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    • 3. 发明授权
    • Phosphorus-nitrogen-based intumescent flame retardant and synthetic method and use thereof
    • US10301548B2
    • 2019-05-28
    • US15032537
    • 2014-05-23
    • Institute of Advanced Technology, University of Science and Technology of China
    • Zhiyong Wang
    • C09K21/12C09D7/63D21H17/07D21H17/00D06M13/282D21H17/10D21H17/28D21H17/25D21H21/34C09D5/18C08K5/00
    • This disclosure provides high-efficiency and low-energy-consumption synthetic methods of a series of phosphorus-nitrogen-based intumescent flame retardants and the use thereof in paint flame retarding. 1 part by weight of a phosphorization agent and 0.5-4.0 parts by weight of a nitrogen-containing foaming agent are uniformly mixed and stirred at room temperature, and an amount of water is further added to emit heat and initiate reaction. 0.5-3.0 parts by weight of a charring agent and 0.5-4.0 parts by weight of a hydroxy-containing polyfuctional crosslinking agent are then added, and reacted with stirring. An amine compound is finally added for neutralization until pH value is 5-8, and solid liquid separation is performed. The solid portion is dried to obtain a main body portion of a phosphorus-nitrogen-based intumescent flame retardant. The resultant filtrate is diluted with ⅓-⅔ volume of water, and a flame retardant product is obtained. This flame retardant product is mainly used in the flame retarding of paper and cotton fabrics. The main body and different proportions of other nitrogen-containing foaming agents and charring agents are uniformly mixed and pulverized into nano- and micro-scale, and a phosphorus-nitrogen-based intumescent flame retardant is obtained. The nano- and micro-scale phosphorus-nitrogen intumescent flame retardant is mixed into a paint at a weight ratio of 15-30%, to obtain a flame-retardant paint which is capable of maintaining mechanical and physical properties of the paint. The phosphorus-nitrogen-based intumescent flame retardant of this disclosure is an intumescent flame retardant having a synergistic effect of phosphorus and nitrogen.
    • 4. 发明申请
    • PHOSPHORUS-NITROGEN INTUMESCENT FLAME RETARDANT, SYNTHESIS METHOD THEREFOR AND USE THEREOF
    • 磷 - 硝基灭火剂阻燃剂及其合成方法及其应用
    • US20160272892A1
    • 2016-09-22
    • US15032537
    • 2014-05-23
    • INSTITUTE OF ADVANCED TECHNOLOGY, UNIVERSITY OF SCIENCE AND TECHNOLOGY OF CHINA
    • Zhiyong Wang
    • C09K21/12D21H21/34D06M13/282D21H17/25D21H17/28C09D5/18D21H17/10
    • C09K21/12C08K5/0066C09D5/185C09D7/63D06M13/282D21H17/07D21H17/10D21H17/25D21H17/28D21H17/71D21H21/34
    • This disclosure provides high-efficiency and low-energy-consumption synthetic methods of a series of phosphorus-nitrogen-based intumescent flame retardants and the use thereof in paint flame retarding. 1 part by weight of a phosphorization agent and 0.5-4.0 parts by weight of a nitrogen-containing foaming agent are uniformly mixed and stirred at room temperature, and an amount of water is further added to emit heat and initiate reaction. 0.5-3.0 parts by weight of a charring agent and 0.5-4.0 parts by weight of a hydroxy-containing polyfuctional crosslinking agent are then added, and reacted with stirring. An amine compound is finally added for neutralization until pH value is 5-8, and solid liquid separation is performed. The solid portion is dried to obtain a main body portion of a phosphorus-nitrogen-based intumescent flame retardant. The resultant filtrate is diluted with 1/3-2/3 volume of water, and a flame retardant product is obtained. This flame retardant product is mainly used in the flame retarding of paper and cotton fabrics. The main body and different proportions of other nitrogen-containing foaming agents and charring agents are uniformly mixed and pulverized into nano- and micro-scale, and a phosphorus-nitrogen-based intumescent flame retardant is obtained. The nano- and micro-scale phosphorus-nitrogen intumescent flame retardant is mixed into a paint at a weight ratio of 15-30%, to obtain a flame-retardant paint which is capable of maintaining mechanical and physical properties of the paint. The phosphorus-nitrogen-based intumescent flame retardant of this disclosure is an intumescent flame retardant having a synergistic effect of phosphorus and nitrogen.
    • 该公开内容提供了一系列磷 - 氮系膨胀型阻燃剂的高效低能耗合成方法及其在油漆阻燃剂中的应用。 将1重量份磷化剂和0.5-4.0重量份含氮发泡剂在室温下均匀混合并搅拌,并进一步加入一定量的水进行发热并引发反应。 0.5-3.0重量份的炭化剂和0.5-4.0重量份的含羟基的多官能交联剂,然后在搅拌下反应。 最后加入胺化合物进行中和,直到pH值为5-8,进行固体分液。 将固体部分干燥以获得磷 - 氮系膨胀型阻燃剂的主体部分。 将得到的滤液用1 / 3-2 / 3体积的水稀释,得到阻燃剂。 这种阻燃产品主要用于纸和棉织物的阻燃。 将其主体和不同比例的其它含氮发泡剂和炭化剂均匀混合并粉碎成纳米和微米级,得到磷 - 氮系膨胀型阻燃剂。 将纳米和微尺度的磷 - 氮膨胀型阻燃剂以15-30%的重量比混合到涂料中,得到能够保持涂料机械和物理性能的阻燃涂料。 本公开的磷 - 氮系膨胀型阻燃剂是具有磷和氮的协同作用的膨胀型阻燃剂。