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    • 5. 发明申请
    • METHOD FOR PRODUCING WATER-INSOLUBLE LIQUEFIED FUEL OIL FROM BIOMASS
    • 从生物量生产水不溶性液化燃料油的方法
    • US20100312027A1
    • 2010-12-09
    • US12794386
    • 2010-06-04
    • Kazushi TSURUTANITsutomu SAKAIMitsuru KONDO
    • Kazushi TSURUTANITsutomu SAKAIMitsuru KONDO
    • C10G1/00
    • C10G1/04C10G1/002C10G3/49C10G3/50C10G2300/1014C10G2300/4081C10G2300/44C10G2300/805Y02P30/10Y02P30/20
    • A method for producing a water-insoluble liquefied fuel oil containing a hydrocarbon from biomass is provided, comprising converting an oxygen-containing compound in a liquefied fuel oil obtained after liquefaction to a hydrocarbon and converting a water-soluble organic substance contained in an aqueous phase to a hydrocarbon, thereby improving the yield of the water-insoluble liquefied fuel oil. The method for producing a water-insoluble liquefied fuel oil containing a hydrocarbon comprises the steps of: subjecting a mixture that contains biomass containing lignocellulose, an organic solvent, and water to liquefaction; simultaneously with or after liquefaction, causing a mixture of the liquefied fuel oil that contains the organic solvent and an aqueous phase that contains a water-soluble organic substance to come into contact with a dehydration catalyst under pressure and then subjecting the resultant to dehydration, or causing a mixture of the liquefied fuel oil that contains the organic solvent and an aqueous phase that contains a water-soluble organic substance to come into contact with hydrogen in the presence of a hydrogenation catalyst under pressure, and then subjecting the resultant to hydrogenation; and separating a water-insoluble liquefied fuel oil from the mixture after dehydration or hydrogenation.
    • 提供了一种从生物质中生产含有烃的水不溶性液化燃料油的方法,包括将液化后获得的液化燃料油中的含氧化合物转化成烃,并将水相中所含的水溶性有机物质 从而提高了不溶于水的液化燃料油的产率。 含有烃的水不溶性液化燃料油的制造方法包括以下步骤:使含有木质纤维素,有机溶剂和水的生物质的混合物液化; 在液化之后或之后,使含有有机溶剂的液化燃料油和含有水溶性有机物的水相的混合物在压力下与脱水催化剂接触,然后使所得物脱水,或 使含有有机溶剂的液化燃料油和含有水溶性有机物质的水相在氢化催化剂的存在下与氢气接触的混合物在压力下进行氢化; 并在脱水或氢化后从混合物中分离出不溶于水的液化燃料油。
    • 7. 发明授权
    • Gas oil (law451)
    • 瓦斯油(法律451)
    • US5730762A
    • 1998-03-24
    • US690445
    • 1996-07-26
    • Kazuyuki MurakamiShoukichi YamamotoYutaka HasegawaKazushi Tsurutani
    • Kazuyuki MurakamiShoukichi YamamotoYutaka HasegawaKazushi Tsurutani
    • C10L1/08C10L1/14C10L1/16C10L1/22C10L1/232C10L10/02C10L10/04
    • C10L10/08C10L1/08C10L1/14C10L1/232C10L10/02C10L10/14C10L1/1608C10L1/1616
    • A gas oil according to the present invention comprises a gas oil fraction, and has a sulfur content not higher than 0.05 wt %, and either or both of (1) a content of bicyclic and higher aromatic hydrocarbons in a range of from 3.5 wt % to 15 wt %, bicyclic and higher aromatic hydrocarbons having at least one side-chain C.sub.3-11 alkyl group amounting to at least 80 wt % of said first-mentioned bicyclic and higher aromatic hydrocarbons, and (2) a content of nitrogen-containing heterocyclic compounds in a range of from 80 ppm to 500 ppm, nitrogen-containing heterocyclic compounds having at least one side-chain alkyl group accounting for at least 90 wt % of said first-mentioned nitrogen-containing heterocyclic compounds. The gas oil according to the present invention, as a diesel fuel, can impart anti-wearing properties by simply adjusting its components without the need for incorporation of an additive such as an anti-wearing agent. It does not cause wearing of a fuel injection pump, has excellent storage stability and can be furnished as an economical gas oil. It can also be furnished as a gas oil suited for use especially in cold districts.
    • 根据本发明的瓦斯油包含粗柴油馏分,硫含量不高于0.05重量%,并且(1)双环和高级芳烃的含量为3.5重量% 至少15重量%,具有至少一个侧链C3-11烷基的双环和高级芳族烃占所述第一提到的双环和高级芳烃的至少80重量%,和(2)含氮的 80ppm至500ppm范围的杂环化合物,至少含有一个侧链烷基的含氮杂环化合物占所述第一提到的含氮杂环化合物的至少90重量%。 根据本发明的瓦斯油作为柴油燃料,可以通过简单地调节其组分而赋予抗磨损性,而不需要加入诸如耐磨剂的添加剂。 不会引起燃油喷射泵的磨损,具有良好的储存稳定性,并且可以作为经济的瓦斯油来提供。 它也可以作为适用于特别是在寒冷地区使用的瓦斯油来提供。