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1. 发明授权

US5665435A Method for fluorination of diamond surfaces 失效
标题翻译：金刚石表面氟化方法
公开(公告)号：US5665435A
公开(公告)日：1997-09-09
申请号：US521894
申请日：1995-08-31
申请人： Vincent S. Smentkowski , John T. Yates, Jr.
发明人： Vincent S. Smentkowski , John T. Yates, Jr.
IPC分类号： B05D3/06 , B05D5/08 , C01B31/06 , C04B41/50 , C23C16/26 , C23C16/56 , G11B5/725 , G11B5/84
CPC分类号： C23C16/26 , B05D3/06 , B05D5/08 , C01B31/065 , C04B41/5019 , C04B41/5093 , C23C16/56 , G11B5/725 , G11B5/8408 , Y10T428/30
摘要： An improved method for the fluorination of a diamond surfaces comprises condensing a layer of perfluorinated alkyl iodides consisting of C.sub.n F.sub.2n+1 I (where n is a positive integer from 1 to 13) on the diamond surface, producing perfluorinated alkyl free radicals by photodecomposing C--I bonds of said perfluorinated alkyl iodides on the diamond surface, reacting the diamond surface with photochemically produced perfluorinated alkyl radicals thereby anchoring photochemically induced photofragments of the perfluorinated alkyl iodides to the diamond surface forming a perfluorinated alkyl layer, and decomposing the perfluorinated alkyl layer on the diamond surface to cause the fluorination of the diamond surface by atomic F. The method achieves greater than one fluorine atom per surface carbon atom chemisorbed on the diamond using C.sub.4 F.sub.9 I.
摘要翻译：用于金刚石表面氟化的改进方法包括将由CnF2n + 1I（其中n为1至13的正整数）组成的全氟化烷基碘层凝集在金刚石表面上，通过光致分解CI键来产生全氟化烷基自由基所述金刚石表面上的全氟化烷基碘化物使金刚石表面与光化学产生的全氟化烷基反应，从而将全氟化烷基碘化物的光化学诱导的光致斑片锚定到形成全氟化烷基层的金刚石表面，并将金刚石表面上的全氟化烷基层分解成导致金刚石表面被原子F氟化。该方法使用C4F9I在金刚石上化学吸附表面碳原子上大于一个氟原子。

2. 发明授权

US5028575A Process for the chemical modification of aluminum oxide supported rhodium catalysts and associated automotive catalyst 失效
标题翻译：氧化铝负载铑催化剂和相关汽车催化剂的化学改性方法
公开(公告)号：US5028575A
公开(公告)日：1991-07-02
申请号：US515385
申请日：1990-04-27
申请人： John T. Yates, Jr. , Dilip K. Paul , Todd H. Ballinger
发明人： John T. Yates, Jr. , Dilip K. Paul , Todd H. Ballinger
IPC分类号： B01D53/94 , B01J23/46
CPC分类号： B01D53/945 , B01J23/464 , Y02T10/22
摘要： A process for chemically removing surface hydroxyl groups present on an aluminum oxide supported rhodium catalyst that is suitable for use as an automotive catalyst in controlling automative exhaust emissions is disclosed. The process includes removing the hydroxyl groups from the aluminum oxide supported catalyst by silation at a temperature preferably equal to or greater than about 450 K so that the conversion of active metallic rhodium Rh.sub.x (0) to oxidized rhodium species Rh.sup.(I) cannot substantially occur by reduction of the active hydroxyl groups. The silation is carried out by exposing the aluminum oxide supported rhodium catalyst to a gas phase alkylhalosilane. Subsequent to the silation, evacuation of the alkylhalosilane treated aluminum oxide supported rhodium catalyst is effected to remove substantially all unreacted alkylhalosilane. An associated catalyst suitable for use in automotive catalytic converter technology for environmental protection is also provided.
摘要翻译：公开了一种用于化学去除存在于氧化铝负载的铑催化剂上的表面羟基的方法，其适用于控制汽车尾气排放物中的汽车催化剂。该方法包括通过在优选等于或大于约450K的温度下进行硅酸化从氧化铝负载的催化剂中除去羟基，使得活性金属铑Rhx（0）转化成氧化铑类Rh（I）不能基本上发生通过还原活性羟基。通过将氧化铝负载的铑催化剂暴露于气相烷基卤代硅烷来进行硅酸盐化。在沉淀之后，进行烷基卤代硅烷处理的氧化铝负载的铑催化剂的抽真空以除去基本上所有未反应的烷基卤硅烷。还提供了适用于环境保护的汽车催化转化器技术的相关催化剂。

3. 发明授权

US4663297A Temperature programmed spectroscopy techniques 失效
标题翻译：温度程序光谱技术
公开(公告)号：US4663297A
公开(公告)日：1987-05-05
申请号：US416666
申请日：1982-09-10
申请人： John T. Yates, Jr. , Gregory L. Griffin , Maya Kiskinova
发明人： John T. Yates, Jr. , Gregory L. Griffin , Maya Kiskinova
IPC分类号： G01N25/14 , G01N30/00 , G01N30/12 , H01J49/04 , G01N15/00 , G01N37/00
CPC分类号： H01J49/0077 , G01N25/14 , G01N30/00 , H01J49/049 , G01N2030/128
摘要： Temperature programmed spectroscopy wherein particles of a substrate under investigation are attached in a non-overlapping manner to a heating filament. The temperature of the filament is increased in a controlled manner, thus increasing the temperature of the attached substrate particles as well. An instrument for analyzing the gases is a mass spectrometer. Gases desorbed from the particles can be studied according to this technique, or the nature of heterogeneous catalytic chemical reactions of a gaseous atmosphere on the particles' surface may alternatively be detected and studied.
摘要翻译：温度程序化光谱法，其中正在研究的基底的颗粒以不重叠的方式连接到加热丝。以受控的方式增加丝的温度，从而也增加了附着的基底颗粒的温度。用于分析气体的仪器是质谱仪。可以根据该技术研究从颗粒中脱附的气体，或者可以检测和研究气态气体在颗粒表面上的非均相催化化学反应的性质。

4. 发明授权

US4871526A Heterogeneous catalytic oxidation of organophosphonate esters 失效
标题翻译：有机膦酸酯的非均相催化氧化
公开(公告)号：US4871526A
公开(公告)日：1989-10-03
申请号：US260478
申请日：1988-10-20
申请人： Vincent S. Smentkowski , Patrick L. Hagans , John T. Yates, Jr.
发明人： Vincent S. Smentkowski , Patrick L. Hagans , John T. Yates, Jr.
IPC分类号： A62D3/00 , A62D3/38 , A62D101/02 , A62D101/04 , A62D101/26 , A62D101/28
CPC分类号： A62D3/38 , A62D2101/02 , A62D2101/04 , A62D2101/26 , A62D2101/28 , A62D2203/10
摘要： A method of catalytic oxidation of organophosphonate esters includes introducing the organophosphonate esters in gaseous form into contact with a molybdenum catalyst and effecting such introduction in the presence of oxygen to cause the organophosphonate ester to be oxidized on the molybdenum catalyst surface. The process is preferably carried out at a temperature of at least 900.degree. K. in the presence of excess oxygen. A chemisorbed oxide coating or molybdenum oxide coating or both may be established on all or part of the molybdenum catalyst. Among the organophosphonate esters which may be oxidized in this manner are dimethyl methylphosphonate, diisopropyl methylphosphonate, diphenyl methylphosphonate, and other molecules with the structure: ##STR1## The catalytic oxidation results in emission of carbon monoxide and phosphorus oxides(s) without undesired buildup of carbonaceous or phosphorus overlayers on the Mo catalyst surface.
摘要翻译：有机膦酸酯的催化氧化方法包括将有机膦酸酯以气态形式与钼催化剂接触，并在氧的存在下进行这种引入，使有机膦酸酯在钼催化剂表面上被氧化。该方法优选在过量氧的存在下在至少900°K的温度下进行。可以在全部或部分钼催化剂上建立化学吸附氧化物涂层或氧化钼涂层或两者。可以以这种方式被氧化的有机膦酸酯可以是甲基膦酸二甲酯，甲基膦酸二异丙酯，甲基膦酸二苯基酯和具有以下结构的其它分子：催化氧化导致一氧化碳和磷氧化物的排放，碳质或磷覆盖层在Mo催化剂表面上。

5. 发明授权

US5840426A Method for fluorination of diamond surfaces and associated product 失效
标题翻译：金刚石表面及相关产品的氟化方法
公开(公告)号：US5840426A
公开(公告)日：1998-11-24
申请号：US798311
申请日：1997-02-07
申请人： Vincent S. Smentkowski , John T. Yates, Jr.
发明人： Vincent S. Smentkowski , John T. Yates, Jr.
IPC分类号： B05D3/06 , B05D5/08 , C01B31/06 , C04B41/50 , C23C16/26 , C23C16/56 , G11B5/725 , G11B5/84 , B32B9/00
CPC分类号： C23C16/26 , B05D3/06 , B05D5/08 , C01B31/065 , C04B41/5019 , C04B41/5093 , C23C16/56 , G11B5/725 , G11B5/8408 , Y10T428/30
摘要： An improved method for the fluorination of a diamond surfaces comprises condensing a layer of perfluorinated alkyl iodides consisting of C.sub.n F.sub.2n+1 I (where n is a positive integer from 1 to 13) on the diamond surface, producing perfluorinated alkyl free radicals by photodecomposing C--I bonds of said perfluorinated alkyl iodides on the diamond surface, reacting the diamond surface with photochemically produced perfluorinated alkyl radicals thereby anchoring photochemically induced photofragments of the perfluorinated alkyl iodides to the diamond surface forming a perfluorinated alkyl layer, and decomposing the perfluorinated alkyl layer on the diamond surface to cause the fluorination of the diamond surface by atomic F. The method achieves greater than one fluorine atom per surface carbon atom chemisorbed on the diamond using C.sub.4 F.sub.9 I. A fluorinated diamond made by the above method is also disclosed wherein a fluorinating perfluoroalkyl iodide, C.sub.n F.sub.2n+1 I, is selected from the group consisting of n=1 to 5. In one case, the fluorinating perfluoroalkyl iodide is C.sub.4 F.sub.9 I. In another case, it is CF.sub.3 I.
摘要翻译：用于金刚石表面氟化的改进方法包括将由CnF2n + 1I（其中n为1至13的正整数）组成的全氟化烷基碘层凝集在金刚石表面上，通过光致分解CI键来产生全氟化烷基自由基所述金刚石表面上的全氟化烷基碘化物使金刚石表面与光化学产生的全氟化烷基反应，从而将全氟化烷基碘化物的光化学诱导的光致斑片锚定到形成全氟化烷基层的金刚石表面，并将金刚石表面上的全氟化烷基层分解成导致金刚石表面被原子F氟化。该方法使用C4F9I在金刚石上化学吸附表面碳原子上大于一个氟原子。还公开了通过上述方法制备的氟化金刚石，其中氟化全氟烷基碘CnF2n + 1I选自n = 1至5.在一种情况下，氟化全氟烷基碘为C 4 F 9 I。在另一种情况下，它是CF3I。

6. 发明授权

US5492880A Process for the inorganic chemical modification of rhodium alumina catalysts and automotive catalyst made by the process 失效
标题翻译：铑氧化铝催化剂和汽车催化剂无机化学改性方法
公开(公告)号：US5492880A
公开(公告)日：1996-02-20
申请号：US259737
申请日：1994-06-01
申请人： Mohamed I. Zaki , Todd H. Ballinger , John T. Yates, Jr.
发明人： Mohamed I. Zaki , Todd H. Ballinger , John T. Yates, Jr.
IPC分类号： B01D53/94 , B01J23/02 , B01J23/58 , B01J37/08 , B01J37/14 , B01J21/04
CPC分类号： B01J23/02 , B01D53/944 , B01J23/58 , B01J37/08
摘要： A process for chemically converting surface hydroxyl groups present on an uminum oxide supported rhodium catalyst that is suitable for use as an automotive catalyst in controlling automotive exhaust emissions is disclosed. The process includes converting the hydroxyl groups on the aluminum oxide supported catalyst by reacting the aluminum oxide support with an alumina modifier which comprises an inorganic compound containing the cation Y, wherein Y is either an alkali metal or an alkaline earth metal. This process involves replacing the hydroxyl groups on the aluminum oxide support with OY groups to resist the oxidative conversion of supported metallic rhodium Rh.sub.x .sup.(O) to Rh.sup.(I). An associated catalyst suitable for use in automotive catalytic converter technology for environmental protection is provided.
摘要翻译：公开了一种用于化学转化存在于氧化铝负载的铑催化剂上的表面羟基的方法，其适用于控制汽车废气排放物中的汽车催化剂。该方法包括通过使氧化铝载体与包含阳离子Y的无机化合物的氧化铝改性剂反应使氧化铝载体催化剂上的羟基转化，其中Y为碱金属或碱土金属。该方法包括用OY基团取代氧化铝载体上的羟基以抵抗负载的金属铑Rh（O）至Rh（I）的氧化转化。提供了适用于环境保护的汽车催化转化器技术的相关催化剂。

7. 发明授权

US5698272A Method for lubrication of diamond-like carbon surfaces 失效
标题翻译：类金刚石表面的润滑方法
公开(公告)号：US5698272A
公开(公告)日：1997-12-16
申请号：US764392
申请日：1996-12-11
申请人： Vincent S. Smentkowski , John T. Yates, Jr.
发明人： Vincent S. Smentkowski , John T. Yates, Jr.
IPC分类号： B05D3/06 , B05D5/08 , C01B31/06 , C04B41/50 , C23C16/26 , C23C16/56 , G11B5/725 , G11B5/84
CPC分类号： B05D3/06 , B05D5/08 , C01B31/065 , C04B41/5019 , C04B41/5093 , C23C16/26 , C23C16/56 , G11B5/725 , G11B5/8408
摘要： An improved method for the lubrication of diamond-like carbon surfaces comprises condensing a layer of perflourinated alkyl halides of the formula C.sub.n F.sub.2n+1 X, wherein n is a positive integer from 1 to 13 and X is selected from I, Br and Cl, on the diamond-like carbon surface. Perflourinated alkyl free radicals are then produced by photodecomposing C--X bonds of said perflourinated alkyl halides on the surface. The diamond-like carbon surface is reacted with photochemically produced perflourinated alkyl radicals thereby anchoring photochemically induced photofragments of the perflourinated alkyl halides to the surface forming a perflourinated alkyl layer. The perfluorinated alkyl layer is preferably decomposed on the diamond-like carbon surface to cause the fluorination of the surface by atomic F. The method preferably achieves greater than one fluorine atom per surface carbon atom chemisorbed on the diamond-like carbon. The fluorination process produces lubricated diamond-like carbon surfaces that are particularly suitable for computer hard disks.
摘要翻译：用于润滑类金刚石碳表面的改进方法包括将式CnF2n + 1X的全氟化烷基卤化物层，其中n是1至13的正整数，X选自I，Br和Cl，类金刚石表面。然后通过在所述表面上光刻分解所述全氟化烷基卤化物的C-X键来产生经过饱和的烷基自由基。将类金刚石碳表面与光化学产生的全氟化烷基反应，从而将全氟化烷基卤化物的光化学诱导的光片锚定到形成全氟化烷基层的表面。全氟化烷基层优选在类金刚石碳表面上分解，以通过原子F使表面氟化。该方法优选在金刚石状碳上化学吸附表面碳原子上大于一个氟原子。氟化过程产生特别适用于计算机硬盘的润滑的类金刚石碳表面。

8. 发明授权

US4877584A Temperature programmed spectroscopy techniques 失效
标题翻译：温度程序光谱技术
公开(公告)号：US4877584A
公开(公告)日：1989-10-31
申请号：US41594
申请日：1987-04-22
申请人： John T. Yates, Jr. , Gregory L. Griffin , Maya Kiskinova
发明人： John T. Yates, Jr. , Gregory L. Griffin , Maya Kiskinova
IPC分类号： G01N25/14 , G01N30/00 , G01N30/12 , H01J49/04
CPC分类号： H01J49/049 , G01N25/14 , G01N30/00 , H01J49/0077 , G01N2030/128
摘要： Temperature programmed spectroscopy wherein particles of a substrate under investigation are attached in a non-overlapping manner to a heating filament. The temperature of the filament is increased in a controlled manner, thus increasing the temperature of the attached substrate particles as well. An instrument for analyzing the gases is a mass spectrometer. Gases desorbed from the particles can be studied according to this technique, or the nature of heterogeneous catalytic chemical reactions of a gaseous atmosphere on the particles' surface may alternativelRIGHTS OF THE U.S. GOVERNMENTThe invention described herein may be manufactured and used by or for the Government of the United States without the payment of any royalties thereon or therefor.
摘要翻译：温度程序化光谱法，其中正在研究的基底的颗粒以不重叠的方式连接到加热丝。以受控的方式增加丝的温度，从而也增加了附着的基底颗粒的温度。用于分析气体的仪器是质谱仪。可以根据该技术研究从颗粒中脱附的气体，或者可以检测和研究气态气体在颗粒表面上的非均相催化化学反应的性质。

9. 发明授权

US06852903B1 Decontamination of chemical warfare agents using a reactive sorbent 失效
标题翻译：使用反应性吸附剂去除化学战剂
公开(公告)号：US06852903B1
公开(公告)日：2005-02-08
申请号：US10162055
申请日：2002-06-04
申请人： Roy S. Brown , Joseph A. Rossin , James E. Kotary , Gyleen Fitzgerald , Karl G. Gerhart , Helen A. Mearns , Richard A. Newton , Joseph H. Keller , Douglas B. Mawhinney , John T. Yates, Jr.
发明人： Roy S. Brown , Joseph A. Rossin , James E. Kotary , Gyleen Fitzgerald , Karl G. Gerhart , Helen A. Mearns , Richard A. Newton , Joseph H. Keller , Douglas B. Mawhinney , John T. Yates, Jr.
IPC分类号： A62D3/00 , A62D3/36 , A62D101/02 , A62D101/26 , A62D101/28
CPC分类号： A62D3/36 , A62D2101/02 , A62D2101/26 , A62D2101/28
摘要： The invention provides reactive sorbents and methods of making and using the same in order to decontaminate surfaces contaminated with toxic agents, such as chemical warfare agents and/or industrial toxins. The reactive sorbents are of two general types, one of which comprises dehydroxylated aluminum oxide and the other comprises porous carbon impregnated with a reactive solution, so that both sorbents take up and then detoxify toxic agents.
摘要翻译：本发明提供反应性吸附剂及其制造和使用方法，以便去除被有毒物质如化学战剂和/或工业毒素污染的表面。反应性吸附剂是两种一般类型，其中之一包括脱羟基化氧化铝，另一种包括浸渍有反应性溶液的多孔碳，使得两种吸附剂吸收然后使毒性剂解毒。

10. 发明授权

US5573592A Method for forming pure group III-V compound semi-conductor films 失效
标题翻译：纯III-V族复合半导体薄膜的制备方法
公开(公告)号：US5573592A
公开(公告)日：1996-11-12
申请号：US361838
申请日：1994-12-22
申请人： Andreas H ubner , Scott R. Lucas , William D. Partlow , W. J. Choyke , J. A. Sch afer , John T. Yates, Jr.
发明人： Andreas H ubner , Scott R. Lucas , William D. Partlow , W. J. Choyke , J. A. Sch afer , John T. Yates, Jr.
IPC分类号： C30B25/02 , C30B25/20
CPC分类号： C30B25/02 , C30B29/40 , C30B29/406
摘要： This invention discloses a method of synthesizing a Group III-V compound semi-conducting film from a Group III metal alkyl and Group V hydride wherein the method comprises providing a vacuum chamber in which the synthesis takes place, adsorbing at least one monolayer of said Group III metal alkyl on an inert surface, backfilling the chamber with a Group V hydride, adsorbing the Group V hydride on the inert surface, providing atomic hydrogen atoms from electron-induced dissociation of Group V hydride adsorbed on the surface, inducing an electron-induced depletion of carbon at a rate which is dependent on the pressure of the Groups V hydride, retaining substantially all Group III metal on the surface and providing a thermally stable Group III-V compound semi-conducting film on the inert SiO.sub.2 surface. Methods for synthesizing a multilayer Group III-V semi-conducting film and specifically a GaN film are also disclosed, along with the apparatus for the synthesis of Group III-V compound semi-conducting films.
摘要翻译：本发明公开了一种由III族金属烷基和V族氢化物合成III-V族化合物半导电膜的方法，其中所述方法包括提供其中发生合成的真空室，吸附所述组的至少一个单层 III族金属烷基在惰性表面上，用V族氢化物回填室，将V族氢化物吸附在惰性表面上，从吸附在表面上的V族氢化物的电子诱导解离提供原子氢原子，诱导电子诱导以取决于V族氢化物的压力的速率消耗碳，并在表面上保留基本上所有的III族金属，并在惰性SiO 2表面上提供热稳定的III-V族化合物半导电膜。还公开了用于合成III-V族化合物半导体膜的多层III-V族半导体膜，特别是GaN膜的方法。

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