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1. 发明申请

US20120157713A1 METHOD FOR PREPARATION OF 4,4'-DINITRODIPHENYLAMINE AND 4,4'-BIS(ALKYLAMINO)DIPHENYLAMINE WITH THE BASE CATALYST COMPLEX 有权
标题翻译： 4,4'-二氨基苯胺和4,4'-双（双（甲基）氨基）二苯胺与基础催化剂复合物的制备方法
公开(公告)号：US20120157713A1
公开(公告)日：2012-06-21
申请号：US13162610
申请日：2011-06-17
申请人： Jin-Eok Kim , Seoung-IL Kim , Han Jin Kwag , Sang hee Park
发明人： Jin-Eok Kim , Seoung-IL Kim , Han Jin Kwag , Sang hee Park
IPC分类号： C07C209/36 , C07C209/78
CPC分类号： C07C201/12 , C07C209/36 , C07C211/56
摘要： Provided is a method for preparing 4,4′-dinitrodiphenylamine (4,4′-DNDPA) in high yield via the NASH reaction using a mixture of a bis-quaternary ammonium base and a base catalyst for the reaction of urea with nitrobenzene, and a method of preparing 4,4′-bis(alkylamino)diphenylamine (4,4′BAADA) in high yield and purity by hydrogenating the resulting 4,4′-DNDPA with a ketone in the presence of hydrogen and hydrogenation catalyst. The catalyst complex used in the present invention allows easy recovery, provides superior alkaline stability and is capable of reducing production cost.
摘要翻译：提供了通过使用二季铵碱和碱催化剂的混合物通过NASH反应以高产率制备4,4'-二硝基二苯胺（4,4'-DNDPA）的方法，用于尿素与硝基苯的反应，以及通过在氢气和氢化催化剂存在下用酮氢化所得的4,4'-DNDPA，以高产率和纯度制备4,4'-双（烷基氨基）二苯胺（4,4'BAADA）的方法。本发明中使用的催化剂配合物容易回收，提供优异的碱稳定性，能够降低生产成本。

2. 发明授权

US08759587B2 Method for preparation of 4,4′-dinitrodiphenylamine and 4,4′-bis(alkylamino)diphenylamine by using 4-nitroaniline 有权
标题翻译：通过使用4-硝基苯胺制备4,4'-二硝基二苯胺和4,4'-双（烷基氨基）二苯胺的方法
公开(公告)号：US08759587B2
公开(公告)日：2014-06-24
申请号：US13162618
申请日：2011-06-17
申请人： Jin-Eok Kim , Seoung-Il Kim , Han Jin Kwag , Sang hee Park
发明人： Jin-Eok Kim , Seoung-Il Kim , Han Jin Kwag , Sang hee Park
IPC分类号： C07C209/00
CPC分类号： C07C209/36 , C07C201/12 , C07C211/55 , C07C211/56
摘要： Provided is a method of preparing 4,4′-dinitrodiphenylamine (4,4′-DNDPA) in high yield by reacting 4-nitroaniline with excess nitrobenzene via the NASH reaction, and a method of preparing 4,4′-bis(alkylamino)diphenylamine (4,4′BAADA) in high yield and purity by hydrogenating the resulting 4,4′-DNDPA with a ketone compound in the presence of hydrogen and hydrogenation catalyst. The disclosed process is simple, allows selective preparation of 4,4′-DNDPA without byproducts, and thus allows preparation of 4,4′-BAADA in high yield without a complicated purification procedure.
摘要翻译：提供了通过使NASH反应使4-硝基苯胺与过量硝基苯反应而以高产率制备4,4'-二硝基二苯胺（4,4'-DNDPA）的方法，以及制备4,4'-二（烷基氨基）二苯胺（4,4'BAADA）以高产率和纯度通过在氢气和氢化催化剂存在下用酮化合物氢化所得4,4'- DNDPA。所公开的方法简单，允许选择性制备4,4'- DNDPA而不产生副产物，因此允许以高产率制备4,4'-BAADA而无需复杂的纯化程序。

3. 发明授权

US08283477B2 Method for preparing N-substituted maleimides 有权
标题翻译：制备N-取代马来酰亚胺的方法
公开(公告)号：US08283477B2
公开(公告)日：2012-10-09
申请号：US12999420
申请日：2009-06-24
申请人： Jin-Eok Kim , Seung-il Kim , Han-Jin Kwag
发明人： Jin-Eok Kim , Seung-il Kim , Han-Jin Kwag
IPC分类号： A61K31/4015 , A61K31/402 , C07D207/40
CPC分类号： C07D207/448
摘要： The present invention relates to a method of preparing N-substituted maleimide in high purity and high yield, wherein, unlike a conventional method of preparing N-substituted maleimide after preparing N-substituted maleamic acid, an organic solvent, an acid catalyst, a dehydration co-catalyst and a stabilizer are added into a reactor without separately preparing N-substituted maleamic acid, and then a primary amine is added into the reactor to form an amine salt, maleic anhydride is added into the reactor, and the resulting mixture is subjected to a dehydration-cyclization reaction, wherein water produced during the reaction is azeotropically distilled with the organic solvent so as to effectively suppress formation of a maleimide polymer. Particularly, the invention simplifies the process, has high yield, minimizes side reactions, eliminates the introduction of expensive raw materials and the complicated treatment of the reaction solution and significantly shortens the time over which the raw materials and maleic anhydride are added.
摘要翻译：本发明涉及以高纯度和高收率制备N-取代马来酰亚胺的方法，其中与制备N-取代马来酰胺酸，有机溶剂，酸催化剂，脱水剂的常规制备N-取代马来酰亚胺的方法不同助催化剂和稳定剂加入到反应器中，而无需单独制备N-取代的马来酰胺酸，然后将伯胺加入到反应器中以形成胺盐，将马来酸酐加入到反应器中，并将所得混合物进行脱水 - 环化反应，其中在反应期间产生的水与有机溶剂共沸蒸馏，以有效抑制马来酰亚胺聚合物的形成。特别地，本发明简化了方法，具有高产率，最小化副反应，消除了昂贵原料的引入和复杂的反应溶液处理，并显着缩短了添加原料和马来酸酐的时间。

4. 发明申请

US20110124882A1 Method for Preparing N-Substituted Maleimides 有权
标题翻译： N-取代的马来酰亚胺的制备方法
公开(公告)号：US20110124882A1
公开(公告)日：2011-05-26
申请号：US12999420
申请日：2009-06-24
申请人： Jin-Eok Kim , Seung-il Kim , Han-Jin Kwag
发明人： Jin-Eok Kim , Seung-il Kim , Han-Jin Kwag
IPC分类号： C07D207/448
CPC分类号： C07D207/448
摘要： The present invention relates to a method of preparing N-substituted maleimide in high purity and high yield, wherein, unlike a conventional method of preparing N-substituted maleimide after preparing N-substituted maleamic acid, an organic solvent, an acid catalyst, a dehydration co-catalyst and a stabilizer are added into a reactor without separately preparing N-substituted maleamic acid, and then a primary amine is added into the reactor to form an amine salt, maleic anhydride is added into the reactor, and the resulting mixture is subjected to a dehydration-cyclization reaction, wherein water produced during the reaction is azeotropically distilled with the organic solvent so as to effectively suppress formation of a maleimide polymer. Particularly, the invention simplifies the process, has high yield, minimizes side reactions, eliminates the introduction of expensive raw materials and the complicated treatment of the reaction solution and significantly shortens the time over which the raw materials and maleic anhydride are added.
摘要翻译：本发明涉及以高纯度和高收率制备N-取代马来酰亚胺的方法，其中与制备N-取代马来酰胺酸，有机溶剂，酸催化剂，脱水剂的常规制备N-取代马来酰亚胺的方法不同助催化剂和稳定剂加入到反应器中，而无需单独制备N-取代的马来酰胺酸，然后将伯胺加入到反应器中以形成胺盐，将马来酸酐加入到反应器中，并将所得混合物进行脱水 - 环化反应，其中在反应期间产生的水与有机溶剂共沸蒸馏，以有效抑制马来酰亚胺聚合物的形成。特别地，本发明简化了方法，具有高产率，最小化副反应，消除了昂贵原料的引入和复杂的反应溶液处理，并显着缩短了添加原料和马来酸酐的时间。

5. 发明授权

US08835687B2 Method for preparation of 4,4′-dinitrodiphenylamine and 4,4′-bis(alkylamino)diphenylamine with the base catalyst complex 有权
标题翻译： 4,4'-二硝基二苯胺和4,4'-双（烷基氨基）二苯胺与碱催化剂络合物的制备方法
公开(公告)号：US08835687B2
公开(公告)日：2014-09-16
申请号：US13162610
申请日：2011-06-17
申请人： Jin-Eok Kim , Seoung-IL Kim , Han Jin Kwag , Sang hee Park
发明人： Jin-Eok Kim , Seoung-IL Kim , Han Jin Kwag , Sang hee Park
IPC分类号： C07C209/00 , C07C209/36 , C07C201/12
CPC分类号： C07C201/12 , C07C209/36 , C07C211/56
摘要： Provided is a method for preparing 4,4′-dinitrodiphenylamine (4,4′-DNDPA) in high yield via the NASH reaction using a mixture of a bis-quaternary ammonium base and a base catalyst for the reaction of urea with nitrobenzene, and a method of preparing 4,4′-bis(alkylamino)diphenylamine (4,4′BAADA) in high yield and purity by hydrogenating the resulting 4,4′-DNDPA with a ketone in the presence of hydrogen and hydrogenation catalyst. The catalyst complex used in the present invention allows easy recovery, provides superior alkaline stability and is capable of reducing production cost.
摘要翻译：提供了通过使用二季铵碱和碱催化剂的混合物通过NASH反应以高产率制备4,4'-二硝基二苯胺（4,4'-DNDPA）的方法，用于尿素与硝基苯的反应，以及通过在氢气和氢化催化剂存在下用酮氢化所得的4,4'-DNDPA，以高产率和纯度制备4,4'-双（烷基氨基）二苯胺（4,4'BAADA）的方法。本发明中使用的催化剂配合物容易回收，提供优异的碱稳定性，能够降低生产成本。

6. 发明申请

US20120157714A1 METHOD FOR PREPARATION OF 4,4'-DINITRODIPHENYLAMINE AND 4,4'-BIS(ALKYLAMINO)DIPHENYLAMINE BY USING 4-NITROANILINE 有权
标题翻译：通过使用4-硝基苯胺制备4,4'-二氨基苯胺和4,4'-双（亚氨基）二苯胺的方法
公开(公告)号：US20120157714A1
公开(公告)日：2012-06-21
申请号：US13162618
申请日：2011-06-17
申请人： Jin-Eok Kim , Seoung-IL Kim , Han Jin Kwag , Sang hee Park
发明人： Jin-Eok Kim , Seoung-IL Kim , Han Jin Kwag , Sang hee Park
IPC分类号： C07C209/02 , C07C209/36
CPC分类号： C07C209/36 , C07C201/12 , C07C211/55 , C07C211/56
摘要： Provided is a method of preparing 4,4′-dinitrodiphenylamine (4,4′-DNDPA) in high yield by reacting 4-nitroaniline with excess nitrobenzene via the NASH reaction, and a method of preparing 4,4′-bis(alkylamino)diphenylamine (4,4′BAADA) in high yield and purity by hydrogenating the resulting 4,4′-DNDPA with a ketone compound in the presence of hydrogen and hydrogenation catalyst. The disclosed process is simple, allows selective preparation of 4,4′-DNDPA without byproducts, and thus allows preparation of 4,4′-BAADA in high yield without a complicated purification procedure.
摘要翻译：提供了通过使NASH反应使4-硝基苯胺与过量硝基苯反应而以高产率制备4,4'-二硝基二苯胺（4,4'-DNDPA）的方法，以及制备4,4'-二（烷基氨基）二苯胺（4,4'BAADA）以高产率和纯度通过在氢气和氢化催化剂存在下用酮化合物氢化所得4,4'- DNDPA。所公开的方法简单，允许选择性制备4,4'- DNDPA而不产生副产物，因此允许以高产率制备4,4'-BAADA而无需复杂的纯化程序。

7. 发明申请

US20120197044A1 PRODUCTION METHOD FOR 4,4'-BIS(ALKYLAMINO) DIPHENYLAMINE 审中-公开
标题翻译： 4,4'-双（二氨基）二苯胺的生产方法
公开(公告)号：US20120197044A1
公开(公告)日：2012-08-02
申请号：US13502052
申请日：2010-09-30
申请人： Jin Eok Kim , Seung Il Kim , Jung Hee Jang , Han Jin Kwag
发明人： Jin Eok Kim , Seung Il Kim , Jung Hee Jang , Han Jin Kwag
IPC分类号： C07C209/36
CPC分类号： C07C209/36 , C07C211/54
摘要： The present invention relates to a production method for 4,4′-bis(alkylamino)diphenylamine, and more specifically relates to a method in which 4,4′-dinitrodiphenylamine (4,4′-DNDPA) is produced by reacting urea with nitrobenzene in the presence of a polar organic solvent and a base catalyst, and then the 4,4′-bis(alkylamino)diphenylamine (4,4′-BAADA) is produced by subjecting the 4,4′-DNDPA and a ketone to hydrogenation in the presence of a hydrogenation catalyst.
摘要翻译：本发明涉及一种4,4'-双（烷基氨基）二苯胺的制备方法，更具体地说涉及一种方法，其中4,4'-二硝基二苯胺（4,4'-DNDPA）是通过尿素与硝基苯在极性有机溶剂和碱催化剂存在下，然后通过使4,4'-DNDPA和酮氢化得到4,4'-双（烷基氨基）二苯胺（4,4'-BAADA）在氢化催化剂的存在下。

8. 发明授权

US07468417B2 Method of preparing cyclic olefin copolymer having controlled gel contents 失效
标题翻译：制备具有受控凝胶含量的环烯烃共聚物的方法
公开(公告)号：US07468417B2
公开(公告)日：2008-12-23
申请号：US11467100
申请日：2006-08-24
申请人： Youngchan Jang , Hyun-Kyung Sung , Han Jin Kwag
发明人： Youngchan Jang , Hyun-Kyung Sung , Han Jin Kwag
IPC分类号： C08G61/08 , C08F2/38 , C08F4/78
CPC分类号： C08G61/08
摘要： The present invention relates to a method of preparing a copolymer having controlled gel content by polymerizing cyclic olefin compound by ROMP (Ring Opening Metathesis Polymerization), and more precisely, a method of preparing cyclic olefin copolymer with high yield, in which a complex prepared by mixing a W salt compound and an organoaluminum halide compound is used as a catalyst in the presence or absence of a molecular weight regulator, and a method of controlling gel formation by regulating the composition of cyclic olefin monomer composing a copolymer as shown in the following Empirical Formula 1 without using a reaction speed regulator or gel formation inhibitor. (Empirical Formula 1) Norbornene=30˜70 weight % Cyclic olefin compound=70˜30 weight % At this time, the cyclic olefin compound presented in the above Empirical Formula 1 is one or more compounds selected from a group consisting of dicyclopentadiene and compounds represented by the following Formula 1. Wherein, m is an integer of 0-1, R1 is C1-C5 alkyl and R2 is H or C1-C10 alkyl.
摘要翻译：本发明涉及通过ROMP（开环复分解聚合）聚合环烯烃化合物制备具有控制凝胶含量的共聚物的方法，更确切地说，一种以高产率制备环烯烃共聚物的方法，其中将由在存在或不存在分子量调节剂的情况下，将W盐化合物和有机铝卤化物混合物用作催化剂，以及通过调节构成共聚物的环烯烃单体的组成来控制凝胶形成的方法，如以下实验式1不使用反应速度调节剂或凝胶形成抑制剂。（实验式1）降冰片烯= 30〜70重量％环状烯烃化合物= 70〜30重量％此时，上述实验式1中所示的环状烯烃化合物是选自二环戊二烯和化合物其中m为0-1的整数，R1为C1-C5烷基，R2为H或C1-C10烷基。

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