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    • 8. 发明授权
    • Copper interconnect structure having a graphene cap
    • 铜互连结构具有石墨烯盖
    • US08476765B2
    • 2013-07-02
    • US12961251
    • 2010-12-06
    • John Hongguang ZhangCindy GoldbergWalter KleemeierRonald Kevin Sampson
    • John Hongguang ZhangCindy GoldbergWalter KleemeierRonald Kevin Sampson
    • H01L29/40H01L21/4763
    • H01L23/53238H01L21/76849H01L2924/0002H01L2924/00
    • A copper interconnect structure has an intrinsic graphene cap for improving back end of line (BEOL) reliability of the interconnect by reducing time-dependent dielectric breakdown (TDDB) failure and providing resistance to electromigration. Carbon atoms are selectively deposited onto a copper layer of the interconnect structure by a deposition process to form a graphene cap. The graphene cap increases the activation energy of the copper, thus allowing for higher current density and improved resistance to electromigration of the copper. By depositing the graphene cap on the copper, the dielectric regions remain free of conductors and, thus, current leakage within the interlayer dielectric regions is reduced, thereby reducing TDDB failure and increasing the lifespan of the interconnect structure. The reduction of TDDB failure and improved resistance to electromigration improves BEOL reliability of the copper interconnect structure.
    • 铜互连结构具有本征石墨烯盖,用于通过减少时间相关介质击穿(TDDB)故障并提供电迁移阻力来改善互连的后端(BEOL)可靠性。 通过沉积工艺将碳原子选择性地沉积在互连结构的铜层上以形成石墨烯盖。 石墨烯帽增加了铜的活化能,从而允许更高的电流密度和改善的铜的电迁移性。 通过在铜上沉积石墨烯盖,电介质区域保持没有导体,因此层间电介质区域内的电流泄漏减小,从而减少TDDB故障并增加互连结构的寿命。 TDDB故障的减少和提高的电迁移性提高了铜互连结构的BEOL可靠性。