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1. 发明授权

US07683145B2 Method for the emulsion polymerization of olefins 失效
标题翻译：烯烃乳液聚合方法
公开(公告)号：US07683145B2
公开(公告)日：2010-03-23
申请号：US10521117
申请日：2003-07-16
申请人： Mubarik Mahmood Chowdhry , Markus Schmid , Peter Preishuber-Pfluegl , Xavier Sava , Horst Weiss , Stefan Mecking , Florian M. Bauers
发明人： Mubarik Mahmood Chowdhry , Markus Schmid , Peter Preishuber-Pfluegl , Xavier Sava , Horst Weiss , Stefan Mecking , Florian M. Bauers
IPC分类号： C08F4/00 , C08F2/00
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/26 , C08F2/24 , C08F4/80 , C08F2500/02 , C08F2500/03 , C08F210/14 , C08F212/08 , C08F210/06 , C08F210/08
摘要： A method for the emulsion polymerization of one or more olefins by reacting a ligand of general formulae Ia and Ib or a mixture of at least two ligands Ia or Ib, wherein R respectively represents one or several of the following radicals; hydrogen, halogen, nitrile, C1-C12-alkyl groups, C1-C12-alkoxy groups, C7-C13-aralkyl groups, C6-C14-aryl groups, and wherein identical or different compounds of general formulae Ia and Ib can, optionally, be concatenated by one or several bridges, with a phosphine compound PR3′ and a metal compound of general formula M(L2)2 or M(L2)2 (L1)z, wherein the variables are defined as follows: M is a transition metal of groups 7-10 in the periodic system of the elements; L1 represents phosphanes (R5)xPH3-x or amines (R5)xNH3-x with identical or different radicals R5, ether (R5)2O, H2O, alkohols (R5)OH, pyridine, pyridine derivatives of formula C5H5-x(R5)xN, CO, C1-C12-alkylnitriles, C6-C14-arylnitriles or ethylenically unsaturated double bond systems, wherein x is a whole number ranging from 0-3, L2 represents halogenide ions R6xNH3-x, wherein x is a whole number ranging from 0 3 and R6 represents C1-C12-alkyl, and C1-C6-alkylane ions, allylane ions, benzylane ions or arylane ions, wherein L1 and L2 can be concatenated with each other by one or several covalent bonds, z is a number ranging from 0 4. The invention also relates to the immediate use of the reaction product in the polymerization or copolymerization of olefins in water or in a solvent mixture containing at least 50 vol. % water in the presence of an emulsifier and, optionally, in the presence of an activator.
摘要翻译：通过使通式Ia和Ib的配体或至少两种配体Ia或Ib的混合物反应来使一种或多种烯烃乳液聚合的方法，其中R分别表示一个或几个以下基团; 氢，卤素，腈，C 1 -C 12 - 烷基，C 1 -C 12 - 烷氧基，C 7 -C 13 - 芳烷基，C 6 -C 14 - 芳基，并且其中相同或不同的通式Ia和Ib化合物可以任选地，通过一个或几个桥连，与膦化合物PR3'和通式M（L2）2或M（L2）2（L1）z的金属化合物连接，其中变量定义如下：M是过渡金属在元素周期性系统中的第7-10组; L1代表具有相同或不同基团的磷烷（R5）xPH3-x或具有相同或不同基团的胺（R5）xNH3-x5，醚（R5）2O，H2O，烷醇（R5）OH，吡啶，式C5H5-x（R5） xN，CO，C 1 -C 12烷基腈，C 6 -C 14 - 芳基腈或烯属不饱和双键体系，其中x为0-3的整数，L 2表示卤化物离子R 6 x N H 3-x，其中x为 O 3和R 6表示C 1 -C 12 - 烷基和C 1 -C 6 - 烷基离子，烯丙基离子，苯甲烷离子或芳基烷基离子，其中L1和L2可以通过一个或几个共价键彼此连接，z是数字范围本发明还涉及立即使用反应产物在烯烃在水中或在含有至少50体积％的溶剂混合物中的聚合或共聚中。在乳化剂存在下，和任选地，在活化剂存在下，水分。

2. 发明授权

US07566760B2 Preparation of aqueous polymer dispersions 失效
标题翻译：聚合物水分散体的制备
公开(公告)号：US07566760B2
公开(公告)日：2009-07-28
申请号：US10524216
申请日：2003-07-24
申请人： Mubarik Mahmood Chowdhry , Markus Schmid , Peter Preishuber-Pfluegl , Xavier Sava , Horst Weiss , Stefan Mecking , Martin Zuideveld , Florian M. Bauers
发明人： Mubarik Mahmood Chowdhry , Markus Schmid , Peter Preishuber-Pfluegl , Xavier Sava , Horst Weiss , Stefan Mecking , Martin Zuideveld , Florian M. Bauers
IPC分类号： C08F4/26 , C08F4/70 , C08F2/22
CPC分类号： C08F110/02 , C08F4/80 , C08F2/24
摘要： The invention relates to a method for the production of aqueous polymer dispersions, by the polymerisation of one or more olefins in aqueous media in the presence of dispersing agents and optionally organic solvents, characterised in that the polymerisation of the olefin(s) is catalysed by means of one or more complex compounds of general formula (I), where at least one of the groups R1 to R9 must be in the form of a group of the following general formula (II) where Z=an electron-withdrawing group and n=a whole number from 1 to 5.
摘要翻译：本发明涉及通过在分散剂和任选的有机溶剂的存在下在水性介质中聚合一种或多种烯烃的方法来制备聚合物水分散体，其特征在于烯烃的聚合由一种或多种通式（I）的络合物的手段，其中基团R 1至R 9中的至少一个必须为以下通式（II）的基团的形式，其中Z =吸电子基团和n =从1到5的整数。

3. 发明授权

US07129292B1 Method for the emulsion polymerization of olefins 失效
标题翻译：烯烃乳液聚合方法
公开(公告)号：US07129292B1
公开(公告)日：2006-10-31
申请号：US10168113
申请日：2000-10-18
申请人： Marc Oliver Kristen , Lambertus Manders , Stefan Mecking , Florian M. Bauers , Rolf Mülhaupt
发明人： Marc Oliver Kristen , Lambertus Manders , Stefan Mecking , Florian M. Bauers , Rolf Mülhaupt
IPC分类号： C08F2/16
CPC分类号： C08F10/02 , C08F10/00 , C08F2/22 , C08F4/80 , C08F4/7006 , C08F4/7031 , C08F4/7022 , C08F4/7027 , C08F4/7019
摘要： A process for emulsion polymerizing one or more olefins involves reacting it/them with at least one complex compound of the formula Ia or b where M is a transition metal from groups 7 to 10 of the Periodic Table of the Elements and is preferably Ni in aqueous dispersion and at least one radical R1 to R3 and optionally one radical R4 to R9 contains a hydrophilic group X, selection being made from —SO3−, —O—PO32−, NH(R15)2+, N(R15)3+ or —(OCH2CH2)nOH, where n is an integer between 1 and 15. For the process of the invention it is optional to use an activator such as, for example, olefin complexes of rhodium or of nickel. This invention further relates to dispersions of polyolefins such as polyethylene and ethylene copolymers in water, for example, and to the use of the aqueous dispersions of the invention for paper applications such as paper coating or surface sizing, paints, adhesive base materials, molded foams such as mattresses, textile and leather applications, carpet back coatings, or pharmaceutical applications.
摘要翻译：用于将一种或多种烯烃乳液聚合的方法涉及使其与至少一种式Ia或b的络合物反应，其中M是元素周期表第7至10族的过渡金属，并且优选为Ni 分散体和至少一个R 1至R 3基团和任选的一个基团R 4至R 9包含一个亲水基团X，选自-SO 3 - ， - O-PO 3 - ， - NH 2， - NH （R 15）2 N 2 O 3 N（R 15）3 或+ - 或 - （OCH 2 CH 2）n OH，其中n是1和15之间的整数。对于本发明的方法任选使用活化剂，例如铑或镍的烯烃络合物。本发明还涉及聚烯烃如聚乙烯和乙烯共聚物在水中的分散体，以及本发明的水性分散体用于纸张涂布或表面施胶，涂料，粘合剂基材，模塑泡沫例如床垫，纺织和皮革应用，地毯背部涂层或药物应用。

4. 发明授权

US06800699B2 Process for the production of aqueous polymer dispersions 失效
标题翻译：生产聚合物水分散体的方法
公开(公告)号：US06800699B2
公开(公告)日：2004-10-05
申请号：US10015752
申请日：2001-12-17
申请人： Markus Schmid , Mubarik Mahmood Chowdhry , Marc Oliver Kristen , Stefan Mecking , Florian M. Bauers
发明人： Markus Schmid , Mubarik Mahmood Chowdhry , Marc Oliver Kristen , Stefan Mecking , Florian M. Bauers
IPC分类号： C08F444
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08K5/0091 , C08F4/74 , C08F2/32 , C08F2500/03
摘要： Process for the production of aqueous polymer dispersions by reaction of one or more olefinically unsaturated compounds in aqueous medium in the presence of a complex compound which possesses the structural element Y—M—E, E standing for nitrogen, M for a transition metal of groups 7 to 10 of the periodic system of the elements and Y for oxygen, sulfur, nitrogen or phosphorus, and which possesses no hydrophilic groups in its ligand system.
摘要翻译：通过一种或多种烯属不饱和化合物在水性介质中在配位化合物存在下反应生产含水聚合物分散体的方法，所述络合化合物具有结构元素YME，E代表氮，M代表7至10族的过渡金属元素的周期性系统，Y为氧，硫，氮或磷，并且在其配体体系中不具有亲水基团。

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