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1. 发明授权

US08674135B2 Functionalized ionic liquids, and methods of use thereof 有权
标题翻译：官能化离子液体及其使用方法
公开(公告)号：US08674135B2
公开(公告)日：2014-03-18
申请号：US12713742
申请日：2010-02-26
申请人： James H. Davis, Jr.
发明人： James H. Davis, Jr.
IPC分类号： C07C233/00 , C07C235/00
CPC分类号： C07F9/65515 , B01D53/1456 , B01D53/1493 , B01D2252/30 , B01D2257/302 , B01D2257/304 , B01D2257/308 , B01D2257/504 , B01D2258/06 , B01J31/0224 , B01J31/0227 , B01J31/0281 , B01J31/0285 , B01J31/0288 , B01J2231/40 , B01J2231/52 , C07C41/09 , C07C45/46 , C07C45/52 , C07C67/08 , C07C211/63 , C07C225/22 , C07C243/34 , C07C267/00 , C07C309/14 , C07C309/15 , C07C309/30 , C07C311/48 , C07D233/58 , C07D233/60 , C07D233/61 , C07D295/088 , C07D295/13 , C07D401/06 , C07D405/14 , C07F9/5407 , C07F9/5442 , C07F9/6506 , C10G29/20 , C10G2300/1088 , C10G2300/207 , C10G2400/20 , C10G2400/22 , Y02C10/06 , Y02P20/152 , Y02P20/51 , Y02P20/542 , Y02P30/40 , C07C49/04 , C07C49/782 , C07C69/24 , C07C69/14 , C07C43/04
摘要： One aspect of the present invention relates to ionic liquids comprising a pendant Bronsted-acidic group, e.g., a sulfonic acid group. Another aspect of the present invention relates to the use of an ionic liquid comprising a pendant Bronsted-acidic group to catalyze a Bronsted-acid-catalyzed chemical reaction. A third aspect of the present invention relates to ionic liquids comprising a pendant nucleophilic group, e.g., an amine. Still another aspect of the present invention relates to the use of an ionic liquid comprising a pendant nucleophilic group to catalyze a nucleophile-assisted chemical reaction. A fifth aspect of the present invention relates to the use of an ionic liquid comprising a pendant nucleophilic group to remove a gaseous impurity, e.g., carbon dioxide, from a gas, e.g., sour natural gas.
摘要翻译：本发明的一个方面涉及包含悬臂状布朗斯台德酸性基团例如磺酸基团的离子液体。本发明的另一方面涉及使用包含侧枝Bronsted-酸性基团的离子液体来催化布朗斯台德酸催化的化学反应。本发明的第三方面涉及包含侧亲核基团例如胺的离子液体。本发明的另一方面涉及包含侧亲核基团的离子液体催化亲核试剂辅助化学反应的用途。本发明的第五方面涉及包含侧链亲核基团的离子液体从气体例如酸性天然气中除去气态杂质如二氧化碳的用途。

2. 发明授权

US07744838B2 Functionalized ionic liquids, and methods of use thereof 有权
标题翻译：官能化离子液体及其使用方法
公开(公告)号：US07744838B2
公开(公告)日：2010-06-29
申请号：US11789429
申请日：2007-04-24
申请人： James H. Davis, Jr.
发明人： James H. Davis, Jr.
IPC分类号： C01B17/16
CPC分类号： C07F9/65515 , B01D53/1456 , B01D53/1493 , B01D2252/30 , B01D2257/302 , B01D2257/304 , B01D2257/308 , B01D2257/504 , B01D2258/06 , B01J31/0224 , B01J31/0227 , B01J31/0281 , B01J31/0285 , B01J31/0288 , B01J2231/40 , B01J2231/52 , C07C41/09 , C07C45/46 , C07C45/52 , C07C67/08 , C07C211/63 , C07C225/22 , C07C243/34 , C07C267/00 , C07C309/14 , C07C309/15 , C07C309/30 , C07C311/48 , C07D233/58 , C07D233/60 , C07D233/61 , C07D295/088 , C07D295/13 , C07D401/06 , C07D405/14 , C07F9/5407 , C07F9/5442 , C07F9/6506 , C10G29/20 , C10G2300/1088 , C10G2300/207 , C10G2400/20 , C10G2400/22 , Y02C10/06 , Y02P20/152 , Y02P20/51 , Y02P20/542 , Y02P30/40 , C07C49/04 , C07C49/782 , C07C69/24 , C07C69/14 , C07C43/04
摘要： One aspect of the present invention relates to ionic liquids comprising a pendant Bronsted-acidic group, e.g., a sulfonic acid group. Another aspect of the present invention relates to the use of an ionic liquid comprising a pendant Bronsted-acidic group to catalyze a Bronsted-acid-catalyzed chemical reaction. A third aspect of the present invention relates to ionic liquids comprising a pendant nucleophilic group, e.g., an amine. Still another aspect of the present invention relates to the use of an ionic liquid comprising a pendant nucleophilic group to catalyze a nucleophile-assisted chemical reaction. A fifth aspect of the present invention relates to the use of an ionic liquid comprising a pendant nucleophilic group to remove a gaseous impurity, e.g., carbon dioxide, from a gas, e.g., sour natural gas.
摘要翻译：本发明的一个方面涉及包含悬臂状布朗斯台德酸性基团例如磺酸基团的离子液体。本发明的另一方面涉及使用包含侧枝Bronsted-酸性基团的离子液体来催化布朗斯台德酸催化的化学反应。本发明的第三方面涉及包含侧亲核基团例如胺的离子液体。本发明的另一方面涉及包含侧亲核基团的离子液体催化亲核试剂辅助化学反应的用途。本发明的第五方面涉及包含侧链亲核基团的离子液体从气体例如酸性天然气中除去气态杂质例如二氧化碳的用途。

3. 发明申请

US20140170054A1 Carbon Dioxide Scrubbing Using Ionic Materials 有权
标题翻译：使用离子材料的二氧化碳洗涤
公开(公告)号：US20140170054A1
公开(公告)日：2014-06-19
申请号：US14029298
申请日：2013-09-17
申请人： James H. Davis, JR.
发明人： James H. Davis, JR.
IPC分类号： C01B31/20 , C07C309/14
CPC分类号： C01B31/20 , B01D53/1475 , B01D53/1493 , B01D53/78 , B01D2257/302 , B01D2257/404 , B01D2257/504 , C01B32/50 , C07C211/63 , C07C309/14 , Y02C10/06 , Y02P20/152
摘要： One aspect of the present invention relates to amine-functionalized task-specific ionic liquids (TSILs). In certain embodiments, the ionic liquids of the invention comprise beta-hydroxy amines, aryl amines or tertiary amines. The TSILs may be used for gas capture, capitalizing on their non-volatile nature. In certain embodiments, the captured gas is selected from the group consisting of CO2, SO2, CS2, and NO2. Another aspect of the present invention relates to a library of CO2-philic salts, which library facilitates reactive gas separation. In certain embodiments, the CO2-philic salts are CO2-reactive TSILs. In certain embodiments, the CO2-philic salts are resinous or plastic in nature.
摘要翻译：本发明的一个方面涉及胺官能化的任务特异性离子液体（TSIL）。在某些实施方案中，本发明的离子液体包含β-羟基胺，芳基胺或叔胺。 TSIL可用于气体捕获，利用其非挥发性质。在某些实施方案中，所捕获的气体选自CO 2，SO 2，CS 2和NO 2。本发明的另一方面涉及一种二氧化碳亲和盐的文库，该文库便于反应气体分离。在某些实施方案中，CO 2亲水盐是CO 2反应性TSIL。在某些实施方案中，天然亲水盐是树脂或塑料。

4. 发明申请

US20090200513A1 Ionic Liquids Containing a Sulfonate Anion 审中-公开
标题翻译：含有磺酸根阴离子的离子液体
公开(公告)号：US20090200513A1
公开(公告)日：2009-08-13
申请号：US12404011
申请日：2009-03-13
申请人： Roger Moulton , James H. Davis, JR.
发明人： Roger Moulton , James H. Davis, JR.
IPC分类号： C09K3/00
CPC分类号： C07D295/088 , C07C211/63 , C07C309/17 , C07C2601/14 , Y02P20/544
摘要： The present invention relates to novel ionic liquids comprising a docusate, docusate variant, or other sulfonate anion. The ionic liquids may be conveniently made via, for example, metathesis. The ionic liquids are often hydrophobic and useful in many hydrocarbon compositions, polymer compositions, and in supercritical carbon dioxide applications. The ionic liquids are capable of hindering static electricity buildup in the hydrocarbon compositions and can therefore minimize flammability and/or explosiveness.
摘要翻译：本发明涉及包含多库酯，多库酯变体或其它磺酸根阴离子的新型离子液体。离子液体可以通过例如复分解方便地制备。离子液体通常是疏水性的，可用于许多烃组合物，聚合物组合物和超临界二氧化碳应用中。离子液体能够阻碍烃组合物中的静电积累，因此可以使可燃性和/或爆炸性最小化。

5. 发明申请

US20120171094A1 Aqueous solutions of amine functionalized ionic compounds for carbon capture processes 有权
标题翻译：用于碳捕获过程的胺官能化离子化合物的水溶液
公开(公告)号：US20120171094A1
公开(公告)日：2012-07-05
申请号：US12930208
申请日：2010-12-30
申请人： Daniel Chinn , Russell Evan Cooper , Zunqing He , James H. Davis, JR. , Kevin N. West , Hye Kyung Timken , Michael S. Driver
发明人： Daniel Chinn , Russell Evan Cooper , Zunqing He , James H. Davis, JR. , Kevin N. West , Hye Kyung Timken , Michael S. Driver
IPC分类号： B01D53/62 , C09K3/00
CPC分类号： B01D53/62 , B01D53/1475 , B01D53/1493 , B01D53/78 , B01D2252/204 , B01D2252/2056 , B01D2252/30 , B01D2252/502 , B01D2258/0283 , Y02C10/04 , Y02C10/06
摘要： An aqueous ionic absorbent solution is disclosed containing (a) about 15 wt. % to about 80 wt. % of one or more diluents, based on the total weight of the aqueous ionic absorbent solution; and (b) an ionic absorbent containing a cation and an anion comprising an amine moiety.
摘要翻译：公开了一种含水离子吸收剂溶液，其包含（a）约15重量％％至约80wt。％的一种或多种稀释剂，基于含水离子吸收剂溶液的总重量; 和（b）含有阳离子和含有胺部分的阴离子的离子吸收剂。

6. 发明授权

US09180403B2 Aqueous solutions of amine functionalized ionic compounds for carbon capture processes 有权
标题翻译：用于碳捕获过程的胺官能化离子化合物的水溶液
公开(公告)号：US09180403B2
公开(公告)日：2015-11-10
申请号：US12930208
申请日：2010-12-30
申请人： Daniel Chinn , Russell Evan Cooper , Zunqing He , James H. Davis, Jr. , Kevin N. West , Hye Kyung Timken , Michael S. Driver
发明人： Daniel Chinn , Russell Evan Cooper , Zunqing He , James H. Davis, Jr. , Kevin N. West , Hye Kyung Timken , Michael S. Driver
IPC分类号： C07C211/62 , C07C211/63 , C07C211/64 , B01D53/14
CPC分类号： B01D53/62 , B01D53/1475 , B01D53/1493 , B01D53/78 , B01D2252/204 , B01D2252/2056 , B01D2252/30 , B01D2252/502 , B01D2258/0283 , Y02C10/04 , Y02C10/06
摘要： An aqueous ionic absorbent solution is disclosed containing (a) about 15 wt. % to about 80 wt. % of one or more diluents, based on the total weight of the aqueous ionic absorbent solution; and (b) an ionic absorbent containing a cation and an anion comprising an amine moiety.
摘要翻译：公开了一种含水离子吸收剂溶液，其包含（a）约15重量％％至约80wt。％的一种或多种稀释剂，基于含水离子吸收剂溶液的总重量; 和（b）含有阳离子和含有胺部分的阴离子的离子吸收剂。

7. 发明授权

US08952193B2 Carbon dioxide scrubbing using ionic materials 有权
标题翻译：使用离子材料进行二氧化碳洗涤
公开(公告)号：US08952193B2
公开(公告)日：2015-02-10
申请号：US14029298
申请日：2013-09-17
申请人： James H. Davis, Jr.
发明人： James H. Davis, Jr.
IPC分类号： C07C317/04 , C07C317/06 , C01B31/20 , B01D53/14 , B01D53/78 , C07C211/63 , C07C309/14
CPC分类号： C01B31/20 , B01D53/1475 , B01D53/1493 , B01D53/78 , B01D2257/302 , B01D2257/404 , B01D2257/504 , C01B32/50 , C07C211/63 , C07C309/14 , Y02C10/06 , Y02P20/152
摘要： One aspect of the present invention relates to amine-functionalized task-specific ionic liquids (TSILs). In certain embodiments, the ionic liquids of the invention comprise beta-hydroxy amines, aryl amines or tertiary amines. The TSILs may be used for gas capture, capitalizing on their non-volatile nature. In certain embodiments, the captured gas is selected from the group consisting of CO2, SO2, CS2, and NO2. Another aspect of the present invention relates to a library of CO2-philic salts, which library facilitates reactive gas separation. In certain embodiments, the CO2-philic salts are CO2-reactive TSILs. In certain embodiments, the CO2-philic salts are resinous or plastic in nature.
摘要翻译：本发明的一个方面涉及胺官能化的任务特异性离子液体（TSIL）。在某些实施方案中，本发明的离子液体包含β-羟基胺，芳基胺或叔胺。 TSIL可用于气体捕获，利用其非挥发性质。在某些实施方案中，所捕获的气体选自CO 2，SO 2，CS 2和NO 2。本发明的另一方面涉及一种二氧化碳亲和盐的文库，该文库便于反应气体分离。在某些实施方案中，CO 2亲水盐是CO 2反应性TSIL。在某些实施方案中，天然亲水盐是树脂或塑料。

8. 发明授权

US08911539B2 Process for the separation of carbon dioxide from flue gas 有权
标题翻译：从烟道气中分离二氧化碳的方法
公开(公告)号：US08911539B2
公开(公告)日：2014-12-16
申请号：US12930207
申请日：2010-12-30
申请人： Daniel Chinn , Russell Evan Cooper , Zunqing He , James H. Davis, Jr. , Kevin N. West , Hye Kyung Timken , Michael S. Driver
发明人： Daniel Chinn , Russell Evan Cooper , Zunqing He , James H. Davis, Jr. , Kevin N. West , Hye Kyung Timken , Michael S. Driver
IPC分类号： B01D53/14 , B01D53/18
CPC分类号： B01D53/1493 , B01D53/1425 , B01D53/1456 , B01D53/1475 , B01D53/1481 , B01D2252/103 , B01D2252/30 , B01D2258/0233 , B01D2258/025 , B01D2258/0283 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A process and system for separating CO2 from a flue gas stream is disclosed. The process involves (a) contacting a flue gas stream containing water vapor and CO2 with an ionic absorbent under absorption conditions to absorb at least a portion of the CO2 from the flue gas stream and form a CO2-absorbent complex; wherein the ionic absorbent comprises a cation and an anion comprising an amine moiety; and (b) recovering a gaseous product having a reduced CO2 content.
摘要翻译：公开了一种用于从烟道气流中分离CO 2的方法和系统。该方法包括（a）在吸收条件下使含有水蒸气和CO 2的烟道气与离子吸收剂接触，以从烟道气流吸收至少一部分CO 2并形成CO 2吸收复合物; 其中所述离子吸收剂包含阳离子和包含胺部分的阴离子; 和（b）回收具有降低的CO 2含量的气态产物。

9. 发明授权

US07709635B2 Boronium-ion-based ionic liquids and methods of use thereof 有权
标题翻译：基于硼离子的离子液体及其使用方法
公开(公告)号：US07709635B2
公开(公告)日：2010-05-04
申请号：US11437417
申请日：2006-05-19
申请人： James H. Davis, Jr.
发明人： James H. Davis, Jr.
IPC分类号： C07F5/02
CPC分类号： C07F5/027 , C07F5/022
摘要： One aspect of the present invention relates to “boronium” ions that are stable, hydrophobic, room-temperature ionic liquids. In certain embodiments, ionic liquids of the instant invention are represented by the formula [XnBY4−n]+(n−1)(n−1)Z−1, wherein X refers to a Lewis base, Y refers to a substituent covalently bonded to boron, Z−1 is a charge diffuse anion, and x is 2, 3 or 4. In certain embodiments, the ionic liquids of the instant invention are of the general type [X2BY2]+1Tf2N−1, wherein each X is independently a tertiary amine, a N-alkylimidazole or a pyridine; and each B—X bond is a B—N bond.
摘要翻译：本发明的一个方面涉及稳定的，疏水的，室温离子液体的“硼”离子。在某些实施方案中，本发明的离子液体由式[XnBY4-n] +（n-1）（n-1）Z-1表示，其中X表示路易斯碱，Y表示共价键合的取代基对于硼，Z-1是电荷扩散阴离子，x是2,3或4.在某些实施方案中，本发明的离子液体是通式[X2BY2] + 1Tf2N-1，其中每个X独立地叔胺，N-烷基咪唑或吡啶; 并且每个B-X键是B-N键。

10. 发明授权

US09205371B2 Method for improving total energy demand in a post-combustion carbon capture process with ionic absorbent 有权
标题翻译：用离子吸收剂改善后燃碳捕获过程中总能量需求的方法
公开(公告)号：US09205371B2
公开(公告)日：2015-12-08
申请号：US13336597
申请日：2011-12-23
申请人： Russell Evan Cooper , Daniel Chinn , Zunqing He , Hye Hyung Timken , Michael S. Driver , James H. Davis, Jr. , Kevin N. West
发明人： Russell Evan Cooper , Daniel Chinn , Zunqing He , Hye Hyung Timken , Michael S. Driver , James H. Davis, Jr. , Kevin N. West
IPC分类号： B01D53/62 , B01J31/02 , C07C309/69 , C07C323/25 , B01D53/78 , B01D53/96 , B01D53/14
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/20405 , B01D2252/20426 , B01D2252/2056 , B01D2252/30 , B01D2258/0283 , Y02C10/04 , Y02C10/06 , Y02C10/08
摘要： Disclosed herein is a method for improving the total energy demand required to separate carbon dioxide (CO2) from an aqueous ionic absorbent solution in a post-combustion carbon capture process. The method involves (a) contacting a flue gas stream containing CO2 with an aqueous ionic absorbent solution under absorption conditions to absorb at least a portion of the CO2 from the flue gas stream and form a CO2-aqueous ionic absorbent solution stream, wherein the aqueous ionic absorbent solution comprises one or more diluents and an ionic absorbent containing a cation and an anion comprising an amine moiety; and (b) subjecting at least a portion of the CO2-aqueous ionic absorbent solution stream to desorption conditions to form a CO2-rich stream and an aqueous ionic absorbent solution stream having a reduced CO2 content.
摘要翻译：本文公开了一种改进在后燃烧碳捕获过程中从含水离子吸收剂溶液中分离二氧化碳（CO 2）所需的总能量需求的方法。该方法包括（a）在吸收条件下使含有CO 2的烟道气流与含水离子吸收剂溶液接触，以从烟道气流吸收至少一部分CO 2并形成CO 2 - 水离子吸收剂溶液流，其中水离子吸收剂溶液包含一种或多种稀释剂和含有阳离子和含有胺部分的阴离子的离子吸收剂; 和（b）使至少一部分CO 2水溶性离子吸收剂溶液流进行解吸条件以形成富二氧化物流和具有降低的CO 2含量的水性离子吸收剂溶液流。

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