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1. 发明申请

US20100010110A1 POLYURETHANE FOAMS MADE FROM HYDROXYMETHYL-CONTAINING POLYESTER POLYOLS AND TERTIARY AMINE-CONTAINING POLYOLS 审中-公开
标题翻译：含羟基甲基的聚酯多元醇和仲胺含多元醇的聚氨酯泡沫
公开(公告)号：US20100010110A1
公开(公告)日：2010-01-14
申请号：US12440269
申请日：2007-09-18
申请人： Robbyn Prange , Mark F. Sonnenschein , David A. Babb , Alan K. Schrock
发明人： Robbyn Prange , Mark F. Sonnenschein , David A. Babb , Alan K. Schrock
IPC分类号： C08G18/18
CPC分类号： C08G18/36 , C08G18/482 , C08G18/485 , C08G18/5021 , C08G2101/005 , C08G2101/0083
摘要： Flexible polyurethane foams are prepared by reacting a polyisocyanate with a high equivalent weight polyol. At least a portion of the high equivalent weight polyol is a polyester containing hydroxymethyl groups. The high equivalent weight polyol further includes species containing tertiary amine groups. The presence of tertiary amine-containing polyols in the formulation leads to improvements in resiliency, tensile and/or tear strength.
摘要翻译：柔性聚氨酯泡沫通过使多异氰酸酯与高当量多元醇反应制备。高当量多元醇的至少一部分是含有羟甲基的聚酯。高当量多元醇还包括含有叔胺基团的物质。制剂中含叔胺的多元醇的存在导致弹性，拉伸和/或撕裂强度的改善。

2. 发明申请

US20120022177A1 NON-FUGITIVE CATALYSTS CONTAINING IMINE LINKAGES AND TERTIARY AMINES, AND POLYURETHANE PRODUCTS MADE THEREFROM 审中-公开
标题翻译：含有IMINE链接和仲胺的非助催化剂和由其制成的聚氨酯产品
公开(公告)号：US20120022177A1
公开(公告)日：2012-01-26
申请号：US13253131
申请日：2011-10-05
申请人： Ray E. Drumright , Robbyn Prange , Francois M. Casati
发明人： Ray E. Drumright , Robbyn Prange , Francois M. Casati
IPC分类号： C08J9/35 , C07D277/00 , C09D175/04 , C07D301/00 , C09K3/00 , C08G18/18
CPC分类号： C08G18/1858 , C07C251/08 , C07C251/24 , C07D233/61 , C08G18/18 , C08G18/1825 , C08G18/1866 , C08G18/2027 , C08G18/4072 , C08G18/482 , C08G2101/00 , C08G2101/0008 , C08G2101/005 , C08G2290/00 , C08L83/00
摘要： The present invention pertains to non-fugitive amine catalysts wherein the catalyst contains at least one imine and at least one tertiary amine moiety. Such catalysts are suitable for the production of polyurethane products.
摘要翻译：本发明涉及非逸散性胺催化剂，其中催化剂含有至少一种亚胺和至少一种叔胺部分。这种催化剂适用于生产聚氨酯产品。

3. 发明申请

US20070173556A1 Co-catalysis of autocatalytic polyols for low denisty polyurethane foams with improved aging characteristics 审中-公开
标题翻译：具有改善老化特性的低粘度聚氨酯泡沫的自催化多元醇的共催化作用
公开(公告)号：US20070173556A1
公开(公告)日：2007-07-26
申请号：US10589516
申请日：2005-04-27
申请人： Robbyn Prange , Jose Godoy , Francois Casate , Robert Dawe
发明人： Robbyn Prange , Jose Godoy , Francois Casate , Robert Dawe
IPC分类号： C08G18/00
CPC分类号： C08G18/4072 , C08G18/089 , C08G18/1875 , C08G18/2027 , C08G18/5021 , C08G18/5024 , C08G18/632 , C08G18/7621 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： The present invention pertains to the co-catalysis of autocatalytic amine-based polyols with acid blocked, gelling, amine catalysts, and to the use of this catalyst combination in the production of low density polyurethane foams having improved aging characteristics and reduced VOC's (Volatile Organic Compounds) emissions.
摘要翻译：本发明涉及具有酸封闭，胶凝，胺催化剂的自催化胺基多元醇的共催化，以及在生产具有改善的老化特性和降低的VOC（低挥发性有机物）的低密度聚氨酯泡沫体中使用该催化剂组合化合物）排放。

4. 发明申请

US20070238795A1 Non-Fugitive Catalysts Containing Imine Linkages and Tertiary Amines, and Polyurethane Products made Therefrom 审中-公开
标题翻译：含有亚胺连接和叔胺的非逸散催化剂，以及由此制成的聚氨酯产品
公开(公告)号：US20070238795A1
公开(公告)日：2007-10-11
申请号：US10579351
申请日：2004-12-22
申请人： Ray Drumright , Robbyn Prange , Francois Casati
发明人： Ray Drumright , Robbyn Prange , Francois Casati
IPC分类号： C08G18/18 , C07C249/02 , C08G18/48 , C08G18/76
CPC分类号： C08G18/1858 , C07C251/08 , C07C251/24 , C07D233/61 , C08G18/18 , C08G18/1825 , C08G18/1866 , C08G18/2027 , C08G18/4072 , C08G18/482 , C08G2101/00 , C08G2101/0008 , C08G2101/005 , C08G2290/00 , C08L83/00
摘要： The present invention pertains to non-fugitive amine catalysts wherein the catalyst contains at least one imine and at least one tertiary amine moiety. Such catalysts are suitable for the production of polyurethane products.
摘要翻译：本发明涉及非逸散性胺催化剂，其中催化剂含有至少一种亚胺和至少一种叔胺部分。这种催化剂适用于生产聚氨酯产品。

5. 发明授权

US06392008B1 Polyphosphazene polymers 失效
标题翻译：聚磷腈聚合物
公开(公告)号：US06392008B1
公开(公告)日：2002-05-21
申请号：US09621397
申请日：2000-07-21
申请人： Harry R. Allcock , Robbyn Prange , Christine R. deDenus , James M. Nelson , Chester A. Crane , Walter R. Laredo , Scott D. Reeves
发明人： Harry R. Allcock , Robbyn Prange , Christine R. deDenus , James M. Nelson , Chester A. Crane , Walter R. Laredo , Scott D. Reeves
IPC分类号： C08G7902
CPC分类号： C08G77/60 , C08G77/42 , C08G79/025 , C08G81/00 , C08G81/02
摘要： Compositions of polyphosphazene-containing polymers and methods of preparation thereof are provided. The disclosed compositions encompass telechelic functionalized polyphosphazenes and a variety of block and graft polyphosphazene-polystyrene, polyphosphazene-polysiloxane, and polyphosphazene-ROMP of norbornene copolymers. Methods for the preparation of such compositions generally involve generation of a polydichlorophosphazene species, attachment of a function group to the resultant polyphosphazene compound, and coupling the functionalized polyphosphazene with a corresponding organic or inorganic polymers or polymerizing the functionalized polyphosphazene with corresponding organic molecules.
摘要翻译：提供了含聚磷腈的聚合物的组合物及其制备方法。所公开的组合物包含遥爪官能化聚磷腈和降冰片烯共聚物的各种嵌段和接枝聚磷腈 - 聚苯乙烯，聚磷腈 - 聚硅氧烷和聚磷腈-ORMP。制备这种组合物的方法通常包括产生聚二氯磷腈物质，将功能基团连接到所得聚磷腈化合物上，并将官能化的聚磷腈与相应的有机或无机聚合物偶合或者使官能化的聚磷腈与相应的有机分子聚合。

6. 发明授权

US07750108B2 Polyester polyols containing secondary alcohol groups and their use in making polyurethanes such as flexible polyurethane foams 有权
标题翻译：含有仲醇基团的聚酯多元醇及其在制备聚氨酯如柔性聚氨酯泡沫体中的用途
公开(公告)号：US07750108B2
公开(公告)日：2010-07-06
申请号：US11918633
申请日：2006-04-27
申请人： Zenon Lysenko , David A. Babb , Kenneth J. Stutts , Robbyn Prange , Min Zhang , Alan K. Schrock
发明人： Zenon Lysenko , David A. Babb , Kenneth J. Stutts , Robbyn Prange , Min Zhang , Alan K. Schrock
IPC分类号： C08G63/00
CPC分类号： C08G63/676 , C08G18/4018 , C08G18/4244 , C08G18/4288 , C08G18/4825 , C08G18/485 , C08G18/4891 , C08G18/7621 , C08G2101/0008 , C08G2101/0083
摘要： Copolyesters containing secondary hydroxyl groups are useful polyols for manufacturing polyurethanes. These can be prepared by reacting a secondary hydroxyl-containing fatty acid or ester thereof with an initiator containing hydroxyl and/or primary or secondary amino groups. A copolyester of particular interest includes a poly(ethylene oxide) segment derived from a poly(ethylene oxide) initiator.
摘要翻译：含有仲羟基的共聚酯是制造聚氨酯的有用的多元醇。这些可以通过使含仲羟基的脂肪酸或其酯与含有羟基和/或伯或仲氨基的引发剂反应来制备。特别感兴趣的共聚酯包括衍生自聚（环氧乙烷）引发剂的聚（环氧乙烷）链段。

7. 发明申请

US20090264546A1 Polyester polyols containing secondary alcohol groups and their use in making polyurethanes such as flexible polyurethane foams 有权
标题翻译：含有仲醇基团的聚酯多元醇及其在制备聚氨酯如柔性聚氨酯泡沫体中的用途
公开(公告)号：US20090264546A1
公开(公告)日：2009-10-22
申请号：US11918633
申请日：2006-04-27
申请人： Zenon Lysenko , David A. Babb , Kenneth J. Stutts , Robbyn Prange , Min Zhang , Alan K. Schrock
发明人： Zenon Lysenko , David A. Babb , Kenneth J. Stutts , Robbyn Prange , Min Zhang , Alan K. Schrock
IPC分类号： C08G18/30 , C08G63/685 , C08G63/664
CPC分类号： C08G63/676 , C08G18/4018 , C08G18/4244 , C08G18/4288 , C08G18/4825 , C08G18/485 , C08G18/4891 , C08G18/7621 , C08G2101/0008 , C08G2101/0083
摘要： Copolyesters containing secondary hydroxyl groups are useful polyols for manufacturing polyurethanes. These can be prepared by reacting a secondary hydroxyl-containing fatty acid or ester thereof with an initiator containing hydroxyl and/or primary or secondary amino groups. A copolyester of particular interest includes a poly(ethylene oxide) segment derived from a poly(ethylene oxide) initiator.
摘要翻译：含有仲羟基的共聚酯是制造聚氨酯的有用的多元醇。这些可以通过使含仲羟基的脂肪酸或其酯与含有羟基和/或伯或仲氨基的引发剂反应来制备。特别感兴趣的共聚酯包括衍生自聚（环氧乙烷）引发剂的聚（环氧乙烷）链段。

8. 发明申请

US20080096993A1 Acid Blocked, Amine Based, Autocatalytic Polyols and Polyurethane Foams Made Therefrom 审中-公开
标题翻译：酸性封闭，胺基，自动催化多元醇和聚氨酯泡沫制成
公开(公告)号：US20080096993A1
公开(公告)日：2008-04-24
申请号：US11665409
申请日：2005-11-14
申请人： Francois Casati , Robert Dawe , Robbyn Prange , Ray Drumright , Ross Polk
发明人： Francois Casati , Robert Dawe , Robbyn Prange , Ray Drumright , Ross Polk
IPC分类号： C08L75/04 , C08J9/00
CPC分类号： C08G18/482 , C08G18/5021 , C08G18/5069 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： The present invention pertains to acid blocked, amine-based, autocatalytic polyols, and to the use of these autocatalytic polyols in the production of polyurethane foams having superior aging characteristics.
摘要翻译：本发明涉及酸封端，胺基，自催化多元醇，以及这些自催化多元醇在生产具有优异老化特性的聚氨酯泡沫体中的用途。

9. 发明授权

US06339166B1 Phosphinimine modification of organic polymers and silicones 失效
标题翻译：有机聚合物和硅氧烷的磷腈改性
公开(公告)号：US06339166B1
公开(公告)日：2002-01-15
申请号：US09850259
申请日：2001-05-07
申请人： Harry R. Allcock , Thomas J. Hartle , Michael B. McIntosh , Nicolas J. Sunderland , Robbyn Prange , Jonathan P. Taylor
发明人： Harry R. Allcock , Thomas J. Hartle , Michael B. McIntosh , Nicolas J. Sunderland , Robbyn Prange , Jonathan P. Taylor
IPC分类号： C07F708
CPC分类号： C07F9/65815 , C08C19/22 , C08C19/24 , C08F8/30 , C08F8/40 , C08G77/395 , C08G77/42
摘要： Methods have been developed to produce phosphazene modified organic or siloxane polymers. The method includes (a) providing an organic or siloxane polymer comprising phosphine units, and (b) reacting the organic or siloxane polymer with a phosphazene azide compound under conditions wherein the phosphazene azide compound is bound to the phosphine unites in the polymer, thereby producing the phosphazene-modified organic or siloxane polymer. The organic polymer of step (a) is produced by reacting a first monomer comprising phosphine with a second monomer via free radical or anionic polymerization techniques to produce the organic polymer comprising phosphine units. The first and second monomers can be identical. A wide variety of organic polymer backbones can be modified using these techniques. The second monomer, for example, can be selected from monomers forming polyolefins, polydienes, polyacrylics, polyethylenes, polyvinyl chlorides, polyisoprenes, polystyrenes, polycaprolactam, poly(methyl)(meth)acrylates, and polypropylenes. Alternatively, the siloxane polymer of step (a) is produced by reacting a monomer comprising phosphine with a hydrosilicone polymer via hydrosilylation polymerization techniques to produce the siloxane polymer comprising phosphine units. These phosphazene modified organic and siloxane polymers are useful in a variety of applications, particularly as a fire retardant material.
摘要翻译：已经开发了制备磷腈改性的有机或硅氧烷聚合物的方法。该方法包括（a）提供包含磷化氢单元的有机或硅氧烷聚合物，和（b）在叠氮化磷化合物与聚合物中的膦化合物结合的条件下使有机或硅氧烷聚合物与叠氮化磷化合物反应，从而产生磷腈改性的有机或硅氧烷聚合物。通过自由基或阴离子聚合技术使包含膦的第一单体与第二单体反应制备步骤（a）的有机聚合物，以制备包含磷化氢单元的有机聚合物。第一和第二单体可以相同。使用这些技术可以改变各种各样的有机聚合物主链。例如，第二单体可以选自形成聚烯烃，聚二烯，聚丙烯酸，聚乙烯，聚氯乙烯，聚异戊二烯，聚苯乙烯，聚己内酰胺，聚（甲基）（甲基）丙烯酸酯和聚丙烯的单体。或者，步骤（a）的硅氧烷聚合物通过氢化硅烷化聚合技术使包含膦的单体与氢硅氧烷聚合物反应制备包含磷化氢单元的硅氧烷聚合物来制备。这些磷腈改性的有机和硅氧烷聚合物可用于各种应用，特别是作为阻燃材料。

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