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1. 发明授权

US08759261B2 Method and composition for enhanced hydrocarbons recovery 有权
标题翻译：增强烃回收的方法和组成
公开(公告)号：US08759261B2
公开(公告)日：2014-06-24
申请号：US12366558
申请日：2009-02-05
申请人： Julian Richard Barnes , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit , Jasper Roelf Smit
发明人： Julian Richard Barnes , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit , Jasper Roelf Smit
IPC分类号： C09K8/584 , B23G1/06 , E21B43/22
CPC分类号： C09K8/584
摘要： The present invention provides a method of treating a hydrocarbon containing formation comprising (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein the composition comprises one or more internal olefin sulfonates having 17 or more carbon atoms, (b) adding water and/or brine from the hydrocarbon formation to the composition, (c) adding a solubilizer which comprises an ethoxylated alcohol wherein the alcohol before ethoxylation had an average molecular weight of at least about 220 and (d) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation. The solubilizer may comprise less than about 0.1 wt %, preferably from about 0.02 to about 0.05 wt %, of the total composition and it may have from about 5 to about 9 moles of ethylene oxide per mole of alcohol.
摘要翻译：本发明提供了一种处理含烃地层的方法，包括（a）向含烃地层的至少一部分提供烃回收组合物，其中所述组合物包含一种或多种具有17个或更多个碳原子的内烯烃磺酸盐（ b）从组合物中加入水和/或盐水，（c）加入包含乙氧基化醇的增溶剂，其中乙氧基化前的醇的平均分子量至少约为220，（d）使组合物与含烃地层中的烃相互作用。增溶剂可以占总组合物的小于约0.1重量％，优选约0.02至约0.05重量％，并且每摩尔醇可具有约5至约9摩尔环氧乙烷。

2. 发明申请

US20090203557A1 METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY 有权
标题翻译：增强烃回收方法与组合
公开(公告)号：US20090203557A1
公开(公告)日：2009-08-13
申请号：US12366558
申请日：2009-02-05
申请人： Julian Richard BARNES , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit , Jasper Roelf Smit
发明人： Julian Richard BARNES , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit , Jasper Roelf Smit
IPC分类号： C09K8/584 , C09K8/68
CPC分类号： C09K8/584
摘要： The present invention provides a method of treating a hydrocarbon containing formation comprising (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein the composition comprises one or more internal olefin sulfonates having 17 or more carbon atoms, (b) adding water and/or brine from the hydrocarbon formation to the composition, (c) adding a solubilizer which comprises an ethoxylated alcohol wherein the alcohol before ethoxylation had an average molecular weight of at least about 220 and (d) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation. The solubilizer may comprise less than about 0.1 wt %, preferably from about 0.02 to about 0.05 wt %, of the total composition and it may have from about 5 to about 9 moles of ethylene oxide per mole of alcohol.
摘要翻译：本发明提供了一种处理含烃地层的方法，包括（a）向含烃地层的至少一部分提供烃回收组合物，其中所述组合物包含一种或多种具有17个或更多个碳原子的内烯烃磺酸盐（ b）从组合物中加入水和/或盐水，（c）加入包含乙氧基化醇的增溶剂，其中乙氧基化前的醇的平均分子量至少约为220，（d）使组合物与含烃地层中的烃相互作用。增溶剂可以占总组合物的小于约0.1重量％，优选约0.02至约0.05重量％，并且每摩尔醇可具有约5至约9摩尔环氧乙烷。

3. 发明授权

US08940668B2 Method and composition for enhanced hydrocarbons recovery from a very high salinity, high temperature formation 有权
标题翻译：从非常高的盐度，高温形成中提高烃回收的方法和组成
公开(公告)号：US08940668B2
公开(公告)日：2015-01-27
申请号：US13264172
申请日：2010-04-14
申请人： Julian Richard Barnes , Kirk Herbert Raney , Thomas Carl Semple , Johan Paul Smit , Jasper Roelf Smit , Malcolm Shpakoff
发明人： Julian Richard Barnes , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit , Jasper Roelf Smit
IPC分类号： E21B43/00 , C09K8/584
CPC分类号： C09K8/584
摘要： A method of treating a very high salinity high temperature hydrocarbon containing formation is described. The method includes (a) providing a hydrocarbon recovery composition to at least a portion of a hydrocarbon containing formation having a brine salinity of above about 13 wt % and a temperature of above about 7° C., wherein the composition comprises a C15-18 internal olefin sulfonate; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.
摘要翻译：描述了处理非常高盐度的高温含烃地层的方法。该方法包括（a）向至少一部分具有高于约13重量％的盐水盐度和高于约7℃的温度的含烃地层提供烃回收组合物，其中所述组合物包含C15-18 内烯烃磺酸盐; 和（b）允许组合物与含烃地层中的烃相互作用。

4. 发明申请

US20120181025A1 METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY FROM A VERY HIGH SALINITY, HIGH TEMPERATURE FORMATION 有权
标题翻译：来自非常高的盐度，高温形成的增强烃的回收方法和组合
公开(公告)号：US20120181025A1
公开(公告)日：2012-07-19
申请号：US13264172
申请日：2010-04-14
申请人： Julian Richard Barnes , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit , Jasper Roelf Smit
发明人： Julian Richard Barnes , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit , Jasper Roelf Smit
IPC分类号： E21B43/00
CPC分类号： C09K8/584
摘要： A method of treating a very high salinity high temperature hydrocarbon containing formation is described. The method includes (a) providing a hydrocarbon recovery composition to at least a portion of a hydrocarbon containing formation having a brine salinity of above about 13 wt % and a temperature of above about 7° C., wherein the composition comprises a C15-18 internal olefin sulfonate; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.
摘要翻译：描述了处理非常高盐度的高温含烃地层的方法。该方法包括（a）向至少一部分具有高于约13重量％的盐水盐度和高于约7℃的温度的含烃地层提供烃回收组合物，其中所述组合物包含C15-18 内烯烃磺酸盐; 和（b）允许组合物与含烃地层中的烃相互作用。

5. 发明授权

US09284481B2 Method and composition for enhanced oil recovery 有权
标题翻译：提高采收率的方法和组成
公开(公告)号：US09284481B2
公开(公告)日：2016-03-15
申请号：US13578312
申请日：2011-02-09
申请人： Julian Richard Barnes , Hendrik Dirkzwager , Quoc An On , Johan Paul Smit , Jasper Roelf Smit
发明人： Julian Richard Barnes , Hendrik Dirkzwager , Quoc An On , Johan Paul Smit , Jasper Roelf Smit
IPC分类号： C09K8/58 , C09K8/584
CPC分类号： C09K8/584
摘要： A method is provided for treating a hydrocarbon containing formation. The method comprises providing a hydrocarbon recovery composition comprising a mixture of branched internal olefin sulfonate molecules, and contacting hydrocarbons in the hydrocarbon containing formation with the hydrocarbon recovery composition. The mixture of branched internal olefin sulfonate molecules has an average number of carbon atoms of between 19 and 23, and an average number of branches of at least 0.6 per molecule. A hydrocarbon composition produced from a hydrocarbon containing formation, and a hydrocarbon recovery composition comprising a mixture of branched internal olefin sulfonate molecules are also provided.
摘要翻译：提供了一种处理含烃地层的方法。该方法包括提供一种烃回收组合物，其包含支链内烯烃磺酸盐分子的混合物，并使含烃地层中的烃与烃回收组合物接触。支链内烯烃磺酸盐分子的混合物的平均碳原子数为19-23，每分子平均支链数为至少0.6。还提供了由含烃地层产生的烃组合物和包含支链内烯烃磺酸盐分子的混合物的烃回收组合物。

6. 发明申请

US20130190543A1 METHOD AND COMPOSITION FOR ENHANCED OIL RECOVERY 有权
标题翻译：用于增强油回收的方法和组合
公开(公告)号：US20130190543A1
公开(公告)日：2013-07-25
申请号：US13578312
申请日：2011-02-09
申请人： Julian Richard Barnes , Hendrik Dirkzwager , Quoc An On , Johan Paul Smit , Jasper Roelf Smit
发明人： Julian Richard Barnes , Hendrik Dirkzwager , Quoc An On , Johan Paul Smit , Jasper Roelf Smit
IPC分类号： C09K8/584
CPC分类号： C09K8/584
摘要： A method is provided for treating a hydrocarbon containing formation. The method comprises providing a hydrocarbon recovery composition comprising a mixture of branched internal olefin sulfonate molecules, and contacting hydrocarbons in the hydrocarbon containing formation with the hydrocarbon recovery composition. The mixture of branched internal olefin sulfonate molecules has an average number of carbon atoms of between 19 and 23, and an average number of branches of at least 0.6 per molecule. A hydrocarbon composition produced from a hydrocarbon containing formation, and a hydrocarbon recovery composition comprising a mixture of branched internal olefin sulfonate molecules are also provided.
摘要翻译：提供了一种处理含烃地层的方法。该方法包括提供一种烃回收组合物，其包含支链内烯烃磺酸盐分子的混合物，并使含烃地层中的烃与烃回收组合物接触。支链内烯烃磺酸盐分子的混合物的平均碳原子数为19-23，每分子平均支链数为至少0.6。还提供了由含烃地层产生的烃组合物和包含支链内烯烃磺酸盐分子的混合物的烃回收组合物。

7. 发明申请

US20100010251A1 PREPARATION OF ALKOXYSULFATES 审中-公开
标题翻译：烷基糖苷的制备
公开(公告)号：US20100010251A1
公开(公告)日：2010-01-14
申请号：US12500488
申请日：2009-07-09
申请人： Jan Hermen Hendrik MEURS , Jasper Roelf Smit , Arie Van Zon
发明人： Jan Hermen Hendrik MEURS , Jasper Roelf Smit , Arie Van Zon
IPC分类号： C07C305/14
CPC分类号： C07C303/24 , C07C305/04 , C07C305/10
摘要： A process for the preparation of alkoxysulfates from organic compounds containing one or more nucleophilic groups by reacting said organic compound, in a water-miscible solvent selected from the group consisting of sulfur-containing solvents such as dimethylsulfoxide (DMSO) or sulfolane, or polar solvents such as tetrahydrofuran (THF), dimethylformamide (DMF), dimethylacetamide (DMA) and hexamethylphosphoric triamide (HMPT), with an alkylene sulfate, in a non-water-miscible solvent selected from the group consisting of chlorinated solvents such as methylene chloride, chloroform, carbon tetrachloride, trichloroethane or chlorinated aromatics, such as chlorobenzene or dichlorobenzene, and non-chlorinated aromatics, such as toluene or xylenes, in the presence of a base selected from the group consisting of hydroxides, carbonates and hydrogen carbonates of alkali metals or alkaline earth metals.
摘要翻译：一种由含有一个或多个亲核基团的有机化合物制备烷氧基硫酸盐的方法，通过使所述有机化合物与选自二氧化硫（DMSO）或环丁砜的含硫溶剂或极性溶剂的水混溶性溶剂例如四氢呋喃（THF），二甲基甲酰胺（DMF），二甲基乙酰胺（DMA）和六甲基磷酰三胺（HMPT））与亚烷基硫酸盐在非水混溶性溶剂中，选自氯化溶剂如二氯甲烷，氯仿，四氯化碳，三氯乙烷或氯化芳族化合物如氯苯或二氯苯，以及非氯化芳族化合物如甲苯或二甲苯，在选自碱金属或碱金属的氢氧化物，碳酸盐和碳酸氢盐的碱的存在下地球金属。

8. 发明申请

US20090057608A1 ALKOXYLATE COMPOSITION AND A PROCESS FOR PREPARING THE SAME 审中-公开
标题翻译：烷氧基化合物及其制备方法
公开(公告)号：US20090057608A1
公开(公告)日：2009-03-05
申请号：US12146231
申请日：2008-06-25
申请人： Michiel Barend ELEVELD , Harmen Van Der Hulst , Jan Hermen Hendrik Meurs , Jasper Roelf Smit , Arie Van Zon
发明人： Michiel Barend ELEVELD , Harmen Van Der Hulst , Jan Hermen Hendrik Meurs , Jasper Roelf Smit , Arie Van Zon
IPC分类号： C07C29/10 , C09K3/00
CPC分类号： C11D1/722 , C08G65/14 , C08G65/2609 , C08G65/2663 , C08G65/337
摘要： A process for the preparation of an alkoxylate composition, said process comprising the steps of: (a) introducing into a reactor system one or more compounds with one or more active hydrogen atoms, selected from the group comprising alkanoic acids, alkanoic amides, alkanoic ethanolamides, alcohols and alkylmercaptans, and a double metal cyanide catalyst; (b) contacting the one or more compounds with one or more active hydrogen atoms and the double metal cyanide catalyst with propylene oxide and/or butylene oxide to form a first product mixture comprising double metal cyanide catalyst and compounds formed by the addition of one of more propylene oxide and/or butylene oxide units to the one or more compounds with one or more active hydrogen atoms; and (c) contacting the first product mixture with ethylene oxide to form a second product mixture comprising compounds formed by the addition of one of more ethylene oxide units to the compounds formed in step (b).
摘要翻译：一种制备烷氧基化物组合物的方法，所述方法包括以下步骤：（a）将一种或多种具有一个或多个活性氢原子的化合物引入反应器系统中，所述活性氢原子选自链烷酸，链烷酰胺，链烷醇乙酰胺，醇和烷基硫醇，以及双金属氰化物催化剂; （b）使一种或多种化合物与一种或多种活性氢原子和双金属氰化物催化剂与环氧丙烷和/或环氧丁烷接触以形成包含双金属氰化物催化剂的第一产物混合物和通过加入以下之一形成的化合物：更多的环氧丙烷和/或环氧丁烷单元与一种或多种具有一个或多个活性氢原子的化合物; 和（c）使第一产物混合物与环氧乙烷接触以形成包含通过向步骤（b）中形成的化合物中加入更多环氧乙烷单元之一形成的化合物的第二产物混合物。

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