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1. 发明授权

US06395341B1 Organic-inorganic hybrid polymer materials with compositional gradient, and processes for preparing the same 失效
公开(公告)号：US06395341B1
公开(公告)日：2002-05-28
申请号：US09354152
申请日：1999-07-16
申请人： Motoomi Arakawa , Kazuaki Sukata , Yasuyuki Agari , Masayuki Shimada
发明人： Motoomi Arakawa , Kazuaki Sukata , Yasuyuki Agari , Masayuki Shimada
IPC分类号： B05D136
CPC分类号： C08G65/48 , C08F8/42 , C08G63/916 , C08G64/42 , C08G65/485 , C08G83/001 , C08J3/245
摘要： According to the present invention, organic-inorganic hybrid polymer materials with compositional gradient, and processes for preparing the same are provided. In the organic-inorganic hybrid polymer materials with compositional gradient, formation of cracks, removal of surface, or deformation such as warp and distortion, under heat shock or upon aging, hardly occurs. The organic-inorganic hybrid polymer materials with compositional gradient are comprised of an organic polymer component and a metal oxide component which are covalently bonded each other, characterized in that concentration of the organic polymer component, or of the metal oxide component is increased or decreased in the direction of thickness of the material.

2. 发明授权

US4855208A Toner for developing electrostatic latent images 失效
标题翻译：用于显影静电潜像的调色剂
公开(公告)号：US4855208A
公开(公告)日：1989-08-08
申请号：US206472
申请日：1988-06-13
申请人： Akihiro Tada , Takashi Kiriu , Motoomi Arakawa
发明人： Akihiro Tada , Takashi Kiriu , Motoomi Arakawa
IPC分类号： G03G9/097
CPC分类号： G03G9/09783
摘要： A toner for developing electrostatic latent images which is characterized in that the toner comprises an aluminum compound of aromatic o-aminocarboxylic acid, the aromatic o-aminocarboxylic acid being represented by the formula ##STR1## wherein Q is benzene nucleus which is optionally substituted with at least one nuclear substituent or naphthalene nucleus which is optionally substituted with at least one nuclear substituent, R is hydrogen, alkyl (C.sub.1 -C.sub.18), aryl or nuclear substituted aryl (C.sub.6 -C.sub.18), aralkyl or nuclear substituted aralkyl (C.sub.7 -C.sub.18), or --COR', wherein R' is alkyl(C.sub.1 -C.sub.8), aryl(C.sub.6 -C.sub.8), alkoxy (C.sub.1 -C.sub.8) or amino.

3. 发明授权

US07326762B2 Copolymer having reactive silicon-containing group and organic-inorganic hybrid polymeric material 失效
标题翻译：具有反应性含硅基团和有机 - 无机杂化聚合物材料的共聚物
公开(公告)号：US07326762B2
公开(公告)日：2008-02-05
申请号：US11313788
申请日：2005-12-22
申请人： Motoomi Arakawa , Kazuaki Sukata , Masayuki Shimada , Shigehiro Sasao
发明人： Motoomi Arakawa , Kazuaki Sukata , Masayuki Shimada , Shigehiro Sasao
IPC分类号： C08G77/20
CPC分类号： C08F293/00 , C08F290/06 , Y10S528/901
摘要： Disclosed is a copolymer comprising a polyethylene segment which is a main chain; a reactive silicon-containing group which is a side group of the polyethylene segment; and a polycondensation segment bonded to the polyethylene segment, which is a part of the main chain together with the polyethylene segment or a side chain with respect to the polyethylene segment. There are provided a condensation polymer having many reactive silicon-containing groups with respect to one molecule and an organic-inorganic hybrid polymeric material having superior properties such as strength, heat resistance, weather resistance and chemical resistance by using the polymer.
摘要翻译：公开了包含作为主链的聚乙烯部分的共聚物; 作为聚乙烯部分的侧基的反应性含硅基团; 以及与聚乙烯部分结合的缩聚链段，该聚乙烯部分是与聚乙烯部分或侧链相对于聚乙烯部分一起的主链的一部分。提供了相对于一个分子具有许多反应性含硅基团的缩合聚合物和通过使用该聚合物而具有优异性能如强度，耐热性，耐候性和耐化学性的有机 - 无机复合聚合材料。

4. 发明申请

US20070100083A1 Polycarbonate or polyester having reactive silicon-containing group and organic-inorganic hybrid polymeric material from the same 审中-公开
标题翻译：具有反应性含硅基团的聚碳酸酯或聚酯和来自其的有机 - 无机杂化聚合物材料
公开(公告)号：US20070100083A1
公开(公告)日：2007-05-03
申请号：US10562069
申请日：2004-06-18
申请人： Motoomi Arakawa , Kazuaki Sukata
发明人： Motoomi Arakawa , Kazuaki Sukata
IPC分类号： C08F8/42 , C08G64/00
CPC分类号： C08G63/6954 , C08G63/914 , C08G64/0266 , C08G64/42
摘要： The present invention provides a polycarbonate or polyester having reactive silicon-containing groups which can provide an organic-inorganic hybrid polymeric material having strong cross-linkage to inorganic components based on its many reactive silicon-containing groups. The polycarbonate or polyester has the following unit: wherein, either Q1 or Q2 is a side chain having a reactive silicon-containing group, the other of Q1 or Q2, and R1, R2 are each independently hydrogen atom, or an alkyl group, an aryl group, an aroyl group or an aralkyl group, wherein the groups may have a substituted group or atom, Q1 and Q2 may be taken together to form a ring, R1 and R2 may be taken together to form a ring, and R is a bivalent group of alkylene group, arylene group or combination thereof, which accomplishes the above objective.
摘要翻译：本发明提供了具有反应性含硅基团的聚碳酸酯或聚酯，其可以提供与基于其许多反应性含硅基团的无机组分具有强交联的有机 - 无机杂化聚合物材料。聚碳酸酯或聚酯具有以下单元：其中，Q 1或Q 2 2是具有反应性含硅基团的侧链，Q < 1或Q 2，R 1，R 2，R 2各自独立地为氢原子，或烷基，芳基，芳酰基或芳烷基，其中基团可以具有取代基或原子，Q 1和Q 2可以一起形成环，可以将1个和1个R 2一起形成环，R是亚烷基，亚芳基或其组合的二价基团，其实现上述目的。

5. 发明授权

US07157542B2 Copolymer having reactive silicon-containing group and organic-inorganic hybrid polymeric material 失效
标题翻译：具有反应性含硅基团和有机 - 无机杂化聚合物材料的共聚物
公开(公告)号：US07157542B2
公开(公告)日：2007-01-02
申请号：US10736708
申请日：2003-12-17
申请人： Motoomi Arakawa , Kazuaki Sukata , Masayuki Shimada , Shigehiro Sasao
发明人： Motoomi Arakawa , Kazuaki Sukata , Masayuki Shimada , Shigehiro Sasao
IPC分类号： C08G77/20
CPC分类号： C08F293/00 , C08F290/06 , Y10S528/901
摘要： Disclosed is a copolymer comprising a polyethylene segment which is a main chain; a reactive silicon-containing group which is a side group of the polyethylene segment; and a polycondensation segment bonded to the polyethylene segment, which is a part of the main chain together with the polyethylene segment or a side chain with respect to the polyethylene segment. There are provided a condensation polymer having many reactive silicon-containing groups with respect to one molecule and an organic-inorganic hybrid polymeric material having superior properties such as strength, heat resistance, weather resistance and chemical resistance by using the polymer.
摘要翻译：公开了包含作为主链的聚乙烯部分的共聚物; 作为聚乙烯部分的侧基的反应性含硅基团; 以及与聚乙烯部分结合的缩聚链段，该聚乙烯部分是与聚乙烯部分或侧链相对于聚乙烯部分一起的主链的一部分。提供了相对于一个分子具有许多反应性含硅基团的缩合聚合物和通过使用该聚合物而具有优异性能如强度，耐热性，耐候性和耐化学性的有机 - 无机复合聚合材料。

6. 发明授权

US4845003A Toner for developing electrostatic latent images and complex compounds containing aluminum usable therein 失效
标题翻译：用于显影静电潜像的调色剂和可用于其中的铝的复合化合物
公开(公告)号：US4845003A
公开(公告)日：1989-07-04
申请号：US224466
申请日：1988-07-26
申请人： Takashi Kiriu , Motoomi Arakawa
发明人： Takashi Kiriu , Motoomi Arakawa
IPC分类号： G03G9/097
CPC分类号： G03G9/09783
摘要： A toner for developing electrostatic latent images characterized in that the toner comprises an aluminum compound of a hydroxycarboxylic acid which may be substituted with alkyl and/or aralkyl.

7. 发明授权

US08318305B2 Resin composition 有权
标题翻译：树脂组成
公开(公告)号：US08318305B2
公开(公告)日：2012-11-27
申请号：US13115605
申请日：2011-05-25
申请人： Kenji Watanabe , Kenji Atarashi , Kumiko Chatani , Motoomi Arakawa
发明人： Kenji Watanabe , Kenji Atarashi , Kumiko Chatani , Motoomi Arakawa
IPC分类号： B32B27/04 , B32B27/00 , C08F8/00 , C08F242/00
CPC分类号： C08L23/12 , C08L51/06 , C08L2203/12 , C08L2205/03 , Y10T428/24994 , Y10T428/2933 , Y10T428/2967 , C08L23/0884 , C08L23/16
摘要： A resin composition comprising a fiber component and a resin component, whereinthe fiber component is (A) a surface-treated fiber (component A) which comprises 100 parts by weight of a fiber comprising a polyalkylene terephthalate and/or a polyalkylene naphthalene dicarboxylate (component Af) and 0.1 to 10 parts by weight of a sizing agent having a glass transition point of −80° C. or higher and lower than 70° C. and adhered to the surface of the fiber (component Ac); andthe resin component comprises (B) an ethylene-based copolymer containing a glycidyl group (component B), (C) a modified polyolefin resin modified with an unsaturated carboxylic acid and/or an unsaturated carboxylic acid derivative (component C), and (D) a polyolefin resin having a melt flow rate of 40 to 200 g/10 min (component D), except for the components C and D, the content of the component D being 30 to 850 parts by weight based on 100 parts by weight of the component A, and the total content of the components B and C being 5 to 630 parts by weight based on 100 parts by weight of the component A,and a molded article thereof.
摘要翻译：一种树脂组合物，其包含纤维成分和树脂成分，其中，所述纤维成分为（A）表面处理纤维（A成分），其包含100重量份的包含聚对苯二甲酸亚烷基酯和/或聚亚烷基二羧酸二烷基酯成分Af）和0.1〜10重量份的玻璃化转变温度为-80℃以上且低于70℃的上胶剂，并附着在纤维（Ac成分）表面上。树脂成分包含（B）含有缩水甘油基（B成分）的乙烯系共聚物，（C）用不饱和羧酸和/或不饱和羧酸衍生物（C成分）改性的改性聚烯烃树脂，（C） D）熔体流动速率为40〜200g / 10分钟（成分D）的聚烯烃树脂除了成分C，D以外，成分D的含量相对于100重量份为30〜850重量份的组分A和组分B和C的总含量为5〜630重量份，基于100重量份的组分A及其模制品。

8. 发明授权

US06476098B1 Organic-inorganic composite material and process for preparing the same 失效
标题翻译：有机 - 无机复合材料及其制备方法
公开(公告)号：US06476098B1
公开(公告)日：2002-11-05
申请号：US09572497
申请日：2000-05-18
申请人： Motoomi Arakawa , Kazuaki Sukata , Yasuyuki Agari , Masayuki Shimada
发明人： Motoomi Arakawa , Kazuaki Sukata , Yasuyuki Agari , Masayuki Shimada
IPC分类号： C08K906
CPC分类号： C08G83/001 , C08K9/08 , Y10S977/753 , Y10S977/776 , Y10S977/778 , Y10S977/788
摘要： According to the present invention, there is provided an organic-inorganic composite material which shows high mechanical strength and high water resistance, requires low cost for preparation, and is preferred to be used as a high performance and a high functional plastic material. The present invention provides an organic-inorganic composite material which comprises a matrix of an organic polymer (E), metal oxide particles (C) dispersed uniformly in the organic polymer (E), and a surface modifier for allowing the metal oxide particles (C) to disperse uniformly in the organic polymer (E), wherein the surface modifier is another organic polymer (A) which has a functional group formable of a covalent bond to a surface of the metal oxide particles (C).
摘要翻译：根据本发明，提供了一种机械强度高，耐水性高的有机 - 无机复合材料，制备成本低，优选用作高性能和高功能塑料材料。本发明提供一种有机 - 无机复合材料，其包含有机聚合物（E）的基体，均匀分散在有机聚合物（E）中的金属氧化物颗粒（C））和表面改性剂，用于使金属氧化物颗粒（C ）分散在有机聚合物（E）中，其中表面改性剂是具有与金属氧化物颗粒（C）的表面形成共价键的官能团的另一种有机聚合物（A）。

9. 发明授权

US06228796B1 Organic-inorganic hybrid materials and processes for preparing the same 失效
标题翻译：有机 - 无机杂化材料及其制备方法
公开(公告)号：US06228796B1
公开(公告)日：2001-05-08
申请号：US09472975
申请日：1999-12-28
申请人： Motoomi Arakawa , Kazuaki Sukata , Yasuyuki Agari , Masayuki Shimada
发明人： Motoomi Arakawa , Kazuaki Sukata , Yasuyuki Agari , Masayuki Shimada
IPC分类号： B01J3100
CPC分类号： B01J21/066 , B01D53/86 , B01D2255/802 , B01J21/063 , B01J31/069 , B01J35/002 , B01J35/004 , B01J37/0209 , B01J37/0244 , B01J37/033 , Y10T428/252 , Y10T428/31663
摘要： The present invention is made to provide an organic-inorganic hybrid material, a surface of which is supplied with a layer having photo-catalysis, without photo-degradation of the substrate. The present invention provides an organic-inorganic hybrid material comprising a substrate, an intermediate layer and a photo-catalysis layer which are sequentially formed on a surface of the substrate wherein, the intermediate layer is composed of an organic-inorganic hybrid polymer material in which an organic polymer component and a metal oxide component are covalently bonded each other, which is obtained by hydrolyzing and polycondensing a solution or a wet gel which comprises an organic polymer having an alkoxymetal group as a functional group or an organic polymer having a functional group reactable with a metal alkoxide compound, and a metal alkoxide compound, and the photo-catalysis layer is composed of metal oxides having photo-catalysis.
摘要翻译：本发明提供一种有机 - 无机混合材料，其表面被提供有光催化层，而不会使基板光降解。本发明提供了一种有机 - 无机混合材料，其包含依次形成在基板的表面上的基板，中间层和光催化层，其中，中间层由有机 - 无机杂化聚合物材料构成，其中有机聚合物组分和金属氧化物组分彼此共价键合，其通过水解和缩聚溶液或湿凝胶获得，所述溶液或湿凝胶包含具有烷氧基金属基团作为官能团的有机聚合物或具有可反应官能团的有机聚合物与金属醇盐化合物和金属醇盐化合物反应，光催化层由具有光催化作用的金属氧化物构成。

10. 发明授权

US6103854A Organic-inorganic hybrid polymer material and process for preparing the same 有权
标题翻译：有机 - 无机杂化聚合物材料及其制备方法
公开(公告)号：US6103854A
公开(公告)日：2000-08-15
申请号：US196787
申请日：1998-11-20
申请人： Motoomi Arakawa , Kazuaki Sukata , Yasuyuki Agari , Masayuki Shimada
发明人： Motoomi Arakawa , Kazuaki Sukata , Yasuyuki Agari , Masayuki Shimada
IPC分类号： C08G63/64 , C08G63/91 , C08G64/14 , C08G64/42 , C08G83/00 , C08G64/00
CPC分类号： C08G83/001 , C08G63/64 , C08G64/14 , C08G63/916 , C08G64/42
摘要： According to the present invention, the characteristics of an inorganic material are suitably supplied to an organic material, and the characteristics of an organic material are suitably supplied to an inorganic material. The organic-inorganic hybrid polymer is obtained by the process in which a polymer having a polycarbonate and/or a polyarylate moiety as a main frame and having a metal alkoxide group as a functional group, is hydrolyzed and polycondensed to form crosslinkages. Another process is that in which a polymer having a polycarbonate and/or a polyarylate moiety as a main frame and having a metal alkoxide group as a functional group, and a metal alkoxide compound are cohydrorized and copolycondensed to form crosslinkages.
摘要翻译：根据本发明，无机材料的特性适当地供给到有机材料中，有机材料的特性适当地供给到无机材料中。有机 - 无机杂化聚合物通过其中以聚碳酸酯和/或多芳基化合物部分为主体并具有金属醇盐基作为官能团的聚合物水解和缩聚以形成交联的方法获得。另一方法是其中具有聚碳酸酯和/或多芳基化合物部分作为主要框架并具有金属醇盐基团作为官能团的聚合物和金属醇盐化合物被共沉淀并共缩聚以形成交联。

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