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1. 发明授权

US08603399B2 Integrated oxygenate conversion and product cracking 有权
标题翻译：综合含氧化合物转化和产物开裂
公开(公告)号：US08603399B2
公开(公告)日：2013-12-10
申请号：US12571841
申请日：2009-10-01
申请人： Tom N. Kalnes , Robert B. James, Jr. , Daniel H. Wei , Bryan K. Glover
发明人： Tom N. Kalnes , Robert B. James, Jr. , Daniel H. Wei , Bryan K. Glover
IPC分类号： B01J8/18
CPC分类号： C07C1/20 , C07C1/24 , C07C4/06 , C10G3/42 , C10G3/57 , C10G11/18 , C10G2400/20 , Y02P30/42 , Y02P30/48 , C07C11/02
摘要： An improved processing system of an oxygenate-containing feedstock for increased production or yield of light olefins. Such processing involves oxygenate conversion to olefins and subsequent cracking of heavier olefins wherein at least a portion of the products from each of the reactors is elevated in pressure, using a common compressor, prior to being routed to a common product fractionation and recovery section. The system further comprises acid gas removal means to remove acid gases from the cracked product gas and that the olefin cracking reactor is a moving bed reactor.
摘要翻译：含氧化合物原料的改进处理系统，用于提高轻质烯烃的生产或产率。这种处理涉及含氧化合物转化为烯烃并随后开裂较重的烯烃，其中使用普通的压缩机将来自每个反应器的产物的至少一部分在压力下升高，然后被送至共同的产物分馏和回收段。该系统还包括从裂化产物气体除去酸性气体的酸性气体去除装置，并且烯烃裂解反应器是移动床反应器。

2. 发明授权

US08414798B2 Processes and systems for producing syngas from methane 失效
标题翻译：从甲烷生产合成气的工艺和系统
公开(公告)号：US08414798B2
公开(公告)日：2013-04-09
申请号：US12917781
申请日：2010-11-02
申请人： Colleen Costello , Lisa King , Paul Barger , Deng-Yang Jen , Robert B. James , Kurt Vanden Bussche
发明人： Colleen Costello , Lisa King , Paul Barger , Deng-Yang Jen , Robert B. James , Kurt Vanden Bussche
IPC分类号： C01B3/38 , C01B3/24
CPC分类号： B01J8/26 , B01J23/002 , B01J35/0006 , B01J38/12 , B01J38/28 , B01J2523/00 , C01B3/38 , C01B3/42 , C01B2203/0261 , C01B2203/1041 , Y02P20/52 , Y02P20/584 , B01J2523/12 , B01J2523/24 , B01J2523/3706 , B01J2523/51 , B01J2523/842 , B01J2523/847
摘要： Embodiments of a process for producing syngas comprising hydrogen and carbon monoxide from a gas stream comprising methane are provided. The process comprises the step of contacting the gas stream with a two-component catalyst system comprising an apatite component and a perovskite component at reaction conditions effective to convert the methane to the syngas.
摘要翻译：提供了由包含甲烷的气流产生包含氢气和一氧化碳的合成气的方法的实施方案。该方法包括使气流与包含磷灰石组分和钙钛矿组分的双组分催化剂体系在有效将甲烷转化为合成气的反应条件下接触的步骤。

3. 发明申请

US20120104322A1 PROCESSES AND SYSTEMS FOR PRODUCING SYNGAS FROM METHANE 失效
标题翻译：从甲烷生产基本原理的方法和系统
公开(公告)号：US20120104322A1
公开(公告)日：2012-05-03
申请号：US12917781
申请日：2010-11-02
申请人： Colleen Costello , Lisa King , Paul Barger , Deng-Yang Jan , Robert B. James , Kurt Vanden Bussche
发明人： Colleen Costello , Lisa King , Paul Barger , Deng-Yang Jan , Robert B. James , Kurt Vanden Bussche
IPC分类号： C01B3/38 , B01J8/18 , B01J8/02
CPC分类号： B01J8/26 , B01J23/002 , B01J35/0006 , B01J38/12 , B01J38/28 , B01J2523/00 , C01B3/38 , C01B3/42 , C01B2203/0261 , C01B2203/1041 , Y02P20/52 , Y02P20/584 , B01J2523/12 , B01J2523/24 , B01J2523/3706 , B01J2523/51 , B01J2523/842 , B01J2523/847
摘要： Embodiments of a process for producing syngas comprising hydrogen and carbon monoxide from a gas stream comprising methane are provided. The process comprises the step of contacting the gas stream with a two-component catalyst system comprising an apatite component and a perovskite component at reaction conditions effective to convert the methane to the syngas.
摘要翻译：提供了由包含甲烷的气流产生包含氢气和一氧化碳的合成气的方法的实施方案。该方法包括使气流与包含磷灰石组分和钙钛矿组分的双组分催化剂体系在有效将甲烷转化为合成气的反应条件下接触的步骤。

4. 发明申请

US20100143225A1 Integrated Warm Gas Desulfurization and Gas Shift for Cleanup of Gaseous Streams 有权
标题翻译：集成的瓦斯气体脱硫和气体转换用于气体流的清理
公开(公告)号：US20100143225A1
公开(公告)日：2010-06-10
申请号：US12328496
申请日：2008-12-04
申请人： Manuela Serban , Tom N. Kalnes , Kurt M. Vanden Bussche , John P. Brady , Robert B. James, JR.
发明人： Manuela Serban , Tom N. Kalnes , Kurt M. Vanden Bussche , John P. Brady , Robert B. James, JR.
IPC分类号： B01D53/62
CPC分类号： B01D53/75 , B01D53/1456 , B01D53/58 , B01D53/64 , B01D53/8618 , B01D53/864 , B01D2256/16 , B01D2257/304 , B01D2257/308 , B01D2257/406 , B01D2257/408 , B01D2257/502 , B01D2257/504 , B01D2257/602 , B01D2257/706 , B01D2259/4009 , C01B3/16 , C01B3/56 , C01B2203/0288 , C01B2203/0415 , C01B2203/045 , C01B2203/0475 , C01B2203/0485 , C01B2203/82 , C01B2203/84 , Y02C10/04 , Y02P20/152
摘要： The present invention involves a catalytic process for purifying a gas stream comprising purifying the gas stream at a temperature from about 250° to 550° C. by removing sulfur compounds and including a gas shift reaction to convert carbon monoxide to carbon dioxide to produce a partially purified gas stream. The warm gas stream purification involves COS hydrolysis and hydrogenation to H2S, the removal of H2S, and a CO gas shift to convert CO to CO2 to produce a partially purified stream. Then the carbon dioxide and other impurities are removed from the partially purified gas stream.
摘要翻译：本发明涉及用于纯化气流的催化方法，其包括在约250℃至550℃的温度下净化气流，通过除去硫化合物并包括气体转换反应将一氧化碳转化为二氧化碳以产生部分净化气流。温暖的气体流净化涉及COS水解和氢化至H 2 S，除去H 2 S和CO气体转移以将CO转化为CO 2以产生部分纯化的流。然后从部分纯化的气流中除去二氧化碳和其它杂质。

5. 发明授权

US07687671B2 Integrated oxygenate conversion and product cracking 有权
标题翻译：综合含氧化合物转化和产物开裂
公开(公告)号：US07687671B2
公开(公告)日：2010-03-30
申请号：US11293934
申请日：2005-12-05
申请人： Tom N. Kalnes , Robert B. James, Jr. , Daniel H. Wei , Bryan K. Glover
发明人： Tom N. Kalnes , Robert B. James, Jr. , Daniel H. Wei , Bryan K. Glover
IPC分类号： C07C1/00
CPC分类号： C07C1/20 , C07C1/24 , C07C4/06 , C10G3/42 , C10G3/57 , C10G11/18 , C10G2400/20 , Y02P30/42 , Y02P30/48 , C07C11/02
摘要： Improved processing of an oxygenate-containing feedstock for increased production or yield of light olefins. Such processing involves oxygenate conversion to olefins and subsequent cracking of heavier olefins wherein at least a portion of the products from each of the reactors is elevated in pressure, using a common compressor, prior to being routed to a common product fractionation and recovery section. In one particular embodiment, the cracked product gas can be treated to remove acid gas therefrom. In another embodiment, the olefin cracking reactor is a moving bed reactor.
摘要翻译：改进含氧化合物原料的加工，以提高轻质烯烃的生产或产率。这种处理涉及含氧化合物转化为烯烃并随后开裂较重的烯烃，其中使用普通的压缩机将来自每个反应器的产物的至少一部分在压力下升高，然后被送至共同的产物分馏和回收段。在一个具体实施方案中，可以处理裂化产物气体以从其中除去酸性气体。在另一个实施方案中，烯烃裂解反应器是移动床反应器。

6. 发明申请

US20100061902A1 Metal-Based Coatings for Inhibiting Metal Catalyed Coke Formation in Hydrocarbon Conversion Processes 有权
标题翻译：用于在烃转化过程中抑制金属催化焦炭形成的金属基涂料
公开(公告)号：US20100061902A1
公开(公告)日：2010-03-11
申请号：US12205290
申请日：2008-09-05
申请人： Steven A. Bradley , Robert B. James, JR. , David W. Alley
发明人： Steven A. Bradley , Robert B. James, JR. , David W. Alley
IPC分类号： B01J19/02 , B05D3/02 , B32B15/04
CPC分类号： C23C30/00 , B01J19/0026 , B01J19/02 , B01J2219/0236 , B01J2219/024 , C23C4/06 , C23C4/08 , C23C26/00 , Y10T428/12736 , Y10T428/12847 , Y10T428/12944
摘要： A coating applied to at least a portion of the surfaces of reactors, reactor internals, other reactor components, and/or heater tubes is provided in order to minimize the formation of metal catalyzed coke in hydrocarbon conversion processes operating at temperatures at about 350° C. (662° F.) or greater and in reducing environments. These coatings may comprise Nickel coatings or complexes thereof, such as Ni—Al, Ni—Cr/Cr carbide, as well as aluminum painted coatings that are applied in a reduction cure process (e.g., application temperatures of about 600° C. (1112° F.)). Additionally, where H2S is necessary for the process, such as to minimize thermal cracking, the coatings also reduce corrosion of base metal due to sulfidation attack and eliminate the requirement of continuous replacement of reactor internals and other components.
摘要翻译：提供了施加到反应器，反应器内部件，其他反应器部件和/或加热器管的表面的至少一部分的涂层，以便最小化在约350℃的温度下操作的烃转化过程中金属催化焦炭的形成（662°F）或更大，并且在还原环境中。这些涂层可以包括镍涂层或其复合物，例如Ni-Al，Ni-Cr / Cr碳化物，以及以还原固化过程（例如，约600℃的应用温度（1112） F。））。另外，如果H2S对于该方法是必需的，例如最小化热裂解，则涂层还可以减少由于硫化作用引起的贱金属的腐蚀，并消除对反应器内部件和其它部件的连续更换的要求。

7. 发明授权

US07638040B2 Process for upgrading contaminated hydrocarbons 有权
标题翻译：改造受污染碳氢化合物的工艺
公开(公告)号：US07638040B2
公开(公告)日：2009-12-29
申请号：US11770826
申请日：2007-06-29
申请人： Mark Van Wees , Robert B. James, Jr. , Tom N. Kalnes , Gavin P. Towler
发明人： Mark Van Wees , Robert B. James, Jr. , Tom N. Kalnes , Gavin P. Towler
IPC分类号： C10G11/20
CPC分类号： C10M175/0041 , C10G7/003 , C10G7/006 , C10G45/02 , C10G45/44 , C10G2300/1003
摘要： A process for the recovery and purification of a contaminated hydrocarbons, wherein the contamination includes metals, finely divided solids and non-distillable components. The process further includes hydroprocessing the oil to remove deleterious compounds, to produce high quality reusable lubricants, solvents and fuels and to improve the quality of water byproduct.
摘要翻译：用于回收和净化污染的碳氢化合物的方法，其中污染物包括金属，细碎固体和不可蒸馏组分。该方法还包括加氢处理油以除去有害化合物，生产高品质的可重复使用的润滑剂，溶剂和燃料，并提高水副产物的质量。

8. 发明授权

US5244565A Integrated process for the production of distillate hydrocarbon 失效
标题翻译：生产馏出油的综合工艺
公开(公告)号：US5244565A
公开(公告)日：1993-09-14
申请号：US813522
申请日：1991-12-26
申请人： Steven P. Lankton , Tom N. Kalnes , Robert B. James, Jr.
发明人： Steven P. Lankton , Tom N. Kalnes , Robert B. James, Jr.
IPC分类号： C10G65/00
CPC分类号： C10G65/00
摘要： A process for the production of distillate hydrocarbon from atmospheric fractionation residue and waste lubricants by means of contacting the waste lubricant with a hot hydrogen-rich gaseous stream to increase the temperature of this feed stream to vaporize at least a portion of the distillable hydrocarbonaceous compounds thereby producing a distillable hydrocarbonaceous stream which is immediately hydrogenated in an integrated hydrogenation zone. The vaporization of the waste oil is also conducted in the presence of a vacuum fractionation residue which is produced in the integrated process. The resulting effluent from the integrated hydrogenation zone and a distillable hydrocarbon stream recovered from the atmospheric fraction residue is catalytically converted to produce lower molecular weight hydrocarbon compounds.
摘要翻译：通过使废润滑剂与富含氢气的气态流接触以提高该进料流的温度以蒸发至少一部分可蒸馏烃类化合物，从大气馏分残余物和废润滑剂生产馏出物烃的方法，由此产生可在一体化的氢化区中立即氢化的可蒸馏烃物流。废油的汽化也是在一体化过程中产生的真空分馏残渣的存在下进行的。来自整体氢化区的所得流出物和从大气馏分残余物回收的可馏出烃流被催化转化以产生较低分子量的烃化合物。

9. 发明授权

US5176816A Process to produce a hydrogenated distillable hydrocarbonaceous product 失效
标题翻译：生产氢化蒸馏烃类产品的方法
公开(公告)号：US5176816A
公开(公告)日：1993-01-05
申请号：US862146
申请日：1992-04-02
申请人： Steven P. Lankton , Robert B. James, Jr.
发明人： Steven P. Lankton , Robert B. James, Jr.
IPC分类号： C10G45/02 , C10G49/22
CPC分类号： C10G49/22 , C10G45/02
摘要： An integrated process for the production of a hydrogenated distillable hydrocarbonaceous product from a temperature-sensitive hydrocarbonaceous stream containing a non-distillable component by the utilization of a hot hydrogen flash zone and a secondary separation zone to achieve a high yield of hydrogenated distillable hydrocarbonaceous product.
摘要翻译：一种用于通过利用热氢闪蒸区和二次分离区从含有不可蒸馏组分的温度敏感烃流产生氢化可蒸馏烃产物以实现高产率的氢化可蒸馏烃类产物的综合方法。

10. 发明授权

US4895995A Process for the simultaneous hydroconversion of a first feedstock comprising unsaturated, halogenated organic compounds and a second feedstock comprising saturated, halogenated organic compounds 失效
标题翻译：用于同时加氢转化包含不饱和卤代有机化合物的第一原料和包含饱和卤代有机化合物的第二原料的方法
公开(公告)号：US4895995A
公开(公告)日：1990-01-23
申请号：US278991
申请日：1988-12-02
申请人： Robert B. James, Jr. , Tom N. Kalnes
发明人： Robert B. James, Jr. , Tom N. Kalnes
IPC分类号： A62D3/00 , A62D3/37 , A62D101/22 , B01J23/44 , C07B61/00 , C07C1/26 , C07C5/03 , C07C9/00 , C07C9/08 , C07C17/00 , C10G1/00
CPC分类号： A62D3/37 , C07C1/26 , A62D2101/22 , A62D2203/02 , A62D2203/10 , C07C2521/04 , C07C2523/44
摘要： A process for the simultaneous hydroconversion of a first feestock comprising unsaturated, halogenated organic compounds and a second feedstock comprising saturated, halogenated organic compounds which process comprises: (a) contacting the first feedstock comprising unsaturated, halogenated organic compounds with hydrogen in a first hydrogenation reaction zone (b) contacting at least a portion of the first hydrogenated stream and the second feedstock comprising saturated, halogenated organic compounds with hydrogen in a second hydrogenation reaction zone; (c) contacting the resulting effluent from the second hydrogenation zone comprising hydrogenated hydrocarbonaceous compounds, residual trace quantities of halogenated organic compounds, a hydrogen-rich gas and at least one water-soluble hydrogen halide compound with a halide-lean absorber solution in an absorption zone; (d) withdrawing a halide-rich absorber solution containing at least a portion of the water-soluble hydrogen halide compound from the absorption zone; (e) withdrawing a stream comprising hydrogenated hydrocarbonaceous compounds, the residual trace quantities of halogenated organic compounds and a hydrogen-rich gas from the absorption zone; (f) introducing the stream recovered in step (e) into a third hydrogenation reaction zone; (g) contacting the third hydrogenated stream with a halide-lean aqueous scrubbing solution; and (h) introducing a resulting admixture from step (g) into a separation zone.
摘要翻译：一种用于同时加氢转化含有不饱和卤代有机化合物和包含饱和卤代有机化合物的第二原料的方法，该方法包括：（a）在第一氢化反应中使包含不饱和卤代有机化合物的第一原料与氢接触区域（b）在第二加氢反应区中使至少一部分第一氢化物流和包含饱和卤代有机化合物的第二原料与氢接触; （c）使来自包含氢化烃化合物的第二氢化区，残余痕量的卤代有机化合物，富氢气体和至少一种水溶性卤化氢化合物的所得流出物与吸收剂中的贫卤素吸收剂溶液接触区; （d）从吸收区取出含有至少一部分水溶性卤化氢化合物的富卤化物吸收剂溶液; （e）从吸收区取出含有氢化烃类化合物的物流，剩余痕量的卤代有机化合物和富氢气体; （f）将步骤（e）中回收的物流引入第三加氢反应区; （g）使第三氢化物流与卤化物贫含水洗涤溶液接触; 和（h）将所得到的步骤（g）的混合物引入分离区。

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