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1. 发明授权

US07566760B2 Preparation of aqueous polymer dispersions 失效
标题翻译：聚合物水分散体的制备
公开(公告)号：US07566760B2
公开(公告)日：2009-07-28
申请号：US10524216
申请日：2003-07-24
申请人： Mubarik Mahmood Chowdhry , Markus Schmid , Peter Preishuber-Pfluegl , Xavier Sava , Horst Weiss , Stefan Mecking , Martin Zuideveld , Florian M. Bauers
发明人： Mubarik Mahmood Chowdhry , Markus Schmid , Peter Preishuber-Pfluegl , Xavier Sava , Horst Weiss , Stefan Mecking , Martin Zuideveld , Florian M. Bauers
IPC分类号： C08F4/26 , C08F4/70 , C08F2/22
CPC分类号： C08F110/02 , C08F4/80 , C08F2/24
摘要： The invention relates to a method for the production of aqueous polymer dispersions, by the polymerisation of one or more olefins in aqueous media in the presence of dispersing agents and optionally organic solvents, characterised in that the polymerisation of the olefin(s) is catalysed by means of one or more complex compounds of general formula (I), where at least one of the groups R1 to R9 must be in the form of a group of the following general formula (II) where Z=an electron-withdrawing group and n=a whole number from 1 to 5.
摘要翻译：本发明涉及通过在分散剂和任选的有机溶剂的存在下在水性介质中聚合一种或多种烯烃的方法来制备聚合物水分散体，其特征在于烯烃的聚合由一种或多种通式（I）的络合物的手段，其中基团R 1至R 9中的至少一个必须为以下通式（II）的基团的形式，其中Z =吸电子基团和n =从1到5的整数。

2. 发明授权

US07683145B2 Method for the emulsion polymerization of olefins 失效
标题翻译：烯烃乳液聚合方法
公开(公告)号：US07683145B2
公开(公告)日：2010-03-23
申请号：US10521117
申请日：2003-07-16
申请人： Mubarik Mahmood Chowdhry , Markus Schmid , Peter Preishuber-Pfluegl , Xavier Sava , Horst Weiss , Stefan Mecking , Florian M. Bauers
发明人： Mubarik Mahmood Chowdhry , Markus Schmid , Peter Preishuber-Pfluegl , Xavier Sava , Horst Weiss , Stefan Mecking , Florian M. Bauers
IPC分类号： C08F4/00 , C08F2/00
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/26 , C08F2/24 , C08F4/80 , C08F2500/02 , C08F2500/03 , C08F210/14 , C08F212/08 , C08F210/06 , C08F210/08
摘要： A method for the emulsion polymerization of one or more olefins by reacting a ligand of general formulae Ia and Ib or a mixture of at least two ligands Ia or Ib, wherein R respectively represents one or several of the following radicals; hydrogen, halogen, nitrile, C1-C12-alkyl groups, C1-C12-alkoxy groups, C7-C13-aralkyl groups, C6-C14-aryl groups, and wherein identical or different compounds of general formulae Ia and Ib can, optionally, be concatenated by one or several bridges, with a phosphine compound PR3′ and a metal compound of general formula M(L2)2 or M(L2)2 (L1)z, wherein the variables are defined as follows: M is a transition metal of groups 7-10 in the periodic system of the elements; L1 represents phosphanes (R5)xPH3-x or amines (R5)xNH3-x with identical or different radicals R5, ether (R5)2O, H2O, alkohols (R5)OH, pyridine, pyridine derivatives of formula C5H5-x(R5)xN, CO, C1-C12-alkylnitriles, C6-C14-arylnitriles or ethylenically unsaturated double bond systems, wherein x is a whole number ranging from 0-3, L2 represents halogenide ions R6xNH3-x, wherein x is a whole number ranging from 0 3 and R6 represents C1-C12-alkyl, and C1-C6-alkylane ions, allylane ions, benzylane ions or arylane ions, wherein L1 and L2 can be concatenated with each other by one or several covalent bonds, z is a number ranging from 0 4. The invention also relates to the immediate use of the reaction product in the polymerization or copolymerization of olefins in water or in a solvent mixture containing at least 50 vol. % water in the presence of an emulsifier and, optionally, in the presence of an activator.
摘要翻译：通过使通式Ia和Ib的配体或至少两种配体Ia或Ib的混合物反应来使一种或多种烯烃乳液聚合的方法，其中R分别表示一个或几个以下基团; 氢，卤素，腈，C 1 -C 12 - 烷基，C 1 -C 12 - 烷氧基，C 7 -C 13 - 芳烷基，C 6 -C 14 - 芳基，并且其中相同或不同的通式Ia和Ib化合物可以任选地，通过一个或几个桥连，与膦化合物PR3'和通式M（L2）2或M（L2）2（L1）z的金属化合物连接，其中变量定义如下：M是过渡金属在元素周期性系统中的第7-10组; L1代表具有相同或不同基团的磷烷（R5）xPH3-x或具有相同或不同基团的胺（R5）xNH3-x5，醚（R5）2O，H2O，烷醇（R5）OH，吡啶，式C5H5-x（R5） xN，CO，C 1 -C 12烷基腈，C 6 -C 14 - 芳基腈或烯属不饱和双键体系，其中x为0-3的整数，L 2表示卤化物离子R 6 x N H 3-x，其中x为 O 3和R 6表示C 1 -C 12 - 烷基和C 1 -C 6 - 烷基离子，烯丙基离子，苯甲烷离子或芳基烷基离子，其中L1和L2可以通过一个或几个共价键彼此连接，z是数字范围本发明还涉及立即使用反应产物在烯烃在水中或在含有至少50体积％的溶剂混合物中的聚合或共聚中。在乳化剂存在下，和任选地，在活化剂存在下，水分。

3. 发明授权

US07462673B2 Method for producing aqueous polymer dispersions 失效
标题翻译：生产聚合物水分散体的方法
公开(公告)号：US07462673B2
公开(公告)日：2008-12-09
申请号：US10556605
申请日：2004-05-06
申请人： Markus Schmid , Mubarik Mahmood Chowdhry , Peter Preishuber-Pfluegl , Xavier Sava , Ekkehard Lindner , Mahmoud Sunjuk , Peter Wegner
发明人： Markus Schmid , Mubarik Mahmood Chowdhry , Peter Preishuber-Pfluegl , Xavier Sava , Ekkehard Lindner , Mahmoud Sunjuk , Peter Wegner
IPC分类号： C08F4/26
CPC分类号： C08F10/00 , C08F110/06 , C08F2/18 , C08F4/7016
摘要： Process for preparing an aqueous polymer dispersion by polymerization of at least one olefinically unsaturated compound in an aqueous medium in the presence of at least one dispersant and a solid polymerization catalyst.
摘要翻译：在至少一种分散剂和固体聚合催化剂的存在下，通过在水介质中聚合至少一种烯属不饱和化合物来制备聚合物水分散体的方法。

4. 发明授权

US08313935B2 Method for isolating polyhydroxyl alkanoates 失效
标题翻译：多羟基烷酸酯的分离方法
公开(公告)号：US08313935B2
公开(公告)日：2012-11-20
申请号：US13002404
申请日：2009-06-30
申请人： Rajan Hollmann , Bryan Cooper , Peter Preishuber-Pfluegl , Arnold Schneller
发明人： Rajan Hollmann , Bryan Cooper , Peter Preishuber-Pfluegl , Arnold Schneller
IPC分类号： C12P7/62 , C08G63/06
CPC分类号： C08G63/90 , C08G63/89 , C12P7/625
摘要： The invention relates to a method for isolating polyhydroxyalkanoates from production cells which comprises i) disintegrating the production cells, subsequently ii) separating off the cell fragments from the polyhydroxyalkanoate grains by means of a continuous jet separator; iii) the concentrated polyhydroxyalkanoate grains are washed with an aqueous alkali solution and then iv) with an aqueous acid.
摘要翻译：本发明涉及从生产细胞中分离聚羟基链烷酸酯的方法，其包括：i）使生产细胞分解，随后ii）通过连续喷射分离器从聚羟基链烷酸酯颗粒中分离出细胞碎片; iii）浓缩的聚羟基链烷酸酯颗粒用碱水溶液洗涤，然后iv）用酸水溶液洗涤。

5. 发明申请

US20110112274A1 METHOD FOR ISOLATING POLYHYDROXYL ALKANOATES 失效
标题翻译：分离聚羟基烷基铝酸盐的方法
公开(公告)号：US20110112274A1
公开(公告)日：2011-05-12
申请号：US13002404
申请日：2009-06-30
申请人： Rajan Hollmann , Bryan Cooper , Peter Preishuber-Pfluegl , Arnold Schneller
发明人： Rajan Hollmann , Bryan Cooper , Peter Preishuber-Pfluegl , Arnold Schneller
IPC分类号： C08G63/89
CPC分类号： C08G63/90 , C08G63/89 , C12P7/625
摘要： The invention relates to a method for isolating polyhydroxyalkanoates from production cells which comprises i) disintegrating the production cells, subsequently ii) separating off the cell fragments from the polyhydroxyalkanoate grains by means of a continuous jet separator; iii) the concentrated polyhydroxyalkanoate grains are washed with an aqueous alkali solution and then iv) with an aqueous acid.
摘要翻译：本发明涉及从生产细胞中分离聚羟基链烷酸酯的方法，其包括：i）使生产细胞分解，随后ii）通过连续喷射分离器从聚羟基链烷酸酯颗粒中分离出细胞碎片; iii）浓缩的聚羟基链烷酸酯颗粒用碱水溶液洗涤，然后iv）用酸水溶液洗涤。

6. 发明授权

US08771812B2 Paper and cardboard packaging with barrier coating 有权
标题翻译：纸和纸板包装与屏障涂层
公开(公告)号：US08771812B2
公开(公告)日：2014-07-08
申请号：US13482526
申请日：2012-05-29
申请人： Hermann Seyffer , Carmen-Elena Cimpeanu , Ines Pietsch , Axel Weiss , Peter Preishuber-Pfluegl , Heiko Diehl , Marc Bothe , Florian Buesch
发明人： Hermann Seyffer , Carmen-Elena Cimpeanu , Ines Pietsch , Axel Weiss , Peter Preishuber-Pfluegl , Heiko Diehl , Marc Bothe , Florian Buesch
IPC分类号： B32B1/02 , B32B1/08
CPC分类号： D21H27/10 , B65B25/001 , D21H11/14 , D21H19/58 , D21H19/82 , D21H21/16 , Y10T428/13 , Y10T428/1303 , Y10T428/1314 , Y10T428/1352 , Y10T428/1359
摘要： Described is paper or cardboard packaging produced from mineral oil contaminated, recycled paper, wherein the packaging includes a barrier layer obtainable by applying an aqueous polymeric dispersion comprising a copolymer obtainable by emulsion polymerization of C1-C4 alkyl(meth)acrylates, acid monomers, e.g., acrylic acid or methacrylic acid, 0-20 wt % of acrylonitrile and 0 to 10 wt % of further monomers, wherein the glass transition temperature of the copolymer is in the range from +10 to +45° C. The barrier layer may be situated on one of the surfaces of the packaging or form one of multiple layers of a multilayered packaging coating or be situated as a coating on one side of an inner bag situated within the packaging.
摘要翻译：描述的是由矿物油污染的再循环纸产生的纸或纸板包装，其中包装包括通过施加包含可通过乳液聚合的（甲基）丙烯酸C1-C4烷基酯，酸单体，例如，丙烯酸或甲基丙烯酸，0-20重量％的丙烯腈和0-10重量％的其它单体，其中共聚物的玻璃化转变温度在+ 10℃至+ 45℃的范围内。阻挡层可以是位于包装的一个表面上或形成多层包装涂料的多层之一或者作为涂层位于位于包装内的内袋的一侧上。

7. 发明授权

US06900153B2 Supported olefin polymerization catalysts 失效
标题翻译：负载型烯烃聚合催化剂
公开(公告)号：US06900153B2
公开(公告)日：2005-05-31
申请号：US10108938
申请日：2002-03-27
申请人： Peter Preishuber-Pfluegl
发明人： Peter Preishuber-Pfluegl
IPC分类号： A61N1/40 , A61N2/02 , C08F4/70 , C08F110/02 , C08F4/02 , C08F4/80
CPC分类号： C08F110/02 , C08F10/00 , C08F4/025 , C08F4/7006 , C08F4/7042
摘要： A method for forming supported late transition metal olefin polymerization catalysts is described in which an already formed transition metal complex, usually containing a reactive functional group, is placed on a support containing a complementary reactive functional group. Also described are novel polymerization catalyst components containing late transition metal complexes of neutral tridentate ligands.
摘要翻译：描述了形成负载型后过渡金属烯烃聚合催化剂的方法，其中已经形成的通常含有反应性官能团的过渡金属络合物放置在含有互补反应性官能团的载体上。还描述了含有中性三齿配体的后过渡金属络合物的新型聚合催化剂组分。

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