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    • 6. 发明授权
    • Process for the production of oxides
    • 氧化物生产工艺
    • US4990632A
    • 1991-02-05
    • US376338
    • 1989-07-06
    • Ramakrishnan RamachandranDonald L. MacleanDonald P. Satchell, Jr.
    • Ramakrishnan RamachandranDonald L. MacleanDonald P. Satchell, Jr.
    • C07C253/26
    • C07D301/04C07D301/06C07D301/08C07D301/10
    • An improved process is provided for the production of oxides from hydrocarbons by reaction with oxygen, air or a gas enriched in oxygen relative to air, preferably the latter, in the presence of an oxidation catalyst. An alkane, e.g. propane, is converted to an alkene in a dehydrogenator. The product stream is introduced into an oxidation reactor. The product formed therein is recovered in a quench tower. The gas phase from the quench tower is treated in a PSA unit to form a gaseous stream containing the unreacted alkane, alkene, a minor amount of oxygen, i.e. less than about 2 percent by volume, and nitrogen if present in the feed to the oxidation reactor. The gaseous stream, which may or may not contain hydrogen depending on the adsorbent on the PSA unit, is introduced into a selective oxidation unit to remove the remaining oxygen and then recycled to the dehydrogenator. Hydrogen may be introduced into or removed from the PSA effluent, depending on the function of the adsorbent therein, to obtain an optimum concentration for introduction into the dehydrogenator. A preferred PSA system for use in the subject process comprises two parallel PSA units containing differnt adsorbents such that the gaseous stream formed in one PSA unit contians all of the hydrogen from the gas phase of the quench tower. The feed to the PSA units is divided disaproportionately so that the combined PSA effluent recycle streams contain the optimum concentration of hydrogen for the dehydrogenator.
    • 提供了一种改进的方法,用于在氧化催化剂存在下,通过与氧气,空气或相对于空气富含氧的气体(优选后者)与烃反应生成氧化物。 烷烃,例如 丙烷转化为脱氢剂中的烯烃。 将产物流引入氧化反应器中。 其中形成的产品在骤冷塔中回收。 来自淬火塔的气相在PSA单元中进行处理以形成含有未反应的烷烃,烯烃,少量氧气(即小于约2体积%)的气态物流,以及如果存在于氧化物进料中的氮气 反应堆。 将取决于PSA单元上的吸附剂的可能含有或不含氢的气流引入选择性氧化装置以除去剩余的氧气,然后再循环至脱氢器。 取决于其中的吸附剂的功能,可以将氢气引入或从PSA流出物中除去,以获得用于引入脱氢器的最佳浓度。 在本发明方法中使用的优选PSA系统包括两个平行的PSA单元,其含有不同的吸附剂,使得在一个PSA单元中形成的气流能够承受来自骤冷塔的气相的全部氢气。 PSA单元的进料不成比例地分配,使得组合的PSA流出物再循环流含有用于脱氢剂的最佳氢浓度。
    • 7. 发明授权
    • Ammonia leaching
    • 氨浸出
    • US4165264A
    • 1979-08-21
    • US915176
    • 1978-06-14
    • Donald P. Satchell, Jr.
    • Donald P. Satchell, Jr.
    • C22B15/00C25C1/12
    • C22B15/0089C22B15/0078C22B15/0086Y02P10/236
    • An improved process for obtaining copper from a copper sulfide, in which: the copper sulfide is treated with oxygen and an aqueous leaching solution of ammonium carbonate, to form a leach liquor which contains ammonia complexes of copper sulfate and copper carbonate; the leach liquor is heated to form gaseous ammonia and carbon dioxide; the leach liquor is treated with a strongly alkaline material to precipitate sulfates and form additional gaseous ammonia; and the copper is then recovered by electrowinning. In this process, the ammonium carbonate leaching solution is formed from carbon dioxide that is generated by: adding a metal carbonate to the leach liquor during the heating thereof; and recovering the gaseous carbon dioxide, as well as the gaseous ammonia, formed during the heating of the leach liquor.
    • 一种从硫化铜获得铜的改进方法,其中:用氧和硫酸铵的水溶液处理硫化铜,形成含有硫酸铜和碳酸铜的氨络合物的浸出液; 将浸出液加热形成气态氨和二氧化碳; 浸出液用强碱性物质处理以沉淀硫酸盐并形成另外的气态氨; 然后通过电解沉积来回收铜。 在该方法中,碳酸铵浸出溶液由二氧化碳形成,二氧化碳是通过以下步骤产生的:在加热过程中向浸出液中加入金属碳酸盐; 并回收在浸出液的加热期间形成的气态二氧化碳以及气态氨。
    • 9. 发明授权
    • Process for the production of nitriles
    • US4849537A
    • 1989-07-18
    • US215859
    • 1988-07-06
    • Ramakrishnan RamachandranDonald L. MacLeanDonald P. Satchell, Jr.
    • Ramakrishnan RamachandranDonald L. MacLeanDonald P. Satchell, Jr.
    • C07D301/22C07B43/08C07C253/24C07C253/26C07C253/34C07C255/08C07D301/08C07D303/04
    • C07C253/34C07C253/26C07D301/08Y02P20/582
    • An improved process is provided for the production of nitriles from hydrocarbons by reaction with oxygen, air or gas-enriched in relative to an air, and ammonia, in the presence of an ammoxidation catalyst. An alkane, e.g. propane, is converted to an alkene in a multistage dehydrogenator. The product stream is withdrawn from a reactor in the dehydrogenator other than the first and the last reactor and introduced into an ammoxidation reactor. The product is recovered in a conventional quench tower. The gaseous effluent from the quench tower is treated in a pressure swing adsorption unit to form a gas stream containing the unreacted alkane and alkene as well as a minor amount of oxygen. The gas stream, which may or may not contain hydrogen depending on the absorbent in the pressure swing adsorption unit, is introduced into the reactor in the dehydrogenator following that from which the product stream was withdrawn. The effluent from the last reactor in the dehydrogenator is introduced into: the first reactor; an intermediate reactor wherein the alkene concentration closely approximates the effluent or the ammoxidation reactor. The subject process is particularly efficient utilizing oxygen-enriched air in the reactor feed. A particularly preferred pressure swing adsorption system for use in the subject process comprises two parallel pressure swing adsorption units containing different adsorbents such that the gas stream formed in one contains all of the hydrogen in the gas phase from the quench tower. The feed to the pressure swing adsorption units is divided disproportionately so that the conbined pressure swing adsorption effluent recycle streams contain the optimum concentration of hydrogen for the dehydrogenator.