; and the 2,2-bis-(4-hydroxy-3-chlorophenyl)-propane, is thereby precipitated from this aqueous solution.
摘要翻译：通过2,2-双 - （4-羟基苯基） - 丙烷的氯化，在存在下制备特别纯的2,2-双 - （4-羟基-3-氯苯基） - 丙烷（二氯代，DCD）的方法通过现有技术方法基本上对氯无关的溶剂; 然后，为了净化，氯化双酚溶解在20℃下为液态的卤代烃和/或卤代烃中，它们在不存在水相的情况下易于溶解，但其中它们最多仅仅是微溶的加水后; 和2,2-双 - （4-羟基-3-氯苯基） - 丙烷，由此从该水溶液中沉淀出来。

5. 发明授权

US4424375A Method and apparatus for performing carbonylation reactions 失效
标题翻译：用于进行羰基化反应的方法和装置
公开(公告)号：US4424375A
公开(公告)日：1984-01-03
申请号：US274108
申请日：1981-06-16
申请人： Moustafa El-Chahawi , Uwe Prange , Hermann Richtzenhain , Wilhelm Vogt
发明人： Moustafa El-Chahawi , Uwe Prange , Hermann Richtzenhain , Wilhelm Vogt
IPC分类号： C07C67/36 , B01F5/10 , B01J10/00 , C02F1/00 , C07C27/00 , C07C51/00 , C07C51/10 , C07C51/12 , C07C67/00 , C07C69/00 , C07C69/76
CPC分类号： C07C51/10
摘要： Improvement in the process of producing carboxylic acid esters or salts involving contacting a halogen alkyl compound with carbon monoxide and a basic substance in the presence of a carbonylation catalyst for carbonylation of the halogen alkyl and production of the corresponding ester or salt of the basic substance. The improvement involves performing the contacting in a reaction vessel, circulating a liquid mass of the halogen alkyl, basic substance and carbonylation catalyst through the vessel and maintaining a carbon monoxide atmosphere in the vessel, injecting the circulating liquid mass into the vessel with a nozzle to spray the liquid mass into the vessel and intimately mixing the liquid mass with carbon monoxide in the nozzle for injection of carbon monoxide into the vessel with the sprayed liquid mass.
摘要翻译：包括在羰基化羰基化催化剂存在下将卤代烷基化合物与一氧化碳和碱性物质接触的羧酸酯或盐的改进，用于羰基化卤代烷基和生成碱性物质的相应酯或盐。改进包括在反应容器中进行接触，使卤素烷基，碱性物质和羰基化催化剂的液体物质通过容器循环并保持容器中的一氧化碳气氛，将循环液体物质用喷嘴注入容器将液体物质喷射到容器中，并将液体物质与喷嘴中的一氧化碳充分混合，用喷射的液体物质将一氧化碳注射到容器中。

6. 发明授权

US4284732A Halogen-containing unsaturated bis-esters and polymers and copolymers based on these esters 失效
标题翻译：含卤素的不饱和双酯和基于这些酯的聚合物和共聚物
公开(公告)号：US4284732A
公开(公告)日：1981-08-18
申请号：US59091
申请日：1979-07-19
申请人： Egon N. Petersen , Norbert Vollkommer , Georg Blumfeld , Hermann Richtzenhain , Wilhelm Vogt
发明人： Egon N. Petersen , Norbert Vollkommer , Georg Blumfeld , Hermann Richtzenhain , Wilhelm Vogt
IPC分类号： C07C69/653 , C08F20/00 , C08F20/10 , C08F20/22 , C08F20/30 , C08F122/20 , C08L67/00 , C08L101/00 , C09K21/00 , C09K21/08 , C09K21/14 , C08L67/06 , C08F222/20
CPC分类号： C09K21/14 , C08F20/30 , C08L101/00 , C09K21/08 , Y10S260/24
摘要： Halogen-containing bis-acrylates and bis-methacrylates corresponding to the formula ##STR1## in which R represents hydrogen or a methyl group and X represents chlorine and/or bromine, are provided as well as a process for producing such compounds. The compounds are useful for the formation of polymers and copolymers and as cross-linking agents. Also included in the invention are the polymers and copolymers based on the above-described halogen-containing bis-acrylates and bis-methacrylates, methods for the production of said polymers and the use of said polymers as flame proofing agents, etc.
摘要翻译：提供了相应于式（1）的含卤素的双丙烯酸酯和双甲基丙烯酸酯，其中R表示氢或甲基，X表示氯和/或溴，以及制备此类化合物的方法。该化合物可用于形成聚合物和共聚物以及作为交联剂。本发明还包括基于上述含卤素的双丙烯酸酯和双甲基丙烯酸酯的聚合物和共聚物，所述聚合物的制备方法和所述聚合物作为防火剂等的用途。

7. 发明授权

US4156785A Method of preparing .alpha.,.beta.-unsaturated carboxylic acid esters 失效
标题翻译：制备{60，{62-不饱和羧酸酯
公开(公告)号：US4156785A
公开(公告)日：1979-05-29
申请号：US599913
申请日：1975-07-28
申请人： Uwe Prange , Hermann Richtzenhain , Wilhelm Vogt
发明人： Uwe Prange , Hermann Richtzenhain , Wilhelm Vogt
IPC分类号： C07C69/533 , B01J31/00 , C07B61/00 , C07C69/52 , C07C69/708
CPC分类号： C07C69/52
摘要： Process of preparing an .alpha.,.beta.-unsaturated carboxylic acid ester, comprising contacting an .alpha.,.beta.-unsaturated halogen compound with carbon monoxide, an alkali alcoholate in the presence of a metal carbonyl as catalyst, in an alcohol that is the basis of the alkali alcoholate, at a pH of 8.5-11.5. Thereby, for example, crotonic acid methyl ester can be produced from allyl chloride.
摘要翻译：制备α，β-不饱和羧酸酯的方法，包括在作为催化剂的金属羰基存在下，在作为碱的基础的醇中使α，β-不饱和卤素化合物与一氧化碳接触，碱金属醇化物醇化物，pH为8.5-11.5。因此，例如可以由烯丙基氯制造巴豆酸甲酯。

8. 发明授权

US4104300A Method of preparing carboxylic acid chlorides of the benzene series 失效
标题翻译：苯系列羧酸氯化物的制备方法
公开(公告)号：US4104300A
公开(公告)日：1978-08-01
申请号：US813595
申请日：1977-07-07
申请人： Gunter Zoche , Hermann Richtzenhain , Wilhelm Vogt
发明人： Gunter Zoche , Hermann Richtzenhain , Wilhelm Vogt
IPC分类号： C07C51/60 , C07C51/58
CPC分类号： C07C51/60
摘要： In a process for preparing substituted or unsubstituted carboxylic acid chlorides of the benzene series by contacting the corresponding carboxylic acid ester with an aromatic compound containing at least one nuclearly bound trichlormethyl group in the presence of a molybdenum catalyst, the improvement which comprises introducing into the reaction mixture prior to distillation of the carboxylic acid chloride a complexing agent which complexes with the molybdenum catalyst.
摘要翻译：在通过在钼催化剂的存在下使相应的羧酸酯与含有至少一个核结合的三氯甲基的芳族化合物接触来制备苯系列的取代或未取代的羧酸氯化物的方法，其包括引入反应在蒸馏羧酸氯化物之前的混合物是与钼催化剂复合的络合剂。

9. 发明授权

US4086237A Method of preparing 3-methyl pyridine 失效
标题翻译：制备3-甲基吡啶的方法
公开(公告)号：US4086237A
公开(公告)日：1978-04-25
申请号：US681100
申请日：1976-04-28
申请人： Gerhard Daum , Hermann Richtzenhain
发明人： Gerhard Daum , Hermann Richtzenhain
IPC分类号： C07D213/09 , C07D213/06 , C07D213/08 , C07D213/133 , C07D295/023
CPC分类号： C07D213/06 , C07D213/08 , C07D295/023
摘要： 3-METHYL PYRIDINE IS PRODUCED BY CATALYTIC, E.G. PALLADIUM, DEHYDROGENATION OF 2-METHYL-1,5-DIAMINOPENTANE OR A MIXTURE THEREOF WITH 3-METHYL PIPERIDINE, AT 200.degree.-400.degree. C.
摘要翻译： 3-甲基吡啶由催化剂，E.G. 钯，2-甲基-1,5-二氨基戊酸或其与3-甲基哌啶的混合物在200°-400℃下脱水

10. 发明授权

US4080378A Process for the preparation of carboxylic acid chlorides of the benzene series 失效
标题翻译：苯系列羧酸氯化物的制备方法
公开(公告)号：US4080378A
公开(公告)日：1978-03-21
申请号：US737368
申请日：1976-11-01
申请人： Gunter Zoche , Hermann Richtzenhain , Wilhelm Vogt
发明人： Gunter Zoche , Hermann Richtzenhain , Wilhelm Vogt
IPC分类号： C07C63/00 , B01J23/00 , C07B61/00 , C07C51/00 , C07C51/60 , C07C67/00 , C07C51/58
CPC分类号： C07C51/60
摘要： A process for preparing substituted or unsubstituted carboxylic acid chlorides of the benzene series which comprises contacting the corresponding carboxylic acid ester with an aromatic compound containing at least one nuclearly bound trichloromethyl group in the presence of a molybdenum catalyst.
摘要翻译：一种制备苯系列的取代或未取代的羧酸氯化物的方法，其包括在钼催化剂存在下使相应的羧酸酯与含有至少一个核结合的三氯甲基的芳族化合物接触。

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