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1. 发明授权

US07628888B2 Cellulosic composition 失效
标题翻译：纤维素组成
公开(公告)号：US07628888B2
公开(公告)日：2009-12-08
申请号：US11450999
申请日：2006-06-12
申请人： Eric J. Beckman , W. Eamon Carroll , Toby Chapman , Kristen E. Minnich , Dennis Sagl , Richard J. Goddard
发明人： Eric J. Beckman , W. Eamon Carroll , Toby Chapman , Kristen E. Minnich , Dennis Sagl , Richard J. Goddard
IPC分类号： C09K8/68 , C09K8/90 , C08L101/00 , D21H17/24 , D21H17/56
CPC分类号： D21H21/18 , C08L39/00 , C08L39/02 , C09D133/14 , C09D139/02 , D21H17/06 , D21H17/36 , D21H17/56
摘要： A composition includes at least one hydrophilic polymer containing primary (—NH2) and/or secondary (—NHR) amine groups and at least one saccharide containing a reducible function. A method of increasing the strength of paper includes the step of contacting the paper with a composition comprising (i) at least one hydrophilic polymer containing at least two groups which are independently the same or different a primary amine group or a secondary amine group and at least one saccharide containing a reducible function. A hydrogel composition is formed from a mixture of at least one hydrophilic polymer containing at least two groups which are independently the same or different a primary amine group or a secondary amine group and at least one saccharide containing a reducible function.
摘要翻译：组合物包含至少一种含有伯（-NH 2）和/或仲（-NHR）胺基团的至少一种亲水性聚合物和至少一种含有可还原功能的糖。提高纸张强度的方法包括使纸与包含（i）至少一种亲水性聚合物的步骤，所述组合物含有至少两个独立地相同或不同的伯胺基或仲胺基的基团，并且在至少一种含有可还原功能的糖。水凝胶组合物由至少一种含有至少两个独立地相同或不同的伯胺基或仲胺基的亲水性聚合物和至少一种含有还原性功能的糖的亲水性聚合物的混合物形成。

2. 发明授权

US5753753A Hydrolysis of polyvinyl aklaenoates 失效
标题翻译：聚烯烃烯烃的水解
公开(公告)号：US5753753A
公开(公告)日：1998-05-19
申请号：US803172
申请日：1997-02-19
申请人： Kien Van Phung , Dennis Sagl
发明人： Kien Van Phung , Dennis Sagl
IPC分类号： C08F8/12 , C08K3/00 , C08F16/06
CPC分类号： C08K3/0008 , C08F8/12 , C08F2800/10
摘要： This invention relates to an improved process for producing a vinyl alcohol containing polymer having a narrow particle size without substantial reactor fouling. The process for producing the vinyl alcohol containing polymer involves hydrolyzing a vinyl ester containing polymer, e.g., a polymer containing polymerized vinyl alkanoate units in the presence of an alcoholic medium and a hydrolysis catalyst in the presence of an alcoholic medium having finely divided, inert material such as an alkali metal carbonate dispersed therein. The finely divided inert material acts as nucleating sites for the polyvinyl alcohol as it precipitates from the solution during hydrolysis.
摘要翻译：本发明涉及一种改进的具有窄的粒度的含乙烯醇的聚合物的方法，而没有实质的反应器结垢。制备含乙烯醇的聚合物的方法包括在含有细分惰性材料的醇介质存在下，在含醇介质和水解催化剂的存在下水解含乙烯基酯的聚合物，例如含有聚合的乙烯基链烷酸酯单元的聚合物例如分散在其中的碱金属碳酸盐。精细分散的惰性材料作为聚乙烯醇的成核位置，因为它在水解过程中从溶液中沉淀出来。

3. 发明授权

US5470903A N-vinylamide polymers as stabilizing protective colloids in aqueous emulsion polymerization 失效
标题翻译： N-乙烯基酰胺聚合物作为水乳液聚合中的稳定保护胶体
公开(公告)号：US5470903A
公开(公告)日：1995-11-28
申请号：US277827
申请日：1994-07-20
申请人： William E. Lenney , Dennis Sagl
发明人： William E. Lenney , Dennis Sagl
IPC分类号： C08F2/30 , C08L39/02
CPC分类号： C08F2/30
摘要： A method for preparing aqueous polymer emulsions by effecting polymerization of vinyl monomers in the presence of a stabilizing amount of a water soluble poly(N-vinylformamide) containing polymer as a protective colloid and aqueous polymer emulsions containing poly(N-vinylformamide) stablizer.
摘要翻译：在稳定量的含水溶性聚（N-乙烯基甲酰胺）的聚合物作为保护胶体和含有聚（N-乙烯基甲酰胺）稳定剂的含水聚合物乳液的存在下，通过进行乙烯基单体的聚合来制备水性聚合物乳液的方法。

4. 发明申请

US20130149929A1 LOW FORMALDEHYDE AND HIGH WET STRENTGH VINYL ACETATE ETHYLENE DISPERSIONS 审中-公开
标题翻译：低甲醛和高湿乙酸乙烯酯乙烯分散体
公开(公告)号：US20130149929A1
公开(公告)日：2013-06-13
申请号：US13313467
申请日：2011-12-07
申请人： John Richard Boylan , Dennis Sagl
发明人： John Richard Boylan , Dennis Sagl
IPC分类号： B32B5/02 , B05D3/00 , C08L33/26 , B05D7/24 , C08L29/04 , C08L31/04
CPC分类号： D06M15/29 , C09D123/0853 , C09D133/26 , D04H1/64 , D06M15/263 , D06M15/333 , Y10T442/20 , C09D131/04 , C08K3/28 , C08L29/04 , C08K3/16
摘要： An aqueous composition includes a blend of: a) an aqueous dispersion of an N-methylol-containing vinyl acetate ethylene or vinyl acetate polymer, stabilized by polyvinyl alcohol and optionally also by a surfactant, wherein N-methylol-containing monomer units constitute from 0.025 to 0.4 wt % of the polymer; and b) an acid. The invention provides a method of increasing the wet strength of a fibrous nonwoven substrate, including applying to the substrate the above aqueous composition, followed by a drying step. A fibrous nonwoven article is thereby provided.
摘要翻译：水性组合物包括以下混合物：a）含聚乙烯醇稳定的含有N-羟甲基的乙酸乙烯酯乙烯或乙酸乙烯酯聚合物的水性分散体，任选地也可由表面活性剂稳定，其中含N-羟甲基的单体单元构成0.025 至0.4重量％的聚合物; 和b）酸。本发明提供了增加纤维非织造基材的湿强度的方法，包括将上述水性组合物涂布在基材上，随后进行干燥步骤。从而提供纤维非织造制品。

5. 发明授权

US5500251A Process for coating low energy surfaces 失效
标题翻译：低能表面涂层工艺
公开(公告)号：US5500251A
公开(公告)日：1996-03-19
申请号：US261568
申请日：1994-06-17
申请人： William F. Burgoyne, Jr. , Wiley E. Daniels , Dennis Sagl , Heueh-Chi Lee , Menas S. Vratsanos
发明人： William F. Burgoyne, Jr. , Wiley E. Daniels , Dennis Sagl , Heueh-Chi Lee , Menas S. Vratsanos
IPC分类号： B05D7/02 , C08J7/04 , C09D133/06 , B05D3/00
CPC分类号： C08J7/04 , B05D7/02 , C09D133/062 , C08J2323/02 , C08J2431/04 , Y10T428/31692
摘要： N-(4-alkylphenyl)acrylamides, N-(4-alkylphenyl)methacrylamides and N-(4-alkylphenyl)maleimides, when co-polymerized into conventional polymer systems promote adhesion of such systems to low energy polyolefin surfaces. These compounds are effective in increasing the adhesive coating properties of both solution polymer and emulsion polymer systems.
摘要翻译： N-（4-烷基苯基）丙烯酰胺，N-（4-烷基苯基）甲基丙烯酰胺和N-（4-烷基苯基）马来酰亚胺当共聚于常规的聚合物体系中时促进这种体系对低能聚烯烃表面的粘附。这些化合物在提高溶液聚合物和乳液聚合物体系的粘合剂涂层性能方面是有效的。

6. 发明授权

US5171777A Miscible blends of poly(vinyl acetate) and polymers of acrylic acid 失效
标题翻译：聚（醋酸乙烯酯）和丙烯酸聚合物的不均匀混合物
公开(公告)号：US5171777A
公开(公告)日：1992-12-15
申请号：US633830
申请日：1990-12-26
申请人： Jeffrey A. Kuphal , Lloyd M. Robeson , Dennis Sagl
发明人： Jeffrey A. Kuphal , Lloyd M. Robeson , Dennis Sagl
IPC分类号： C08L25/04 , C08L25/08 , C08L31/04 , C08L33/00 , C08L33/02 , C08L33/04 , C08L33/08 , C09D131/04 , C09J131/04
CPC分类号： C08L31/04 , C08L25/08 , C08L33/02 , C08L33/08 , Y10S525/931 , Y10S525/932
摘要： Blends of polymers of vinyl acetate and polymers derived from acrylic acid have been discovered which exhibit thermodynamic miscibility. These polymer blends exhibit excellent mechanical compatibility, provide enhanced toughness and strength superior to the sum of the weight averaged properties of the constituent polymers and are useful in molding structures such as films and in compounded formulations such as coatings, emulsions and adhesives.
摘要翻译：已经发现乙酸乙烯酯的聚合物和衍生自丙烯酸的聚合物的共混物表现出热力学混溶性。这些聚合物共混物表现出优异的机械相容性，提供优于构成聚合物重量平均性能之和的韧性和强度，并且可用于模塑结构如膜和复合配方如涂料，乳液和粘合剂。

7. 发明授权

US10968569B2 Polyvinyl alcohol stabilized acetate ethylene copolymer dispersions as adhesives for creped webs 有权
公开(公告)号：US10968569B2
公开(公告)日：2021-04-06
申请号：US16097018
申请日：2017-04-21
申请人： WACKER CHEMIE AG , John Richard Boylan , Dennis Sagl
发明人： John Richard Boylan , Dennis Sagl
IPC分类号： D21H17/36 , D21H21/14 , D21H19/12 , D21H27/02 , C09J131/04 , C08F218/08 , B31F1/12 , D06C23/04 , D04H1/74 , D04H1/587 , C08L29/04 , B31F1/14
摘要： A crepe process includes applying an adhesive composition to a nonwoven web, drying, and creping the nonwoven web on a creping drum. The improvement includes using an adhesive composition that includes an aqueous copolymer dispersion obtained by emulsion polymerization of a monomer mixture including 65 to 94.5% by weight of vinyl acetate, 5 to 30% by weight of ethylene, (meth)acrylamide, and 0.1 to 4% by weight of an N-methylol functional monomer. The N-methylol functional monomer constitutes from 25 to 85% by weight of the combined amounts of acrylamide and N-methylol functional monomer, which combined amounts constitute from 0.5 to 5% by weight of the monomer mixture. The emulsion polymerization is performed in the presence of 1 to 10% by weight of polyvinyl alcohol, based on the total weight of all monomers used for the polymerization. The adhesive composition does not include alkylphenol ethoxylates, phosphate ester surfactants, or sodium laureth sulfate.

8. 发明授权

US07619017B2 Polymer emulsions resistant to biodeterioration 有权
标题翻译：抗生物降解的聚合物乳液
公开(公告)号：US07619017B2
公开(公告)日：2009-11-17
申请号：US10441806
申请日：2003-05-19
申请人： John Joseph Rabasco , Dennis Sagl
发明人： John Joseph Rabasco , Dennis Sagl
IPC分类号： C08K5/34 , C08K5/17 , C09D5/16
CPC分类号： C08K5/34 , A01N37/44 , C08J3/03 , C08K5/0058 , C08K5/175 , A01N47/44 , A01N43/40 , A01N33/12 , A01N25/30 , A01N2300/00
摘要： This invention is directed to a method of preserving polymer emulsions against biodeteriogenic microbe attack and spoilage by combining with the polymer emulsions selected cationic compounds and an ethylenediamine acid compound. The polymer emulsions contain surfactants and/or anionic constituents. It is also directed to polymer emulsion compositions, that are resistant to spoilage by biodeteriogenic microbes, containing surfactants and/or anionic constituents, an ethylenediamine acid compound, and cationic compounds.
摘要翻译：本发明涉及通过与选择的阳离子化合物和乙二胺酸化合物的聚合物乳液结合来保存聚合物乳液以防止生物发生微生物侵袭和变质的方法。聚合物乳液含有表面活性剂和/或阴离子组分。它还涉及聚合物乳液组合物，其通过生物发生微生物，含有表面活性剂和/或阴离子组分，乙二胺酸化合物和阳离子化合物具有抗腐蚀性。

9. 发明授权

US07485590B2 Self-crosslinking vinyl acetate-ethylene polymeric binders for nonwoven webs 有权
标题翻译：用于非织造纤维网的自交联乙酸乙烯酯 - 乙烯聚合物粘合剂
公开(公告)号：US07485590B2
公开(公告)日：2009-02-03
申请号：US11540299
申请日：2006-09-29
申请人： John Joseph Rabasco , John Richard Boylan , Dennis Sagl , Ronald Bernal Jones
发明人： John Joseph Rabasco , John Richard Boylan , Dennis Sagl , Ronald Bernal Jones
IPC分类号： B32B9/04 , B32B27/12
CPC分类号： D04H1/64 , D04H1/587 , Y10T442/20 , Y10T442/2738 , Y10T442/2787 , Y10T442/60
摘要： This invention is directed to an improvement in nonwoven products comprised of a nonwoven web of fibers bonded together with polymeric binder comprised of emulsion polymerized units of vinyl acetate, ethylene, and a crosslinking monomer. The polymer is stabilized with a surfactant having a critical micelle concentration of about 0.5 to 3% by weight. The surfactant is employed in the polymerization in an amount less than 1% by weight, based upon the total weight of polymer.
摘要翻译：本发明涉及由非织造纤维网组成的非织造产品的改进，所述非织造纤维网与由乙酸乙烯酯，乙烯和交联单体的乳液聚合单元组成的聚合物粘合剂粘合在一起。聚合物用临界胶束浓度为约0.5至3重量％的表面活性剂稳定。基于聚合物的总重量，表面活性剂的用量小于1重量％。

10. 发明申请

US20080081530A1 Self-crosslinking vinyl acetate-ethylene polymeric binders for nonwoven webs 有权
标题翻译：用于非织造纤维网的自交联乙酸乙烯酯 - 乙烯聚合物粘合剂
公开(公告)号：US20080081530A1
公开(公告)日：2008-04-03
申请号：US11540299
申请日：2006-09-29
申请人： John Joseph Rabasco , John Richard Boylan , Dennis Sagl , Ronald Bernal Jones
发明人： John Joseph Rabasco , John Richard Boylan , Dennis Sagl , Ronald Bernal Jones
IPC分类号： D04H13/00 , B32B5/02 , B32B3/00
CPC分类号： D04H1/64 , D04H1/587 , Y10T442/20 , Y10T442/2738 , Y10T442/2787 , Y10T442/60
摘要： This invention is directed to an improvement in nonwoven products comprised of a nonwoven web of fibers bonded together with polymeric binder comprised of emulsion polymerized units of vinyl acetate, ethylene, and a crosslinking monomer. The polymer is stabilized with a surfactant having a critical micelle concentration of about 0.5 to 3% by weight. The surfactant is employed in the polymerization in an amount less than 1% by weight, based upon the total weight of polymer.
摘要翻译：本发明涉及由非织造纤维网组成的非织造产品的改进，所述非织造纤维网与由乙酸乙烯酯，乙烯和交联单体的乳液聚合单元组成的聚合物粘合剂粘合在一起。聚合物用临界胶束浓度为约0.5至3重量％的表面活性剂稳定。基于聚合物的总重量，表面活性剂的用量小于1重量％。

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