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1. 发明授权

US08828103B2 Process for the preparation of an electrode from a porous material, electrode thus obtained and corresponding electrochemical system 有权
标题翻译：从多孔材料制备电极的方法，由此获得的电极和相应的电化学系统
公开(公告)号：US08828103B2
公开(公告)日：2014-09-09
申请号：US13243448
申请日：2011-09-23
申请人： Karim Zaghib , Abdelbast Guerfi , Patrick Charest , Robert Kostecki , Kimio Kinoshita , Michel Armand
发明人： Karim Zaghib , Abdelbast Guerfi , Patrick Charest , Robert Kostecki , Kimio Kinoshita , Michel Armand
IPC分类号： H01M6/00 , H01M4/02 , H01M4/13
CPC分类号： H01M4/0438 , C01B33/02 , H01M4/044 , H01M4/0461 , H01M4/0495 , H01M4/134 , H01M4/1395 , H01M4/366 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/405 , H01M4/505 , H01M4/525 , H01M4/624 , H01M4/625 , H01M10/052 , Y10T29/49108
摘要： Process for the preparation of electrodes from a porous material making it possible to obtain electrodes that are useful in electrochemical systems and that have at least one of the following properties: a high capacity in mAh/gram, a high capacity in mAh/liter, a good capacity for cycling, a low rate of self discharge, and a good environmental tolerance.
摘要翻译：用于从多孔材料制备电极的方法，使得可以获得可用于电化学系统并且具有以下特性中的至少一个的电极：以mAh /克的高容量，以mAh /升的高容量，a 良好的自行车能力，自放电率低，环境友好性好。

2. 发明申请

US20120017429A1 Process for the Preparation of an Electrode from a Porous Material, Electrode Thus Obtained and Corresponding Electrochemical System 有权
标题翻译：从多孔材料制备电极的方法，获得的电极和相应的电化学体系
公开(公告)号：US20120017429A1
公开(公告)日：2012-01-26
申请号：US13243448
申请日：2011-09-23
申请人： KARIM ZAGHIB , Abdelbast Guerfi , Patrick Charest , Robert Kostecki , Kimio Kinoshita , Michel Armand
发明人： KARIM ZAGHIB , Abdelbast Guerfi , Patrick Charest , Robert Kostecki , Kimio Kinoshita , Michel Armand
IPC分类号： H01M4/04
CPC分类号： H01M4/0438 , C01B33/02 , H01M4/044 , H01M4/0461 , H01M4/0495 , H01M4/134 , H01M4/1395 , H01M4/366 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/405 , H01M4/505 , H01M4/525 , H01M4/624 , H01M4/625 , H01M10/052 , Y10T29/49108
摘要： Process for the preparation of electrodes from a porous material making it possible to obtain electrodes that are useful in electrochemical systems and that have at least one of the following properties: a high capacity in mAh/gram, a high capacity in mAh/liter, a good capacity for cycling, a low rate of self discharge, and a good environmental tolerance.
摘要翻译：用于从多孔材料制备电极的方法，使得可以获得可用于电化学系统并且具有以下特性中的至少一个的电极：以mAh /克的高容量，以mAh /升的高容量，a 良好的自行车能力，自放电率低，环境友好性好。

3. 发明授权

US4898985A Process for preparing 3,5,5-trimethylcyclohexa-2-en-1,4-dione 失效
标题翻译：制备3,5,5-三甲基环己-2-烯-1,4-二酮的方法
公开(公告)号：US4898985A
公开(公告)日：1990-02-06
申请号：US254212
申请日：1988-10-06
申请人： Nobuhiko Ito , Kimio Kinoshita , Kiyonori Suzuki , Takeaki Eto
发明人： Nobuhiko Ito , Kimio Kinoshita , Kiyonori Suzuki , Takeaki Eto
IPC分类号： A61K8/35 , A61K8/00 , A61Q13/00 , B01J31/22 , C07B61/00 , C07C45/00 , C07C45/34 , C07C49/603 , C07C67/00 , C11B9/00
CPC分类号： C07C45/34
摘要： 3,5,5-Trimethylcyclohexa-2-en-1,4-diones is prepared by oxidizing 3,5,5-trimethylcyclohexa-3-en-one with molecular oxygen or a molecular oxygen-containing gas in the presence of an organic base and an organometallic complex catalyst comprising manganese, iron, cobalt or copper atom and at least four nitrogen atoms coordination-bonded thereto.

4. 发明授权

US4251600A Method of preparing a sintered lithium aluminate structure for containing electrolyte 失效
标题翻译：制备含有电解质的铝酸锂烧结体的方法
公开(公告)号：US4251600A
公开(公告)日：1981-02-17
申请号：US107760
申请日：1979-12-27
申请人： James W. Sim , Kimio Kinoshita
发明人： James W. Sim , Kimio Kinoshita
IPC分类号： C01F7/04 , C04B35/113 , H01M2/16 , H01M8/02 , H01M8/14 , B28B1/26
CPC分类号： H01M2/1646 , C01F7/043 , C04B35/113 , H01M8/0295 , H01M2300/0048
摘要： A porous sintered tile is formed of lithium aluminate for retaining moltenlectrolyte within a fuel cell. The tile is prepared by reacting lithium hydroxide in aqueous solution with alumina particles to form beta lithium aluminate particles. The slurry is evaporated to dryness and the solids dehydrated to form a beta lithium aluminate powder. The powder is compacted into the desired shape and sintered at a temperature in excess of 1200 K. but less than 1900 K. to form a porous integral structure that is subsequently filled with molten electrolyte. A tile of this type is intended for use in containing molten alkali metal carbonates as electolyte for use in a fuel cell having porous metal or metal oxide electrodes for burning a fuel gas such as hydrogen and/or carbon monoxide with an oxidant gas containing oxygen.
摘要翻译：多孔烧结砖由铝酸锂形成，用于将熔融电解质保持在燃料电池内。通过使氢氧化锂在水溶液中与氧化铝颗粒反应形成β铝酸锂颗粒来制备瓦。将浆料蒸发至干，固体脱水形成β-铝酸锂粉末。将粉末压实成所需的形状并在超过1200K但低于1900K的温度下烧结以形成随后用熔融电解质填充的多孔整体结构。这种瓷砖用于将熔融碱金属碳酸盐作为电解液用于含有多孔金属或金属氧化物电极的燃料电池中，所述多孔金属或金属氧化物电极用含氧气的氧化剂气体燃烧诸如氢气和/或一氧化碳的燃料气体。

5. 发明授权

US4115632A Method of preparing electrolyte for use in fuel cells 失效
标题翻译：制备用于燃料电池的电解质的方法
公开(公告)号：US4115632A
公开(公告)日：1978-09-19
申请号：US794295
申请日：1977-05-05
申请人： Kimio Kinoshita , John P. Ackerman
发明人： Kimio Kinoshita , John P. Ackerman
IPC分类号： C01F7/04 , H01M8/02 , H01M8/14 , H01M8/00
CPC分类号： H01M8/144 , C01F7/043 , H01M8/0295 , H01M8/142 , H01M8/145 , Y02E60/526
摘要： An electrolyte compact for fuel cells includes a particulate support material of lithium aluminate that contains a mixture of alkali metal compounds, such as carbonates or hydroxides, as the active electrolyte material. The porous lithium aluminate support structure is formed by mixing alumina particles with a solution of lithium hydroxide and another alkali metal hydroxide, evaporating the solvent from the solution and heating to a temperature sufficient to react the lithium hydroxide with alumina to form lithium aluminate. Carbonates are formed by reacting the alkali metal hydroxides with carbon dioxide gas in an exothermic reaction which may proceed simultaneously with the formation with the lithium aluminate. The mixture of lithium aluminate and alkali metal in an electrolyte active material is pressed or otherwise processed to form the electrolyte structure for assembly into a fuel cell.
摘要翻译：用于燃料电池的电解质压块包括含有碱金属化合物如碳酸盐或氢氧化物的混合物作为活性电解质材料的铝酸锂颗粒载体材料。通过将氧化铝颗粒与氢氧化锂和另一种碱金属氢氧化物的溶液混合，将溶剂从溶液中蒸发并加热到足以使氢氧化锂与氧化铝反应形成铝酸锂的温度来形成多孔铝酸锂载体结构。碳酸盐通过使碱金属氢氧化物与二氧化碳气体在放热反应中反应而形成，放热反应可与铝酸锂形成同时进行。将电解质活性材料中的铝酸锂和碱金属的混合物压制或以其它方式加工以形成用于组装成燃料电池的电解质结构。

6. 发明授权

US09444092B2 Potato-shaped graphite particles with low impurity rate at the surface, method for preparing the same 有权
标题翻译：表面杂质比低的马铃薯状石墨颗粒，其制备方法
公开(公告)号：US09444092B2
公开(公告)日：2016-09-13
申请号：US12572510
申请日：2009-10-02
申请人： Abdelbast Guerfi , Fernand Brochu , Kimio Kinoshita , Karim Zaghib
发明人： Abdelbast Guerfi , Fernand Brochu , Kimio Kinoshita , Karim Zaghib
IPC分类号： H01M4/133 , C01B31/04 , G01N27/407 , H01M2/02 , H01M4/04 , H01M4/583 , H01M10/0525 , H01M4/1393 , B01J20/32 , H01M4/96 , H01M4/02 , H01M4/86
CPC分类号： H01M4/133 , B01J20/3204 , B01J20/3236 , B01J20/3293 , C01B32/20 , C01P2002/72 , C01P2004/51 , C01P2004/61 , C01P2006/11 , C01P2006/12 , C01P2006/80 , G01N27/4075 , H01M2/0222 , H01M4/02 , H01M4/0402 , H01M4/0404 , H01M4/0409 , H01M4/1393 , H01M4/583 , H01M4/587 , H01M4/622 , H01M4/623 , H01M4/96 , H01M8/0234 , H01M10/052 , H01M10/0525 , H01M2004/021 , H01M2004/027 , H01M2004/8684 , Y02P70/56 , Y10T428/2918 , Y10T428/2967 , Y10T428/2991
摘要： Modified graphite particles obtained from graphite or based on graphite, the said particles having impurities in their internal structure and having on the surface a low, even nil, rate of an impurity or several impurities. In addition, these particles have at least one of the following characteristics: a tab density between 0.3 and 1.5 g/cc; a potatolike shape; and a granulometric dispersion such that the D90/D10 ratio varies between 2 and 5 and the particles have a size between 1 and 50 μm. These particles can be used for fuel cells, electrochemical generators, or as moisture absorbers and/or oxygen absorbers and they have important electrochemical properties. The electrochemical cells and batteries thus obtained are stable and safe.
摘要翻译：这些颗粒可用于燃料电池，电化学发生器，或作为吸湿剂和/或氧吸收剂，它们具有重要的电化学性能。由此获得的电化学电池和电池是稳定和安全的。

7. 发明申请

US20130011702A1 Redox Flow Battery System with Divided Tank System 审中-公开
标题翻译：具有分隔罐系统的氧化还原液流电池系统
公开(公告)号：US20130011702A1
公开(公告)日：2013-01-10
申请号：US13345599
申请日：2012-01-06
申请人： Craig R. Horne , Darren Bawden Hickey , Kimio Kinoshita , Ronald James Mosso , Bruce Lin
发明人： Craig R. Horne , Darren Bawden Hickey , Kimio Kinoshita , Ronald James Mosso , Bruce Lin
IPC分类号： H01M2/38 , H01M2/36
CPC分类号： H01M8/188 , B60L50/64 , B60L53/30 , B60L53/51 , B60L53/52 , B60L53/53 , B60L53/54 , B60L2210/40 , H01M8/20 , Y02E60/528 , Y02T10/7005 , Y02T10/705 , Y02T10/7094 , Y02T10/7241 , Y02T90/12 , Y02T90/121 , Y02T90/127 , Y02T90/14
摘要： A redox flow battery system is provided with one or more tanks for containing electrolytes. Embodiments of electrolyte tanks include active and/or passive dividers within a single tank structure. Dividers may be configured to prevent mixing of a charged electrolyte and a discharged electrolyte stored within a single tank.
摘要翻译：氧化还原液流电池系统设置有一个或多个用于容纳电解质的罐。电解液罐的实施例包括在单个罐结构内的有源和/或无源分配器。分隔器可以被配置为防止电荷电解质和存储在单个容器内的排出的电解质的混合。

8. 发明申请

US20070071669A1 Potatolike shaped graphite particles with low impurity rate at the surface, process for preparing same 审中-公开
标题翻译： Potatolike型石墨颗粒在表面具有低杂质，其制备方法
公开(公告)号：US20070071669A1
公开(公告)日：2007-03-29
申请号：US11606231
申请日：2006-11-30
申请人： Abdelbast Guerfi , Fernand Brochu , Kimio Kinoshita , Karim Zaghib
发明人： Abdelbast Guerfi , Fernand Brochu , Kimio Kinoshita , Karim Zaghib
IPC分类号： C01B31/04
CPC分类号： H01M4/133 , B01J20/3204 , B01J20/3236 , B01J20/3293 , C01B32/20 , C01P2002/72 , C01P2004/51 , C01P2004/61 , C01P2006/11 , C01P2006/12 , C01P2006/80 , G01N27/4075 , H01M2/0222 , H01M4/02 , H01M4/0402 , H01M4/0404 , H01M4/0409 , H01M4/1393 , H01M4/583 , H01M4/587 , H01M4/622 , H01M4/623 , H01M4/96 , H01M8/0234 , H01M10/052 , H01M10/0525 , H01M2004/021 , H01M2004/027 , H01M2004/8684 , Y02P70/56 , Y10T428/2918 , Y10T428/2967 , Y10T428/2991
摘要： Modified graphite particles obtained from graphite or based on graphite, the said particles having impurities in their internal structure and having on the surface a low, even nil, rate of an impurity or several impurities. In addition, these particles have at least one of the following characteristics: a tab density between 0.3 and 1.5 g/cc; a potatolike shape; and a granulometric dispersion such that the D90/D10 ratio varies between 2 and 5 and the particles have a size between 1 and 50 μm. These particles can be used for fuel cells, electrochemical generators, or as moisture absorbers and/or oxygen absorbers and they have important electrochemical properties. The electrochemical cells and batteries thus obtained are stable and safe.
摘要翻译：由石墨或石墨制成的改性石墨颗粒，所述颗粒具有内部结构的杂质，并且在表面上具有低甚至零的速率的杂质或几种杂质。此外，这些颗粒具有以下特征中的至少一个：凸片密度在0.3和1.5g / cc之间; potatolike形状; 和粒度分散体，使得D90 / D10比率在2和5之间变化，并且颗粒的尺寸在1和50μm之间。这些颗粒可用于燃料电池，电化学发生器，或作为吸湿剂和/或氧吸收剂，它们具有重要的电化学性能。由此获得的电化学电池和电池是稳定和安全的。

9. 发明申请

US20060062716A1 Method for the surface purification of a graphite containing impurities using a dilute aqueous solution of nh4f and h2so4 审中-公开
标题翻译：使用nh4f和h2so4的稀水溶液表面净化含有杂质的石墨的方法
公开(公告)号：US20060062716A1
公开(公告)日：2006-03-23
申请号：US10506212
申请日：2003-02-12
申请人： Karim Zaghib , Abdelbast Guerfi , Michael Armand , Claude Gagnon , Kimio Kinoshita
发明人： Karim Zaghib , Abdelbast Guerfi , Michael Armand , Claude Gagnon , Kimio Kinoshita
IPC分类号： H01M4/58 , C01B31/04
CPC分类号： H01M4/587 , C01B32/215 , H01M10/0525
摘要： Process for preparing particles of graphite that are purified in surface, from particles of an impure graphite, this process comprises at least one step of treating particles of graphite by means of a diluted aqueous solution of (H2SO4 and NH4F), H2SO4 and NH4F each being present in the diluted aqueous solution at a weight content representing from 5 to 30% of total weight of the aqueous solution, the quantity of diluted aqueous solution representing from 70 to 95% of the weight of the particles of graphite that undergo purification.
摘要翻译：用于制备表面上纯化的石墨颗粒的方法，由不纯的石墨的颗粒，该方法包括通过稀释的（H 2 SO 2）水溶液处理石墨颗粒的至少一个步骤 H 4和SO 4 F，H 2 SO 4和NH 4 F 各自以水溶液总重量的5〜30重量％存在于稀释水溶液中，稀释水溶液的量为进行纯化的石墨颗粒重量的70〜95％。

10. 发明授权

US5874166A Treated carbon fibers with improved performance for electrochemical and chemical applications 失效
标题翻译：经处理的碳纤维具有改善的电化学和化学应用性能
公开(公告)号：US5874166A
公开(公告)日：1999-02-23
申请号：US708151
申请日：1996-08-22
申请人： Xi Chu , Kimio Kinoshita
发明人： Xi Chu , Kimio Kinoshita
IPC分类号： H01M4/58 , H01M4/62
CPC分类号： H01M4/587 , H01M4/625 , Y10T428/292
摘要： A treated mesophase carbon fiber is disclosed having a high density of exposed edges on the fiber surface, and a method of making such a treated fiber. A carbon electrode is also described which is constructed from such treated mesophase carbon fibers. The resulting electrode, formed from such treated flexible carbon fibers, is characterized by a high density of active sites formed from such exposed edges, low corrosion, and good mechanical strength, and may be fabricated into various shapes. The treated mesophase carbon fibers of the invention are formed by first loading the surface of the mesophase carbon fiber with catalytic metal particles to form catalytic etch sites on a hard carbon shell of the fiber. The carbon fiber is then subject to an etch step wherein portions of the hard carbon shell or skin are selectively removed adjacent the catalytic metal particles adhering to the carbon shell. This exposes the underlying radial edges of the graphite-like layers within the carbon shell of the mesophase carbon fiber, which exposed radial edges then act as active sites of a carbon electrode subsequently formed from the treated mesophase carbon fibers.
摘要翻译：公开了在纤维表面上具有高密度的暴露边缘的处理的中间相碳纤维，以及制备这种处理过的纤维的方法。还描述了由这种处理的中间相碳纤维构成的碳电极。由这种处理的柔性碳纤维形成的所得电极的特征在于由这种暴露边缘形成的高密度的活性位点，低腐蚀性和良好的机械强度，并且可以制造成各种形状。本发明的处理的中间相碳纤维通过首先将中间相碳纤维的表面与催化金属颗粒加载形成，以在纤维的硬碳壳上形成催化蚀刻位点。然后对碳纤维进行蚀刻步骤，其中硬碳壳或皮肤的部分被选择性地除去附着在碳壳上的催化金属颗粒附近。这暴露了中间相碳纤维的碳壳内的石墨状层的下面的径向边缘，其暴露的径向边缘然后作为随后由处理的中间相碳纤维形成的碳电极的活性位点。

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