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    • 3. 发明授权
    • Humidity and temperature corrections to improve accuracy of HF ambient air monitors based on tunable diode laser IR absorption measurements
    • 湿度和温度校正,以提高基于可调二极管激光IR吸收测量的HF环境空气监测器的精度
    • US08614096B2
    • 2013-12-24
    • US13223756
    • 2011-09-01
    • Manuel S. AlvarezDavid B. Spry
    • Manuel S. AlvarezDavid B. Spry
    • G01N33/00
    • G01N21/39G01N21/3504G01N33/006G01N2021/354G01N2021/3595G01N2021/399
    • Method of determining a total HF concentration metric in an environment including measuring an uncorrected HF concentration metric in the environment based on a first infrared absorption measurement at a wavelength corresponding to a vibrational frequency of a non-hydrogen bonded gas phase HF molecule; determining an ambient H2O concentration metric in the environment available for reaction with the non-hydrogen bonded gas phase HF molecules at or about the time of obtaining the first infrared absorption measurement; calculating a HF hydrate concentration metric in the environment based on the uncorrected HF concentration metric, the ambient H2O concentration metric and a reaction equilibrium relationship between the non-hydrogen bonded gas phase HF molecule and the HF hydrate; and determining the total HF concentration metric in the environment based on the uncorrected HF concentration metric and an amount of HF determined by the HF hydrate concentration metric.
    • 一种确定环境中的总HF浓度度量的方法,包括基于在与非氢键合气相HF分子的振动频率相对应的波长处的第一红外吸收测量来测量环境中未校正的HF浓度度量; 在获得第一红外吸收测量时或之前确定可用于与非氢键合气相HF分子反应的环境中的环境H 2 O浓度度量; 基于未校正的HF浓度度量,环境H 2 O浓度度量和非氢键合气相HF分子与HF水合物之间的反应平衡关系计算环境中的HF水合物浓度度量; 以及基于未校正的HF浓度度量和由HF水合物浓度度量确定的HF的量来确定环境中的总HF浓度度量。
    • 5. 发明申请
    • HUMIDITY AND TEMPERATURE CORRECTIONS TO IMPROVE ACCURACY OF HF AMBIENT AIR MONITORS BASED ON TUNABLE DIODE LASER IR ABSORPTION MEASUREMENTS
    • 基于TUNABLE二极管激光红外吸收测量提高HF环境空气监测器精度的湿度和温度校正
    • US20130059395A1
    • 2013-03-07
    • US13223756
    • 2011-09-01
    • Manuel S. ALVAREZDavid B. SPRY
    • Manuel S. ALVAREZDavid B. SPRY
    • G01N21/62
    • G01N21/39G01N21/3504G01N33/006G01N2021/354G01N2021/3595G01N2021/399
    • Method of determining a total HF concentration metric in an environment including measuring an uncorrected HF concentration metric in the environment based on a first infrared absorption measurement at a wavelength corresponding to a vibrational frequency of a non-hydrogen bonded gas phase HF molecule; determining an ambient H2O concentration metric in the environment available for reaction with the non-hydrogen bonded gas phase HF molecules at or about the time of obtaining the first infrared absorption measurement; calculating a HF hydrate concentration metric in the environment based on the uncorrected HF concentration metric, the ambient H2O concentration metric and a reaction equilibrium relationship between the non-hydrogen bonded gas phase HF molecule and the HF hydrate; and determining the total HF concentration metric in the environment based on the uncorrected HF concentration metric and an amount of HF determined by the HF hydrate concentration metric.
    • 一种确定环境中的总HF浓度度量的方法,包括基于在与非氢键合气相HF分子的振动频率相对应的波长处的第一红外吸收测量来测量环境中未校正的HF浓度度量; 在获得第一红外吸收测量时或之前确定可用于与非氢键合气相HF分子反应的环境中的环境H 2 O浓度度量; 基于未校正的HF浓度度量,环境H 2 O浓度度量和非氢键合气相HF分子与HF水合物之间的反应平衡关系计算环境中的HF水合物浓度度量; 以及基于未校正的HF浓度度量和由HF水合物浓度度量确定的HF的量来确定环境中的总HF浓度度量。
    • 6. 发明申请
    • DETERMINING THE RESONANCE PARAMETERS FOR MECHANICAL OSCILLATORS
    • 确定机械振荡器的共振参数
    • US20100324852A1
    • 2010-12-23
    • US12792500
    • 2010-06-02
    • H. Alan WolfChung-Min ChengGeorge AkehurstYvonne MathezDalia G. YablonAlan M. SchilowitzManuel S. Alvarez
    • H. Alan WolfChung-Min ChengGeorge AkehurstYvonne MathezDalia G. YablonAlan M. SchilowitzManuel S. Alvarez
    • G01D18/00
    • G01D1/00G01D15/00G01H13/00G01N17/04G01N29/46
    • The prior art describes the application of mechanical oscillators for the measurement of corrosion and/or deposition. Mechanical oscillators employ the use of resonance parameters, frequency and the quality factor Q, for the measurement of corrosion or deposition. However, the prior art does not consider the required precision for measuring frequency or Q in the presence of noise to make these measurements. In particular, the ability of the mechanical oscillator to measure small amounts of metal loss or deposition is not only dependent upon the mechanical design but is limited by the precision in determining the resonance frequency and Q. The present invention discloses methods for measuring these resonance parameters with a high precision in the presence of noise. This degree of precision is required to maximize the utility of these devices as sensitive probes for corrosion and deposition (fouling) measurement. All of the embodiments described herein employ curve fitting consistent with modeling the mechanical oscillator as a simple harmonic oscillator. This curve fitting procedure, combined with averaging and utilizing signal processing parameters to mitigate noise effects, adds considerable precision in measuring resonance parameters.
    • 现有技术描述了用于测量腐蚀和/或沉积的机械振荡器的应用。 机械振荡器采用谐振参数,频率和质量因子Q来测量腐蚀或沉积。 然而,现有技术不考虑在存在噪声的情况下测量频率或Q的所需精度以进行这些测量。 特别地,机械振荡器测量少量金属损失或沉积的能力不仅取决于机械设计,而且受到确定共振频率和Q的精度的限制。本发明公开了用于测量这些谐振参数的方法 在噪声的存在下具有高精度。 需要这种精度来最大限度地利用这些装置作为腐蚀和沉积(污垢)测量的敏感探头。 本文所述的所有实施例都使用与将机械振荡器建模为简单谐波振荡器一致的曲线拟合。 该曲线拟合程序,结合平均和利用信号处理参数来减轻噪声影响,增加了测量共振参数的相当大的精度。