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1. 发明授权

US06365699B1 Curable compositions composite coatings and process for having improved mar and abrasion resistance 失效
标题翻译：可固化组合物复合涂层和具有改善耐磨性和耐磨性的方法
公开(公告)号：US06365699B1
公开(公告)日：2002-04-02
申请号：US09471213
申请日：1999-12-23
申请人： George W. Mauer , James A. Meier , Lynne R. Stahl
发明人： George W. Mauer , James A. Meier , Lynne R. Stahl
IPC分类号： C08G1880
CPC分类号： C08G18/7893 , C08G18/4294 , C08G18/581 , C08G18/62 , C08G18/6229 , C08G18/6237 , C08G18/6407 , C08G18/792 , C08G18/8064 , C08G59/5086 , C09D175/00 , Y10T428/31551
摘要： A curable composition and process of applying the composition and the resulting composite coatings provide improved resistance to acid etch and mar. The curable composition has (a) about 30 to 90 percent by weight, based on total weight of resin solids, of a film-forming composition selected from the group consisting of: (i) a polyepoxide and a polyacid crosslinking agent; (ii) an acrylosilane polymer, an acrylic polyol polymer, and optionally an alkylated melamine-formaldehyde crosslinking agent; and (iii) a polyisocyanate and a polymer having at least one group that is reactive with isocyanate; and (b) about 10 to 70 percent by weight, based on total weight of resin solids, of a tricarbamoyl triazine compound of the formula: C3N3(NHCOXR)3 wherein X is nitrogen, oxygen, sulfur, phosphorus, or carbon, and R is a lower alkyl group having 1 to 12 carbon atoms, or mixtures of lower alkyl groups. The process involves applying the curable coating as a monocoat on a cured primer surfacer coating on a substrate or as a clear coat on a curable base coat that are cured separately or conjointly. The composite coating includes the primer surfacer and monocoat on a substrate or the color-plus-clear coating on an electrodeposited coating layer or a primer surfacer coating layer.
摘要翻译：可固化组合物和施加组合物和所得复合涂层的方法提供了改善的耐酸蚀和耐蚀性。所述可固化组合物具有（a）基于树脂固体的总重量计约30至90重量％的成膜组合物，所述成膜组合物选自：（i）聚环氧化物和多酸交联剂;（ii）丙烯酸硅烷聚合物，丙烯酸多元醇聚合物和任选的烷基化三聚氰胺 - 甲醛交联剂; 和（iii）多异氰酸酯和具有至少一个与异氰酸酯反应的基团的聚合物; 和（b）基于树脂固体的总重量，约10-70重量％的下式的三氨甲酰三嗪化合物：C3N3（NHCOXR）3，其中X是氮，氧，硫，磷或碳，R 是具有1至12个碳原子的低级烷基或低级烷基的混合物。该方法包括将可固化涂层作为单壳体涂覆在基底上的固化的底漆表面涂层上，或者作为可固化底涂层上的透明涂层单独或共同固化。复合涂层包括底物上的底漆二
面体和单面涂层或电沉积涂层或底漆二层涂层上的彩色 - 透明涂层。

2. 发明授权

US5565243A Color-clear composite coatings having improved hardness, acid etch resistance, and mar and abrasion resistance 失效
标题翻译：透明复合涂层具有改善的硬度，耐酸蚀性，耐磨性和耐磨性
公开(公告)号：US5565243A
公开(公告)日：1996-10-15
申请号：US432296
申请日：1995-05-01
申请人： George W. Mauer , James A. Meier , Lynne R. Stahl
发明人： George W. Mauer , James A. Meier , Lynne R. Stahl
IPC分类号： B05D7/00 , B05D7/14
CPC分类号： B05D7/53
摘要： A process for applying a color-plus-clear composite coating to a substrate is provided. The process comprises applying to the substrate a pigmented or colored film-forming composition to form a base coat and applying to the base coat a transparent film-forming composition to form a clear coat over the base coat. The base coat comprises a resinous binder; a tricarbamoyl triazine compound having the formula C.sub.3 N.sub.3 (NHCOXR).sub.3, wherein X is nitrogen, oxygen, sulfur, phosphorus, or carbon, and R is a lower alkyl group having 1 to 12 carbon atoms, of mixtures of lower alkyl groups; and a pigment to act as the colorant. In a second embodiment of the invention, the base coat comprises a resinous binder, a capped polyisocyanate, and a pigment; and the clear coat comprises a polyepoxide and a polyacid crosslinking agent.
摘要翻译：提供了一种将颜色加透明复合涂层施加到基底的方法。该方法包括将着色或着色的成膜组合物施加到基底上以形成底涂层，并向底涂层施加透明成膜组合物以在底涂层上形成透明涂层。底涂层包括树脂粘合剂; 具有式C3N3（NHCOXR）3的三氨甲酰三嗪化合物，其中X是氮，氧，硫，磷或碳，R是具有1至12个碳原子的低级烷基，低级烷基的混合物; 和作为着色剂的颜料。在本发明的第二个实施方案中，底涂层包括树脂粘合剂，封端多异氰酸酯和颜料; 透明涂层包含聚环氧化物和多酸交联剂。

3. 发明授权

US4807419A Multiple pane unit having a flexible spacing and sealing assembly 失效
标题翻译：具有柔性间隔和密封组件的多窗格单元
公开(公告)号：US4807419A
公开(公告)日：1989-02-28
申请号：US30012
申请日：1987-03-25
申请人： Robert B. Hodek , James A. Meier , James E. Jones , Jerome A. Seiner
发明人： Robert B. Hodek , James A. Meier , James E. Jones , Jerome A. Seiner
IPC分类号： E06B3/66 , C03C27/06 , E06B3/677 , E04C2/54
CPC分类号： E06B3/677
摘要： An improved multiple glazed unit including a pair of glass sheets maintained in spaced-apart relationship to each other by a spacer element to provide an airspace therebetween and a sealing element to hermetically seal the airspace, is characterized by a spacer element containing a dehydrating material and an unplasticized polymeric material which is the reaction product of a polyisocyanate and an active hydrogen containing material; and a sealing element containing an unplasticized polymeric material which is the reaction product of a polyisocyanate and an active hydrogen containing material; the polymeric material of the spacer element having a moisture vapor transmission rating which is greater than that of the polymeric material of the sealing element.

4. 发明授权

US5891981A Curable compositions composite coatings and process for having improved mar and abrasion resistance 失效
标题翻译：可固化组合物复合涂层和具有改善耐磨性和耐磨性的方法
公开(公告)号：US5891981A
公开(公告)日：1999-04-06
申请号：US888937
申请日：1997-07-07
申请人： George W. Mauer , James A. Meier , Lynne R. Stahl
发明人： George W. Mauer , James A. Meier , Lynne R. Stahl
IPC分类号： C08G18/42 , C08G18/58 , C08G18/62 , C08G18/64 , C08G18/78 , C08G18/79 , C08G18/80 , C08G59/42 , C08G59/50 , C09D133/04 , C09D143/04 , C09D163/00 , C09D175/00 , C09D175/04
CPC分类号： C08G18/7893 , C08G18/4294 , C08G18/581 , C08G18/62 , C08G18/6229 , C08G18/6237 , C08G18/6407 , C08G18/792 , C08G18/8064 , C08G59/5086 , C09D175/00 , Y10T428/31551
摘要： A curable composition and process of applying the composition and the resulting composite coatings provide improved resistance to acid etch and mar. The curable composition has (a) about 30 to 90 percent by weight, based on total weight of resin solids, of a film-forming composition selected from the group consisting of:(i) a polyepoxide and a polyacid crosslinking agent;(ii) an acrylosilane polymer, an acrylic polyol polymer, and optionally an alkylated melamine-formaldehyde crosslinking agent; and(iii) a polyisocyanate and a polymer having at least one group that is reactive with isocyanate; and(b) about 10 to 70 percent by weight, based on total weight of resin solids, of a tricarbamoyl triazine compound of the formula: C.sub.3 N.sub.3 (NHCOXR).sub.3, wherein X is nitrogen, oxygen, sulfur, phosphorus, or carbon, and R is a lower alkyl group having 1 to 12 carbon atoms, or mixtures of lower alkyl groups. The process involves applying the curable coating as a monocoat on a cured primer surfacer coating on a substrate or as a clear coat on a curable base coat that are cured separately or conjointly. The composite coating includes the primer surfacer and monocoat on a substrate or the color-plus-clear coating on an electrodeposited coating layer or a primer surfacer coating layer.
摘要翻译：可固化组合物和施加组合物和所得复合涂层的方法提供了改善的耐酸蚀和耐蚀性。可固化组合物具有（a）基于树脂固体的总重量计约30至90重量％的选自以下的成膜组合物：（i）聚环氧化物和多酸交联剂; （ii）丙烯基硅烷聚合物，丙烯酸多元醇聚合物和任选的烷基化三聚氰胺 - 甲醛交联剂; 和（iii）多异氰酸酯和具有至少一个与异氰酸酯反应的基团的聚合物; 和（b）基于树脂固体的总重量，约10-70重量％的下式的三氨甲酰三嗪化合物：C3N3（NHCOXR）3，其中X是氮，氧，硫，磷或碳，以及 R是具有1至12个碳原子的低级烷基或低级烷基的混合物。该方法包括将可固化涂层作为单壳体涂覆在基底上的固化的底漆表面涂层上，或者作为可固化底涂层上的透明涂层单独或共同固化。复合涂层包括底物上的底漆二
面体和单面涂层或电沉积涂层或底漆二层涂层上的彩色 - 透明涂层。

5. 发明授权

US4971837A Chip resistant coatings and methods of application 失效
标题翻译：耐芯片涂层和应用方法
公开(公告)号：US4971837A
公开(公告)日：1990-11-20
申请号：US333352
申请日：1989-04-03
申请人： Jonathan T. Martz , Thomas W. Kelly , Rostyslaw Dowbenko , James A. Meier , Anthony C. Palermo
发明人： Jonathan T. Martz , Thomas W. Kelly , Rostyslaw Dowbenko , James A. Meier , Anthony C. Palermo
IPC分类号： B05D1/36 , C08F299/06 , C08G18/67
CPC分类号： C08F299/065 , B05D7/542 , C08G18/671
摘要： Disclosed is a liquid coating composition, useful for making a chip resistant coating, comprising a binder of: a first and a second urethane resin each containing terminal, reactive ethylenically unsaturated groups. Each urethane resin is prepared by reacting components comprising (A) an isocyanate-terminated prepolymer which is the product of reacting an organic polyisocyanate with an organic polyol with (B) an isocyanate reactive group-containing unsaturated monomer selected from hydroxyalkyl acrylates, hydroxyalkyl methacrylates and hydroxyalkyl acrylamides. The organic polyol for the first urethane resin has a hydroxyl functionality of 3 or more; the organic polyol for the second urethane resin has a hydroxyl functionality of less than three; and the average functionality of the polyols utilized for the first and second urethane resins is less than three.Also disclosed is a method of making a cured chip resistant, coating.

6. 发明授权

US4157994A Low temperature bake water reducible acrylic enamel 失效
标题翻译：低温烘干水可稀释丙烯酸搪瓷
公开(公告)号：US4157994A
公开(公告)日：1979-06-12
申请号：US833770
申请日：1977-09-16
申请人： Stuart M. Totty , James A. Meier
发明人： Stuart M. Totty , James A. Meier
IPC分类号： C08F20/00 , C08F20/26 , C08F212/00 , C08G12/42 , C08L25/00 , C08L33/00 , C08L33/02 , C08L33/04 , C08L59/00 , C08L61/20 , C09D125/00 , C09D125/06 , C09D133/02 , C09D133/04 , C09D133/06 , C09D133/20 , C09D161/20
CPC分类号： C09D133/066 , C08G12/427 , C09D125/06 , C09D133/20 , C08L61/20
摘要： A water-reducible acrylic enamel coating composition capable of being substantially completely cured at a relatively low temperature, such as about 250.degree. F. and containing a water-miscible partially etherified melamine formaldehyde cross-linking agent and an acrylic copolymerization product of about 3% to about 8% of an unsaturated carboxylic acid, about 10% to 30% of a hydroxy functional monomer and about 62% to 87% of a nonfunctional monomer. The acrylic copolymer is further characterized as having a glass transition temperature of about -10.degree. C. to 45.degree. C. and a molecular weight of about 2,000 to about 100,000. The aminoplast resin preferably is only partially etherified and contains about 10% to about 30% by weight reactive methylol groups.
摘要翻译：一种可水稀释的丙烯酸搪瓷涂料组合物，其能够在比较低的温度例如约250°F下基本上完全固化，并含有水混溶的部分醚化的三聚氰胺甲醛交联剂和约3％至约8％的不饱和羧酸，约10％至30％的羟基官能单体和约62％至87％的非官能单体。丙烯酸共聚物的特征还在于具有约-10℃至45℃的玻璃化转变温度和约2,000至约100,000的分子量。氨基塑料树脂优选仅部分醚化并且含有约10重量％至约30重量％的反应性羟甲基。

7. 发明授权

US5066733A Chip resistant coatings and methods of application 失效
标题翻译：耐芯片涂层和应用方法
公开(公告)号：US5066733A
公开(公告)日：1991-11-19
申请号：US556681
申请日：1990-07-23
申请人： Jonathan T. Martz , Thomas W. Kelly , Rostyslaw Dowbenko , James A. Meier , Anthony C. Palermo
发明人： Jonathan T. Martz , Thomas W. Kelly , Rostyslaw Dowbenko , James A. Meier , Anthony C. Palermo
IPC分类号： B05D1/36 , C08F299/06 , C08G18/67
CPC分类号： C08F299/065 , B05D7/542 , C08G18/671
摘要： Disclosed is a liquid coating composition, useful for making a chip resistant coating, comprising a binder of: a first and a second urethane resin each containing terminal, reactive ethylenically unsaturated groups. Each urethane resin is prepared by reacting components comprising (A) an isocyanate-terminated prepolymer which is the product of reacting an organic polyisocyanate with an organic polyol with (B) an isocyanate reactive group-containing unsaturated monomer selected from hydroxyalkyl acrylates, hydroxyalkyl methacrylates and hydroxyalkyl acrylamides. The organic polyol for the first urethane resin has a hydroxyl functionality of 3 or more; the organic polyol for the second urethane resin has a hydroxyl functionality of less than three; and the average functionality of the polyols utilized for the first and second urethane resins is less than three.Also disclosed is a method of making a cured chip resistant, coating.
摘要翻译：公开了一种可用于制造耐芯片涂层的液体涂料组合物，其包含粘合剂，第一和第二聚氨酯树脂各自含有末端，反应性烯属不饱和基团。每个聚氨酯树脂通过使包含（A）异氰酸酯封端的预聚物（其是有机多异氰酸酯与有机多元醇反应的产物）与（B）含异氰酸酯反应性基团的不饱和单体的选自丙烯酸羟烷基酯，甲基丙烯酸羟烷基酯和羟烷基丙烯酰胺。第一聚氨酯树脂的有机多元醇的羟基官能度为3以上; 第二聚氨酯树脂的有机多元醇的羟基官能度小于3; 并且用于第一和第二聚氨酯树脂的多元醇的平均官能度小于3。还公开了一种制造耐固化芯片的涂层的方法。

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