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    • 1. 发明授权
    • Surfactant compositions and uses therefor
    • 表面活性剂组合物及其用途
    • US06302209B1
    • 2001-10-16
    • US09151169
    • 1998-09-10
    • Joseph E. Thompson, Sr.Harold D. BrannonGeorge Tso-Chih WooWilliam R. WoodJeffrey C. DawsonMarshall G. Ault
    • Joseph E. Thompson, Sr.Harold D. BrannonGeorge Tso-Chih WooWilliam R. WoodJeffrey C. DawsonMarshall G. Ault
    • E21B4300
    • B01F17/0028B01F17/0042B01F17/0057C09K8/035C09K8/602
    • Solid surfactant suspension compositions are formed by combining solid surfactants, such as alpha-olefin sulfonates, with an organic base fluid, such as diesel. Solid surfactant suspensions may be combined with an aqueous carrier fluid to form surfactant-containing fluids suitable for, among other things, forming foams or for water wetting surfaces. Solid surfactant suspensions may also be combined with additive materials, such as polymer particles, to form a dispersion or emulsion. Polymer-containing solid surfactant suspensions may also be combined with aqueous carrier fluids to form, for example, viscosified, gelled, or foamed fluids. Concentration of solid surfactant materials contained in a solid surfactant suspension may be varied to affect the function the solid surfactant suspension. For example, the solid surfactant material may function as a polymer surface wetting agent, an emulsifier, a dispersant, a viscosifier, and/or a foamer in well completion and remedial and/or workover fluids.
    • 固体表面活性剂悬浮液组合物通过将固体表面活性剂如α-烯烃磺酸盐与有机基础流体如柴油混合而形成。 固体表面活性剂悬浮液可以与含水载体流体组合以形成适于尤其形成泡沫或用于水润湿表面的含表面活性剂的流体。 固体表面活性剂悬浮液也可以与添加剂材料如聚合物颗粒结合以形成分散体或乳液。 含聚合物的固体表面活性剂悬浮液也可以与含水载体流体混合以形成例如粘稠的,胶凝的或发泡的流体。 包含在固体表面活性剂悬浮液中的固体表面活性剂材料的浓度可以变化以影响固体表面活性剂悬浮液的功能。 例如,固体表面活性剂材料可用作完井和补救和/或修井液中的聚合物表面润湿剂,乳化剂,分散剂,增粘剂和/或起泡剂。
    • 7. 发明授权
    • Fracturing fluid treatment design to optimize fluid rheology and
proppant pack conductivity
    • 压裂液处理设计,优化流体流变性和支撑剂包装电导率
    • US5562160A
    • 1996-10-08
    • US544572
    • 1995-10-18
    • Harold D. BrannonRobert M. Tjon-Joe-Pin
    • Harold D. BrannonRobert M. Tjon-Joe-Pin
    • C09K8/68E21B43/267E21B49/00
    • E21B43/267C09K8/685
    • A method of fracturing a subterranean formation in a well bore is shown in which a gellable fracturing fluid is first formed by blending together an aqueous fluid, a hydratable polymer, a suitable cross-linking agent for cross-linking the hydratable polymer to form a polymer gel and an enzyme breaker. The cross-linked polymer gel is pumped into the well bore under sufficient pressure to fracture the surrounding formation. The enzyme breaker is allowed to degrade the cross-linked polymer with time to reduce the viscosity of the fluid so that the fluid can be pumped from the formation back to the well surface. The particular enzyme breaker utilized has an activity in the temperature range from about 60.degree.-300.degree. F. and at a pH range from about 2.0 to 11.0 and is effective to attack only specific linkages in the cross-linked polymer gel.
    • 示出了在井眼中压裂地层的方法,其中首先通过将水性流体,可水合聚合物,用于交联可水合聚合物的合适的交联剂混合在一起形成聚合物形成可凝胶化的压裂流体,形成聚合物 凝胶和酶切剂。 将交联聚合物凝胶在足够的压力下泵入井眼以破坏周围的地层。 允许酶破坏剂随时降解交联聚合物以降低流体的粘度,使得流体可以从地层泵送回井表面。 所使用的特定酶切剂在约60-300°F的温度范围和约2.0至11.0的pH范围内具有活性,并且仅有效地仅攻击交联聚合物凝胶中的特定键。
    • 8. 发明授权
    • Method of optimizing the conductivity of a propped fractured formation
    • 优化支撑断裂地层导电性的方法
    • US5103905A
    • 1992-04-14
    • US518771
    • 1990-05-03
    • Harold D. BrannonJanet GulbisMilton T. KingGeorge W. Hawkins
    • Harold D. BrannonJanet GulbisMilton T. KingGeorge W. Hawkins
    • C09K8/62C09K8/92E21B43/26E21B43/267
    • C09K8/92C09K8/62E21B43/26E21B43/267Y10S507/902Y10S507/921
    • Method of reducing the viscosity of a fracturing fluid containing a polymer by introducing both delayed breaker and nondelayed breaker into the fracturing fluid. Preferably, the relative amounts of delayed and undelayed breaker are determined by first determining the concentration of polymer in the fracture, determining the relationship of breaker concentration for a polymer concentration to proppant pack permeability, picking a desired proppant pack permeability, calculating the amount of breaker necessary to lessen the viscosity of the polymer concentration in the fracture to the desired permeability. This amount of breaker is X. Next, the minimum viscosity of the fracturing fluid which maintains the proppant in suspension in the fracture is determined. The amount of breaker Y which lessens the viscosity of the fracturing fluid no lower than this minimum viscosity is calculated for the bottom hole static temperature and an interval of time. The amount of delayed breaker Z which upon initial introduction into the fracturing fluid releases Y is calculated. Finally, if X is less than Y, no more than X amount of delayed breaker is introduced into the fracturing fluid; however if Y is less than X, no more than Z amount of delayed breaker is introduced into the fracturing fluid. Additionally, Y amount of nondelayed breaker may be introduced into the fracturing fluid at each of its treatment stages.
    • 通过将延迟的断路器和非延迟断路器引入压裂液中来降低含有聚合物的压裂液的粘度的方法。 优选地,延迟和未延迟断路器的相对量通过首先确定断裂中聚合物的浓度,确定聚合物浓度的破坏剂浓度与支撑剂包渗透性的关系,选择所需的支撑剂包渗透性,计算断路器的量来确定 必要的是将断裂中的聚合物浓度的粘度降低到期望的渗透性。 断屑器数量为X.接下来,确定保持支撑剂在断裂中悬浮的压裂液的最小粘度。 对于井底静态温度和时间间隔,计算减少不低于该最小粘度的压裂液的粘度的断路器Y的量。 计算初始引入压裂液释放量Y的延迟断路器Z的量。 最后,如果X小于Y,则不超过X量的延迟断路器被引入到压裂液中; 然而,如果Y小于X,则不超过Z量的延迟断路器被引入到压裂液中。 另外,在每个处理阶段,可将Y量的非延迟断路器引入压裂液中。