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    • 6. 发明授权
    • Method for the production of noble metal oxalate complexes
    • 贵金属草酸盐配合物的制备方法
    • US09156767B2
    • 2015-10-13
    • US14432224
    • 2013-09-24
    • Heraeus Precious Metals GmbH & Co. KG
    • Richard WalterFlorian EweinerWalter LåssigJörg Fuchs Alameda
    • C07C51/14C07C51/41
    • C07C51/418C07C51/412C07C55/07
    • The production of noble metal oxalate complexes from noble metal precursors and oxalic acid and/or oxalic acid salts is an exothermic reaction, in which heat and CO2 are produced, is described. The temperature can increase above the decomposition point of the noble metal oxalate complexes in the course of the reaction, which simultaneously releases more CO2. For safety reasons, when the reaction is carried out on a large scale, it is therefore necessary to take into consideration that the product must not be decomposed by heat that is produced during the reaction. Therefore, according to the invention, a method for the production of noble metal oxalate complexes is provided, in which the product noble metal oxalate complexes are added to the reaction mixture as an auto-catalyst.
    • 从贵金属前体和草酸和/或草酸盐生产贵金属草酸盐络合物是产生热和二氧化碳的放热反应。 在反应过程中,温度可以高于贵金属草酸盐络合物的分解点,同时释放更多的二氧化碳。 为了安全起见,当大规模进行反应时,因此必须考虑到产物不能被反应中产生的热分解。 因此,根据本发明,提供了一种生产贵金属草酸盐配合物的方法,其中将产物贵金属草酸盐配合物作为自动催化剂加入到反应混合物中。