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    • 2. 发明授权
    • High solids pigmented coating composition containing a blend of ester
diols and a curing agent
    • 含有酯二醇和固化剂的混合物的高固含量着色涂料组合物
    • US4279800A
    • 1981-07-21
    • US140482
    • 1980-04-15
    • Ritse E. BoomgaardRoelof ButerAleidus A. Kiffen
    • Ritse E. BoomgaardRoelof ButerAleidus A. Kiffen
    • C08G63/00C08G63/52C09D161/20C09D167/00C09D167/02C09D167/06C08L61/28C08L67/02
    • C09D161/20C09D167/02
    • A pigment-containing high solids coating composition is prepared from a blend of ester diols as binder and a curing agent for the binder, characterized in that as ester diol there is used a mixture of (a) 20-80 mole % of a compound having the general formula: ##STR1## where R.sub.1 represents the group formed by abstraction of the two carboxyl group from a cycloaliphatic and/or aromatic dicarboxylic acid having 8 to 20 carbon atoms and R.sub.2 and R.sub.3 may be the same or different and represent a hydrogen atom and/or a hydrocarbon group having 1 to 9 carbon atoms, and m is a number of 1-4, and of (b) 80-20 mole % of a compound having the general formula ##STR2## where R.sub.4 represents the group formed by abstraction of the two carboxyl groups from a cycloaliphatic and/or aromatic dicarboxylic acid having 8 to 20 carbon atoms, and R.sub.5 represents the group formed by abstraction of the two hydroxyl groups from a terminal diol having 4 to 12 carbon atoms in the main chain, and n is a number of 1-4.
    • 含有颜料的高固体涂料组合物由作为粘合剂的酯二醇和粘合剂用固化剂的共混物制备,其特征在于,作为酯二醇,使用(a)20-80摩尔%的具有 通式:其中R 1表示通过从具有8至20个碳原子的脂环族和/或芳族二羧酸取代两个羧基而形成的基团,R 2和R 3可以相同或不同,表示氢原子 和/或具有1至9个碳原子的烃基,m是1-4的数量,和(b)80-20摩尔%的具有通式“IMAGE”的化合物,其中R 4表示由 从具有8至20个碳原子的脂环族和/或芳族二羧酸的两个羧基取代,R5表示通过从主链中具有4至12个碳原子的末端二元醇取代两个羟基而形成的基团, n是1-4的数。
    • 3. 发明授权
    • High solids pigment coating composition
    • 高固体颜料涂料组合物
    • US4104240A
    • 1978-08-01
    • US749698
    • 1976-12-10
    • Roelof Buter
    • Roelof Buter
    • C09D201/00C09D5/46C09D167/00C09D167/02C08G37/30
    • C09D167/02
    • A high solids pigmented coating composition is prepared from a curing agent and an ester diol binder which is a mixture of(a) 20-80 mole % of a compound having the general formula: ##STR1## where R.sub.1 represents the group formed by abstraction of the two carboxyl groups from a cycloaliphatic and/or aromatic dicarboxylic acid having 8 to 20 carbon atoms and R.sub.2 and R.sub.3 may be the same or different and represent groups formed by abstraction of the two hydroxyl groups from a divalent alcohol having 2 to 12 carbon atoms, and m is a number of 1 - 3, and(b) 80-20 mole % of a compound having the general formula: ##STR2## where R.sub.4 represents the group formed by abstraction of the two carboxyl groups from an aliphatic dicarboxylic acid having 2 to 12 carbon atoms, and R.sub.5 and R.sub.6 may be the same or different and represent groups formed by abstraction of the two hydroxyl groups from a divalent alcohol having 2 to 12 carbon atoms, and n is a number of 1 - 3.
    • 由固化剂和酯二醇粘合剂制备高固体含量的着色涂料组合物,所述酯二醇粘合剂是(A)20-80%的具有一般公式的化合物的混合物:其中R 1表示通过 具有8至20个碳原子的脂环族和/或芳族二羧酸的两个羧基和R 2和R 3可以相同或不同,表示通过从具有2至12个碳原子的二元醇中提取两个羟基而形成的基团 ,和m为1〜3的数,和(B)80〜20%的具有通用化合物的化合物:其中R 4表示通过从具有 2至12个碳原子,并且R 5和R 6可以相同或不同,并且表示通过从具有2至12个碳原子的二价醇中夺取两个羟基而形成的基团,n为1-3的数。
    • 7. 发明授权
    • Dispersion stabilizer and polymeric aqueous dispersion prepared therefrom
    • 分散稳定剂和由其制备的聚合物水性分散体
    • US4857577A
    • 1989-08-15
    • US8680
    • 1987-01-28
    • Roelof Buter
    • Roelof Buter
    • C08L33/06C08F2/16C08F2/20C08F279/00C08F279/02C08L33/04C09D5/02C09D133/04
    • C08F279/02
    • The invention pertains to an aqueous dispersion of an acrylic polymer stabilized by a compound obtained by copolymerizing specific amounts of (1) styrene and/or methyl styrene, (2) (meth)acrylic acid and/or an amino group-containing (meth) acrylic ester, and optionally another comonomer, in the presence of a specific polybutadiene, the carboxylic acid groups and/or amino groups being at least partly ionized. The invention also pertains to a coating composition based on such aqueous dispersion and to a substrate coated with said coating composition. Finally, the invention also relates to a process for the preparation of the stabilizer of the aqueous dispersion of an acrylic polymer.
    • 本发明涉及通过将特定量的(1)苯乙烯和/或甲基苯乙烯,(2)(甲基)丙烯酸和/或含氨基的(甲基)丙烯酸酯共聚合得到的化合物稳定的丙烯酸类聚合物的水分散体。 丙烯酸酯和任选的另一种共聚单体,在特定的聚丁二烯的存在下,羧酸基团和/或氨基基团至少部分被电离。 本发明还涉及基于这种水分散体的涂料组合物和涂覆有所述涂料组合物的基材。 最后,本发明还涉及制备丙烯酸类聚合物的水分散体的稳定剂的方法。
    • 9. 发明授权
    • Pigment-containing coating composition having a high solids content
    • 含有固体含量高的含颜料的涂料组合物
    • US4271062A
    • 1981-06-02
    • US140574
    • 1980-04-15
    • Ritse E. BoomgaardRoelof ButerAleidus A. Kiffen
    • Ritse E. BoomgaardRoelof ButerAleidus A. Kiffen
    • C08G63/00C08F283/01C08F299/04C08G63/52C09D161/20C09D167/00C09D167/02C09D167/06C08K3/12C08L67/08
    • C09D161/20C09D167/02Y10T428/31681
    • A pigment-containing high solids coating composition is prepared from a curing agent and and ester diol which is a mixture of (a) 20-80 mole % of a compound having the general formula: ##STR1## where R.sub.1 represents the group formed by abstraction of the two carboxyl groups from maleic acid and/or fumaric acid and/or a cycloaliphatic and/or aromatic dicarboxylic acid having 8 to 20 carbon atoms and R.sub.2 and R.sub.3 may be the same or different and represent a hydrogen atom and/or a hydrocarbon group having 1 to 9 carbon atoms, and m is a number of 1-4, and of (b) 80-20 mole % of a compound having the general formula ##STR2## where R.sub.4 represents the group formed by abstraction of the two carboxyl groups from maleic acid and/or fumaric acid and/or a cycloaliphatic and/or aromatic dicarboxylic acid having 8 to 20 carbon atoms, and R.sub.5 represents the group formed by abstraction of 3 hydroxyl groups from a tri- or tetravalent hydroxy compound having 3 to 8 carbon atoms in the main chain, and X represents an aliphatic acyloxy group having 6-25 carbon atoms, and n is a number of 1-4.
    • 含有颜料的高固体涂料组合物由固化剂和酯二醇制备,酯二醇是(a)20-80摩尔%的具有以下通式的化合物的混合物:其中R 1表示 通过从马来酸和/或富马酸和/或具有8至20个碳原子的环脂族和/或芳族二羧酸和R 2和R 3取代两个羧基而形成的基团可以相同或不同,表示氢原子 和/或具有1至9个碳原子的烃基,m是1-4的数量,和(b)80-20摩尔%的具有通式“IMAGE”的化合物,其中R 4表示由 从具有8至20个碳原子的马来酸和/或富马酸和/或脂环族和/或芳族二羧酸的两个羧基取代两个羧基,R 5表示通过从三价或四价取代3个羟基而形成的基团 在主链中具有3至8个碳原子的羟基化合物,a d X表示碳原子数为6〜25的脂肪族酰氧基,n为1-4的数。