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    • 1. 发明授权
    • Method of cleaning sulfide contaminated condensates
    • 清洁硫化物污染的冷凝物的方法
    • US06790313B1
    • 2004-09-14
    • US09856961
    • 2001-11-09
    • Kent K. SandquistOlle Wennberg
    • Kent K. SandquistOlle Wennberg
    • D21C1106
    • D21C11/08D21C11/06
    • A method to remove sulfides and other volatile contaminants from liquor vapor condensate in a pulp manufacturing process, where the mentioned liquor vapor condensate is fed into a stripper, which is part of a closed loop system including the stripper, a regenerative thermal oxidization process (RTO) and a SO2 scrubber, in which loop a gas is circulated, preferably air, and such components formed or stripped off, in this loop whereafter the circulating gas is stripped off sulfides and other volatile components from the liquor vapor condensate, whereafter the gas stream is fed into a RTO process, where the stripped off contaminants are combusted are under formation of SO2 and thereafter the SO2 enriched gas is led to a SO2 scrubber, where preferably alkali is used as absorption medium, and thereafter the circulating gas is returned back into the stripper.
    • 一种在纸浆生产过程中从液体蒸汽冷凝物中除去硫化物和其它挥发性污染物的方法,其中将所提及的液体蒸汽冷凝物送入汽提器,汽提器是包括汽提塔的闭环系统的一部分,再生热氧化过程(RTO )和SO 2洗涤器,其中气体循环,优选空气,并且这种组分在该环中形成或剥离,之后循环气体从液体蒸气冷凝物中除去硫化物和其它挥发性组分,之后气流 进入RTO过程,其中汽脱的污染物在SO2的形成下,然后将富SO 2的气体导入SO 2洗涤器,其中优选使用碱作为吸收介质,然后将循环气体返回到 脱模剂。
    • 4. 发明授权
    • Process for removing metals and recovering a chelating agent from a
bleach plant waste liquor
    • 从漂白植物废液中除去金属和回收螯合剂的方法
    • US6024833A
    • 2000-02-15
    • US850737
    • 1997-05-02
    • Olle Wennberg
    • Olle Wennberg
    • D21C11/00D21C11/04D21C11/10
    • D21C11/0028D21C11/0078Y10S210/928
    • Provided is a process for removing metals from a bleaching plant spent liquor and recovering a chelating agent which includes the steps of: heating a spent liquor containing a chelate comprising metals bound in a chelating agent to a temperature of at least about 140.degree. C. to break bonds in the chelate and release metals from the chelate; increasing the content of at least one of carbonate or sulphide in an alkaline material comprising at least one of green liquor or white liquor to form a carbonate or sulphide enhanced alkaline material; contacting the heated spent liquor with the alkaline material to form a solution containing precipitated metals, wherein the alkaline material is added in an amount sufficient to precipitate a majority of the released metals out of the solution; filtering the solution to separate the precipitated metals from the solution and form a filtrate containing recovered chelating agent; and supplying at least a portion of the recovered chelating agent to a chelating washing stage in a bleaching plant to bond with metals released from pulp and form a chelate. Also provided is a method of reducing encrustations.
    • 提供了从漂白设备废液中除去金属并回收螯合剂的方法,该方法包括以下步骤:将包含螯合剂中螯合物的螯合物的废液加热到至少约140℃的温度至 在螯合物中断开键并从螯合物中释放金属; 在包含绿液或白液中的至少一种的碱性物质中增加碳酸盐或硫化物中的至少一种的含量以形成碳酸盐或硫化物增强的碱性物质; 使加热的废液与碱性材料接触以形成含有沉淀金属的溶液,其中碱金属物质的添加量足以将大部分释放的金属从溶液中沉淀出来; 过滤溶液以将沉淀的金属与溶液分离,并形成含有回收螯合剂的滤液; 并将回收的螯合剂的至少一部分供应到漂白设备中的螯合洗涤阶段以与从纸浆释放的金属结合并形成螯合物。 还提供了减少结壳的方法。