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1. 发明授权

US08759261B2 Method and composition for enhanced hydrocarbons recovery 有权
标题翻译：增强烃回收的方法和组成
公开(公告)号：US08759261B2
公开(公告)日：2014-06-24
申请号：US12366558
申请日：2009-02-05
申请人： Julian Richard Barnes , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit , Jasper Roelf Smit
发明人： Julian Richard Barnes , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit , Jasper Roelf Smit
IPC分类号： C09K8/584 , B23G1/06 , E21B43/22
CPC分类号： C09K8/584
摘要： The present invention provides a method of treating a hydrocarbon containing formation comprising (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein the composition comprises one or more internal olefin sulfonates having 17 or more carbon atoms, (b) adding water and/or brine from the hydrocarbon formation to the composition, (c) adding a solubilizer which comprises an ethoxylated alcohol wherein the alcohol before ethoxylation had an average molecular weight of at least about 220 and (d) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation. The solubilizer may comprise less than about 0.1 wt %, preferably from about 0.02 to about 0.05 wt %, of the total composition and it may have from about 5 to about 9 moles of ethylene oxide per mole of alcohol.
摘要翻译：本发明提供了一种处理含烃地层的方法，包括（a）向含烃地层的至少一部分提供烃回收组合物，其中所述组合物包含一种或多种具有17个或更多个碳原子的内烯烃磺酸盐（ b）从组合物中加入水和/或盐水，（c）加入包含乙氧基化醇的增溶剂，其中乙氧基化前的醇的平均分子量至少约为220，（d）使组合物与含烃地层中的烃相互作用。增溶剂可以占总组合物的小于约0.1重量％，优选约0.02至约0.05重量％，并且每摩尔醇可具有约5至约9摩尔环氧乙烷。

2. 发明申请

US20090203557A1 METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY 有权
标题翻译：增强烃回收方法与组合
公开(公告)号：US20090203557A1
公开(公告)日：2009-08-13
申请号：US12366558
申请日：2009-02-05
申请人： Julian Richard BARNES , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit , Jasper Roelf Smit
发明人： Julian Richard BARNES , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit , Jasper Roelf Smit
IPC分类号： C09K8/584 , C09K8/68
CPC分类号： C09K8/584
摘要： The present invention provides a method of treating a hydrocarbon containing formation comprising (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein the composition comprises one or more internal olefin sulfonates having 17 or more carbon atoms, (b) adding water and/or brine from the hydrocarbon formation to the composition, (c) adding a solubilizer which comprises an ethoxylated alcohol wherein the alcohol before ethoxylation had an average molecular weight of at least about 220 and (d) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation. The solubilizer may comprise less than about 0.1 wt %, preferably from about 0.02 to about 0.05 wt %, of the total composition and it may have from about 5 to about 9 moles of ethylene oxide per mole of alcohol.
摘要翻译：本发明提供了一种处理含烃地层的方法，包括（a）向含烃地层的至少一部分提供烃回收组合物，其中所述组合物包含一种或多种具有17个或更多个碳原子的内烯烃磺酸盐（ b）从组合物中加入水和/或盐水，（c）加入包含乙氧基化醇的增溶剂，其中乙氧基化前的醇的平均分子量至少约为220，（d）使组合物与含烃地层中的烃相互作用。增溶剂可以占总组合物的小于约0.1重量％，优选约0.02至约0.05重量％，并且每摩尔醇可具有约5至约9摩尔环氧乙烷。

3. 发明申请

US20120181025A1 METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY FROM A VERY HIGH SALINITY, HIGH TEMPERATURE FORMATION 有权
标题翻译：来自非常高的盐度，高温形成的增强烃的回收方法和组合
公开(公告)号：US20120181025A1
公开(公告)日：2012-07-19
申请号：US13264172
申请日：2010-04-14
申请人： Julian Richard Barnes , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit , Jasper Roelf Smit
发明人： Julian Richard Barnes , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit , Jasper Roelf Smit
IPC分类号： E21B43/00
CPC分类号： C09K8/584
摘要： A method of treating a very high salinity high temperature hydrocarbon containing formation is described. The method includes (a) providing a hydrocarbon recovery composition to at least a portion of a hydrocarbon containing formation having a brine salinity of above about 13 wt % and a temperature of above about 7° C., wherein the composition comprises a C15-18 internal olefin sulfonate; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.
摘要翻译：描述了处理非常高盐度的高温含烃地层的方法。该方法包括（a）向至少一部分具有高于约13重量％的盐水盐度和高于约7℃的温度的含烃地层提供烃回收组合物，其中所述组合物包含C15-18 内烯烃磺酸盐; 和（b）允许组合物与含烃地层中的烃相互作用。

4. 发明授权

US08940668B2 Method and composition for enhanced hydrocarbons recovery from a very high salinity, high temperature formation 有权
标题翻译：从非常高的盐度，高温形成中提高烃回收的方法和组成
公开(公告)号：US08940668B2
公开(公告)日：2015-01-27
申请号：US13264172
申请日：2010-04-14
申请人： Julian Richard Barnes , Kirk Herbert Raney , Thomas Carl Semple , Johan Paul Smit , Jasper Roelf Smit , Malcolm Shpakoff
发明人： Julian Richard Barnes , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit , Jasper Roelf Smit
IPC分类号： E21B43/00 , C09K8/584
CPC分类号： C09K8/584
摘要： A method of treating a very high salinity high temperature hydrocarbon containing formation is described. The method includes (a) providing a hydrocarbon recovery composition to at least a portion of a hydrocarbon containing formation having a brine salinity of above about 13 wt % and a temperature of above about 7° C., wherein the composition comprises a C15-18 internal olefin sulfonate; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.
摘要翻译：描述了处理非常高盐度的高温含烃地层的方法。该方法包括（a）向至少一部分具有高于约13重量％的盐水盐度和高于约7℃的温度的含烃地层提供烃回收组合物，其中所述组合物包含C15-18 内烯烃磺酸盐; 和（b）允许组合物与含烃地层中的烃相互作用。

5. 发明授权

US08513168B2 Method and composition for enhanced hydrocarbons recovery 有权
标题翻译：增强烃回收的方法和组成
公开(公告)号：US08513168B2
公开(公告)日：2013-08-20
申请号：US12366554
申请日：2009-02-05
申请人： Julian Richard Barnes , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit
发明人： Julian Richard Barnes , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit
IPC分类号： C09K8/84
CPC分类号： C09K8/58 , C09K8/584
摘要： A method of treating a hydrocarbon containing formation is described. The method includes (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein (i) when the salinity of the brine is from about 2 wt % to about 4 wt %, the composition comprises a blend of a C20-24 internal olefin sulfonate and a C24-28 internal olefin sulfonate wherein the weight ratio of the C20-24 internal olefin sulfonate to the C24-28 internal olefin sulfonate is from about 90:10 to about 70:30 and (ii) when the salinity of the brine is greater than about 4 wt % up to about 13 wt % the composition comprises a blend of a C20-24 internal olefin sulfonate and a C15-18 internal olefin sulfonate wherein the weight ratio of the C20-24 internal olefin sulfonate to the C15-18 internal olefin sulfonate is from about 90:10 to about 70:30; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.
摘要翻译：描述了处理含烃地层的方法。该方法包括（a）向含烃地层的至少一部分提供烃回收组合物，其中（i）当盐水的盐度为约2重量％至约4重量％时，该组合物包含 C20-24内烯烃磺酸盐和C24-28内烯烃磺酸盐，其中C20-24内烯烃磺酸盐与C24-28内烯烃磺酸盐的重量比为约90:10至约70:30，（ii）当盐水的盐度大于约4重量％至多约13重量％时，组合物包含C20-24内烯烃磺酸盐和C15-18内烯烃磺酸盐的共混物，其中C20-24内部的重量比烯烃磺酸盐与C15-18内烯烃磺酸盐的摩尔比为约90:10至约70:30; 和（b）允许组合物与含烃地层中的烃相互作用。

6. 发明申请

US20090203558A1 METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY 有权
标题翻译：增强烃回收方法与组合
公开(公告)号：US20090203558A1
公开(公告)日：2009-08-13
申请号：US12366554
申请日：2009-02-05
申请人： Julian Richard BARNES , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit
发明人： Julian Richard BARNES , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit
IPC分类号： C09K8/84
CPC分类号： C09K8/58 , C09K8/584
摘要： A method of treating a hydrocarbon containing formation is described. The method includes (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein (i) when the salinity of the brine is from about 2 wt % to about 4 wt %, the composition comprises a blend of a C20-24 internal olefin sulfonate and a C24-28 internal olefin sulfonate wherein the weight ratio of the C20-24 internal olefin sulfonate to the C24-28 internal olefin sulfonate is from about 90:10 to about 70:30 and (ii) when the salinity of the brine is greater than about 4 wt % up to about 13 wt % the composition comprises a blend of a C20-24 internal olefin sulfonate and a C15-18 internal olefin sulfonate wherein the weight ratio of the C20-24 internal olefin sulfonate to the C15-18 internal olefin sulfonate is from about 90:10 to about 70:30; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.
摘要翻译：描述了处理含烃地层的方法。该方法包括（a）向含烃地层的至少一部分提供烃回收组合物，其中（i）当盐水的盐度为约2重量％至约4重量％时，该组合物包含 C20-24内烯烃磺酸盐和C24-28内烯烃磺酸盐，其中C20-24内烯烃磺酸盐与C24-28内烯烃磺酸盐的重量比为约90:10至约70:30，（ii）当盐水的盐度大于约4重量％至多约13重量％时，组合物包含C20-24内烯烃磺酸盐和C15-18内烯烃磺酸盐的共混物，其中C20-24内部的重量比烯烃磺酸盐与C15-18内烯烃磺酸盐的摩尔比为约90:10至约70:30; 和（b）允许组合物与含烃地层中的烃相互作用。

7. 发明申请

US20140005082A1 METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY FROM A FORMATION CONTAINING A CRUDE OIL 审中-公开
标题翻译：来自含有原油的成分的增强烃的回收方法和组合物
公开(公告)号：US20140005082A1
公开(公告)日：2014-01-02
申请号：US13976537
申请日：2011-12-09
申请人： Julian Richard Barnes , James Laurel Buechele , Robert Hardy Ellison , Kirk Herbert Raney , Thomas Carl Semple , Johan Paul Smit
发明人： Julian Richard Barnes , James Laurel Buechele , Robert Hardy Ellison , Kirk Herbert Raney , Thomas Carl Semple , Johan Paul Smit
IPC分类号： C09K8/584
CPC分类号： C09K8/584
摘要： A hydrocarbon recovery composition comprising vinylidene based alkoxylate derivatives. A method of treating a crude oil formation and a method of preparing the hydrocarbon recovery composition are also described.
摘要翻译：一种包含亚乙烯基烷氧基化物衍生物的烃回收组合物。还描述了处理原油形成的方法和制备烃回收组合物的方法。

8. 发明授权

US09284481B2 Method and composition for enhanced oil recovery 有权
标题翻译：提高采收率的方法和组成
公开(公告)号：US09284481B2
公开(公告)日：2016-03-15
申请号：US13578312
申请日：2011-02-09
申请人： Julian Richard Barnes , Hendrik Dirkzwager , Quoc An On , Johan Paul Smit , Jasper Roelf Smit
发明人： Julian Richard Barnes , Hendrik Dirkzwager , Quoc An On , Johan Paul Smit , Jasper Roelf Smit
IPC分类号： C09K8/58 , C09K8/584
CPC分类号： C09K8/584
摘要： A method is provided for treating a hydrocarbon containing formation. The method comprises providing a hydrocarbon recovery composition comprising a mixture of branched internal olefin sulfonate molecules, and contacting hydrocarbons in the hydrocarbon containing formation with the hydrocarbon recovery composition. The mixture of branched internal olefin sulfonate molecules has an average number of carbon atoms of between 19 and 23, and an average number of branches of at least 0.6 per molecule. A hydrocarbon composition produced from a hydrocarbon containing formation, and a hydrocarbon recovery composition comprising a mixture of branched internal olefin sulfonate molecules are also provided.
摘要翻译：提供了一种处理含烃地层的方法。该方法包括提供一种烃回收组合物，其包含支链内烯烃磺酸盐分子的混合物，并使含烃地层中的烃与烃回收组合物接触。支链内烯烃磺酸盐分子的混合物的平均碳原子数为19-23，每分子平均支链数为至少0.6。还提供了由含烃地层产生的烃组合物和包含支链内烯烃磺酸盐分子的混合物的烃回收组合物。

9. 发明申请

US20130190543A1 METHOD AND COMPOSITION FOR ENHANCED OIL RECOVERY 有权
标题翻译：用于增强油回收的方法和组合
公开(公告)号：US20130190543A1
公开(公告)日：2013-07-25
申请号：US13578312
申请日：2011-02-09
申请人： Julian Richard Barnes , Hendrik Dirkzwager , Quoc An On , Johan Paul Smit , Jasper Roelf Smit
发明人： Julian Richard Barnes , Hendrik Dirkzwager , Quoc An On , Johan Paul Smit , Jasper Roelf Smit
IPC分类号： C09K8/584
CPC分类号： C09K8/584
摘要： A method is provided for treating a hydrocarbon containing formation. The method comprises providing a hydrocarbon recovery composition comprising a mixture of branched internal olefin sulfonate molecules, and contacting hydrocarbons in the hydrocarbon containing formation with the hydrocarbon recovery composition. The mixture of branched internal olefin sulfonate molecules has an average number of carbon atoms of between 19 and 23, and an average number of branches of at least 0.6 per molecule. A hydrocarbon composition produced from a hydrocarbon containing formation, and a hydrocarbon recovery composition comprising a mixture of branched internal olefin sulfonate molecules are also provided.
摘要翻译：提供了一种处理含烃地层的方法。该方法包括提供一种烃回收组合物，其包含支链内烯烃磺酸盐分子的混合物，并使含烃地层中的烃与烃回收组合物接触。支链内烯烃磺酸盐分子的混合物的平均碳原子数为19-23，每分子平均支链数为至少0.6。还提供了由含烃地层产生的烃组合物和包含支链内烯烃磺酸盐分子的混合物的烃回收组合物。

10. 发明申请

US20140290953A1 METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY FROM A FORMATION CONTAINING A CRUDE OIL 审中-公开
标题翻译：来自含有原油的成分的增强烃的回收方法和组合物
公开(公告)号：US20140290953A1
公开(公告)日：2014-10-02
申请号：US13976528
申请日：2011-12-09
申请人： Julian Richard Barnes , Robert Hardy Ellison , Maura Puerto , Kirk Herbert Raney , Johan Paul Smit
发明人： Julian Richard Barnes , Robert Hardy Ellison , Maura Puerto , Kirk Herbert Raney , Johan Paul Smit
IPC分类号： C09K8/58 , E21B43/16
CPC分类号： C09K8/58 , C07C309/20 , C09K8/584 , E21B43/16
摘要： A hydrocarbon recovery composition comprising vinylidene olefin sulfonates is described. A method of treating a crude oil formation and a method of preparing the hydrocarbon recovery composition are also described.
摘要翻译：描述了包含亚乙烯基烯烃磺酸盐的烃回收组合物。还描述了处理原油形成的方法和制备烃回收组合物的方法。

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