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    • 1. 发明授权
    • Gas diffusion electrode assemblies and processes for producing the same
    • 气体扩散电极组件及其制造方法
    • US06399236B1
    • 2002-06-04
    • US09504866
    • 2000-02-16
    • Nagakazu Furuya
    • Nagakazu Furuya
    • H01M486
    • H01M8/0232C25B11/035H01M4/8605H01M8/0239H01M8/0245H01M8/0247Y02P70/56
    • A gas diffusion electrode assembly comprising: a gas diffusion electrode; and a metallic or resinous edging material bonded to a peripheral part of the electrode. The invention also relates to a gas diffusion electrode assembly comprising: a gas diffusion electrode; and a metallic terminal bonded to the electrode. The invention further relates to a gas diffusion electrode assembly comprising: a gas diffusion electrode; and a structure for connection, which comprises a combination of a thin silver sheet and a reinforcing material comprising a tough metal as a base, the structure for connection being bonded to a peripheral part of the gas diffusion electrode. Also disclosed are processes for producing these gas diffusion electrode assemblies.
    • 一种气体扩散电极组件,包括:气体扩散电极; 以及结合到电极的周边部分的金属或树脂边缘材料。 本发明还涉及一种气体扩散电极组件,包括:气体扩散电极; 和与电极结合的金属端子。 本发明还涉及一种气体扩散电极组件,包括:气体扩散电极; 以及连接结构,其包括薄银片和包含韧性金属作为基底的增强材料的组合,所述连接结构结合到气体扩散电极的周边部分。 还公开了用于制造这些气体扩散电极组件的方法。
    • 3. 发明授权
    • Process for converting ferrous ions to ferric ions
    • 将亚铁离子转化成铁离子的方法
    • US5181993A
    • 1993-01-26
    • US757477
    • 1991-09-10
    • Nagakazu Furuya
    • Nagakazu Furuya
    • B01J8/00B01J10/00B01J19/24B01J35/06C01G1/00C01G3/05C01G3/10C01G43/00C01G43/08C01G49/10C01G49/14
    • B01J19/2475B01J10/007B01J35/065B01J8/009C01G1/00C01G3/05C01G3/10C01G43/00C01G43/08C01G49/10C01G49/14C25B1/00C25B1/04Y02E60/366
    • Enclosed herein is an apparatus for converting an ionic valence number which comprises a gas permeable membrane comprising a catalyst-supporting reaction layer and a hydrophobic gas permeable layer having fine pores; a solution chamber retaining an aqueous solution containing an ion, and the respective supply port and discharge port for the supply and the discharge of the aqueous solution containing the ion, which are located on the reaction layer side of the gas permeable membrane; and a gas chamber retaining an oxidizing gas or a reducing gas, and the respective supply port and discharge port for the supply and the discharge of the oxidizing or reducing gas, which are located on the gas permeable layer side of the gas permeable membrane. Another aspect of the invention is process for converting a ionic valence number which comprises supplying an aqueous solution containing an ion to the reaction layer side of a gas permeable membrane formed by joining a catalyst-supporting reaction layer with a gas permeable layer; supplying an oxidizing or a reducing gas to the gas permeable side; and converting the valence number of the ion in the aqueous solution containing the said ion.
    • 本文包括用于转换离子价数的装置,其包括含有催化剂负载反应层和具有细孔的疏水性气体渗透层的透气膜; 保留含有离子的水溶液的溶液室和位于气体透过膜的反应层侧的供给和排出含有离子的水溶液的供给口和排出口; 以及保持氧化性气体或还原性气体的气体室,以及位于透气膜的透气层侧的供给排出和/或排出氧化还原性气体的供给口和排出口。 本发明的另一方面是转化离子价数的方法,该方法包括向含有催化剂的反应层与透气层形成的透气膜的反应层侧供给含有离子的水溶液; 向气体可渗透侧供应氧化或还原气体; 并转化含有所述离子的水溶液中的离子的价数。
    • 5. 发明授权
    • Halogen cell
    • 卤素电池
    • US4748095A
    • 1988-05-31
    • US22866
    • 1987-03-06
    • Nagakazu FuruyaSatoshi Motoo
    • Nagakazu FuruyaSatoshi Motoo
    • H01M4/86H01M12/08
    • H01M4/86H01M12/085Y02E60/128
    • Disclosed herein is a halogen cell of which a positive electrode and/or a negative electrode is a gas permeable electrode. The gas permeable electrode preferably comprises a hydrophilic layer and a gas permeable layer. Since, in this halogen cell, the decrease of the electrode surface area can be prevented, and the desired gas can be rapidly supplied to the electrode, the quantity of charge is increased and the charging time is reduced.Also disclosed herein is a halogen cell of which a positive electrode and/or negative electrode comprises finely divided hydrophilic portions and hydrophobic portions. In this halogen cell, the quantity of charge and the charging time are also improved.
    • 这里公开了一种卤素电池,其正极和/或负极是透气电极。 透气电极优选包括亲水层和透气层。 由于在该卤素电池中,可以防止电极表面积的减小,并且能够将期望的气体迅速地供给至电极,因此电荷量增加,充电时间缩短。 本文还公开了一种卤素电池,其正极和/或负极包括细分的亲水部分和疏水部分。 在该卤素电池中,充电量和充电时间也得到改善。
    • 7. 发明授权
    • Gas permeable member
    • 透气构件
    • US5234768A
    • 1993-08-10
    • US491092
    • 1990-03-09
    • Nagakazu Furuya
    • Nagakazu Furuya
    • C25B11/03C25B11/04H01M4/90H01M4/96
    • C25B11/035C25B11/04H01M4/9008H01M4/96Y10T428/30Y10T428/3154Y10T428/31544
    • Disclosed herein is a gas permeable member, in particular a gas permeable electrode, carrying a metal complex on a reaction layer thereof. A central metal of the complex may be selected from lead, chromium, iron, cobalt, nickel, copper, zinc, platinum, palladium, manganese, tin, vanadium or the like. The selectivity of a reaction employing the gas permeable member depends on the central metal so that the gas permeable member can be employed in a wide range of applications including electrolytic reduction of carbon dioxide by suitably selecting the central metal of the complex.The complex, for instance a Pc-complex, may be deposited from sulfuric acid by diluting the sulfuric acid by water to be uniformly dispersed in the reaction layer.
    • 本文公开了在其反应层上携带金属络合物的气体可渗透构件,特别是透气电极。 络合物的中心金属可以选自铅,铬,铁,钴,镍,铜,锌,铂,钯,锰,锡,钒等。 采用气体可渗透部件的反应的选择性取决于中心金属,使得透气部件可以广泛应用于包括通过适当选择络合物的中心金属的二氧化碳的电解还原。 络合物,例如Pc-络合物,可以通过用硫稀释硫酸而均匀地分散在反应层中,从硫酸沉积。
    • 10. 发明授权
    • Process for preparing raw materials for reaction layer of gas permeable
electrode
    • 制备透气电极反应层原料的方法
    • US5124018A
    • 1992-06-23
    • US283782
    • 1988-12-13
    • Nagakazu FuruyaSatoshi Motoo
    • Nagakazu FuruyaSatoshi Motoo
    • H01M4/88H01M4/96
    • H01M4/8892H01M4/8828
    • Disclosed herein are processes for preparing a raw material dispersion and raw material powders for producing reaction layers of a gas permeable electrode. The raw materials are prepared in one aspect of the invention by mixing fine particles containing a surface-active agent, freezing the mixture to a temperature the surface-active agent loses at least part of its function and then thawing out the same. The resulting material exhibits superior catalytic performance because the particles are dispersed uniformly by lack of the function of surfaceactive agent at the time of freezing.The raw materials are prepared in another aspect of the invention by mixing hydrophilic minute particles coated with ion exchange resin, PTFE and hydrophobic fine powders. The resulting material exhibits superior catalytic performance because catalysts contained in the hydrophilic minute particles are neither liberated nor made to flow so that the initial catalytic activities are substantially maintained even after a relatively long period of use.
    • 本文公开了制备原料分散体和用于制造透气电极的反应层的原料粉末的方法。 通过混合含有表面活性剂的细颗粒,将混合物冷冻至表面活性剂至少部分功能的温度,然后将其解冻,从而在本发明的一个方面制备原料。 所得到的材料表现出优异的催化性能,因为在冷冻时由于缺乏表面活性剂的功能而使颗粒均匀分散。 通过混合涂覆有离子交换树脂,PTFE和疏水性细粉末的亲水微粒,制备本发明的另一方面的原料。 所得到的材料表现出优异的催化性能,因为亲水性微粒子中所含的催化剂既不释放也不能流动,使得即使在相对长的使用时间之后,初始催化活性仍然基本保持。