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    • 3. 发明授权
    • Thermosetting compositions containing isocyanurate rings
    • 含有异氰脲酸酯环的热固性组合物
    • US08501877B2
    • 2013-08-06
    • US12732568
    • 2010-03-26
    • Ming Yang ZhaoChih-Pin Hsu
    • Ming Yang ZhaoChih-Pin Hsu
    • C08K5/07C08L63/02C08L67/00C08G63/12C08G63/47
    • C08G59/12B32B27/38C08G59/42C08K5/07C08L63/00C08L63/10C09J163/00C09J163/10C08L2666/20
    • The invention relates to thermosetting compositions containing isocyanurate ring(s) prepared through chain extension of an epoxy resin (a) with carboxyl-functional oligomers (b), which are the reaction product of polyols (i) containing one or more isocyanurate ring(s) and polycarboxylic acids or their anhydrides (ii). The polyols (i) containing one or more isocyanurate ring(s) can be prepared from the reactions of tris (2-hydroxyalkyl) isocyanurates with a modifier from a caprolactone or alkylene oxide, or glycidyl ester or glycidyl ether and mixtures thereof. The epoxy-functional thermosetting compositions containing an isocyanurate ring(s) can be further reacted with unsaturated acids, preferably (meth)acrylic acid, to obtain a curable polyacrylate. Both epoxy-functional isocyanurate and acrylate-functional isocyanurate thermosetting compositions can be further modified with a polyisocyanate to produce a composition that is useful as a reactive adhesive, binder or in other applications.
    • 本发明涉及含有通过环氧树脂(a)与羧基官能的低聚物(b)的链延伸制备的异氰脲酸酯环的热固性组合物,其是含有一个或多个异氰脲酸酯环的多元醇(i)的反应产物 )和多元羧酸或其酸酐(ii)。 含有一个或多个异氰脲酸酯环的多元醇(i)可以由三(2-羟烷基)异氰脲酸酯与来自己内酯或烯化氧的改性剂或缩水甘油酯或缩水甘油醚及其混合物的反应制备。 含有异氰脲酸酯环的环氧官能性热固性组合物可以进一步与不饱和酸(优选(甲基)丙烯酸)反应得到可固化的聚丙烯酸酯。 环氧官能的异氰脲酸酯和丙烯酸酯官能的异氰脲酸酯热固性组合物可以用多异氰酸酯进一步改性,以产生可用作反应性粘合剂,粘合剂或其它应用的组合物。
    • 5. 发明授权
    • Aromatic polyol end-capped unsaturated polyetherester resins and resin compositions containing the same having improved chemical and/or water resistance
    • 芳族多元醇封端不饱和聚醚酯树脂和含有其的具有改善的化学和/或耐水性的树脂组合物
    • US06830804B2
    • 2004-12-14
    • US09819237
    • 2001-03-28
    • Chih-Pin HsuMing Yang ZhaoLinda Bergstrom
    • Chih-Pin HsuMing Yang ZhaoLinda Bergstrom
    • B32B2502
    • C08G63/676C08G63/918C08L67/06Y10T428/249933Y10T428/24994Y10T428/31786
    • Unsaturated polyetherester resins, and processes for making them, are described which are useful for making curable thermoset resin compositions, intermediates for curable thermoset resin compositions, fiber-reinforced polymer composites, intermediates for making skin laminates for gel coated fiber-reinforced composites and gel coated polymer laminates. The unsaturated polyetherester resins are obtainable by reacting at least one acid-terminated unsaturated polyetherester resin with at least one aromatic polyol having at least one non-primary hydroxy group to produce an unsaturated polyetherester resin at least partially end-capped with an aromatic polyol. The described processes, compositions, methods and uses improve the chemical and/or water resistance of resin compositions, particularly composite materials having a gel coat. That improvement has special significance in outdoor and marine applications, bathtubs and shower stalls, and environments exposed to chemicals such as industrial and commercial applications.
    • 描述了不饱和聚醚酯树脂及其制备方法,其可用于制备可固化热固性树脂组合物,可固化热固性树脂组合物的中间体,纤维增强聚合物复合材料,用于制备凝胶涂层纤维增强复合材料的表层叠体的中间体和凝胶涂层 聚合物层压板。 不饱和聚醚酯树脂可以通过使至少一种酸封端的不饱和聚醚酯树脂与至少一种具有至少一个非伯羟基的芳族多元醇反应来制备至少部分用芳族多元醇封端的不饱和聚醚酯树脂。 所描述的方法,组合物,方法和用途改善了树脂组合物,特别是具有凝胶涂层的复合材料的化学和/或耐水性。 这种改进在户外和船舶应用,浴缸和淋浴间以及暴露于工业和商业应用等化学品的环境中具有特殊意义。
    • 6. 发明授权
    • Slurry homogenizer and supply system
    • 泥浆均质机和供料系统
    • US06719617B2
    • 2004-04-13
    • US10348696
    • 2003-01-22
    • Tun-Yuan LoChih-Pin HsuChih-Kun Chen
    • Tun-Yuan LoChih-Pin HsuChih-Kun Chen
    • B24B100
    • B24B37/04B01F7/00758B01F7/163B24B57/02
    • A slurry homogenizer. A frame having an outlet is disposed on a driving means having a rotating shaft. A waterproof plate having a first opening is disposed in the frame and on the driving means. Part of the shaft penetrates the first opening. A filter is disposed in the frame and on the plate. A first grinding pad has a second opening and is fitted on the shaft through the second opening. The first grinding pad is disposed in the frame and above the plate. A knob is fitted on the top of the shaft. The knob fixes the first grinding pad on the shaft. A cover having a pipe is disposed on the frame. A second grinding pad having a third opening is fitted on the pipe and disposed in the frame. The second grinding pad and the first grinding pad are separated by a fixed distance.
    • 浆料均化器。 具有出口的框架设置在具有旋转轴的驱动装置上。 具有第一开口的防水板设置在框架中和驱动装置上。 轴的一部分穿过第一个开口。 过滤器设置在框架和板上。 第一研磨垫具有第二开口并通过第二开口装配在轴上。 第一研磨垫设置在框架中并在板上方。 在轴的顶部安装一个旋钮。 旋钮将第一个研磨垫固定在轴上。 具有管子的盖子设置在框架上。 具有第三开口的第二研磨垫安装在管上并且设置在框架中。 第二研磨垫和第一研磨垫分开一定距离。
    • 7. 发明申请
    • Thermosetting Compositions Containing Isocyanurate Rings
    • 含有异氰酸酯环的热固性组合物
    • US20100256285A1
    • 2010-10-07
    • US12732568
    • 2010-03-26
    • Ming Yang ZhaoChih-Pin Hsu
    • Ming Yang ZhaoChih-Pin Hsu
    • C09J133/08C08G73/00C08L79/00
    • C08G59/12B32B27/38C08G59/42C08K5/07C08L63/00C08L63/10C09J163/00C09J163/10C08L2666/20
    • The invention relates to thermosetting compositions containing isocyanurate ring(s) prepared through chain extension of an epoxy resin (a) with carboxyl-functional oligomers (b), which are the reaction product of polyols (i) containing one or more isocyanurate ring(s) and polycarboxylic acids or their anhydrides (ii). The polyols (i) containing one or more isocyanurate ring(s) can be prepared from the reactions of tris (2-hydroxyalkyl) isocyanurates with a modifier from a caprolactone or alkylene oxide, or glycidyl ester or glycidyl ether and mixtures thereof. The epoxy-functional thermosetting compositions containing an isocyanurate ring(s) can be further reacted with unsaturated acids, preferably (meth)acrylic acid, to obtain a curable polyacrylate. Both epoxy-functional isocyanurate and acrylate-functional isocyanurate thermosetting compositions can be further modified with a polyisocyanate to produce a composition that is useful as a reactive adhesive, binder or in other applications.
    • 本发明涉及含有通过环氧树脂(a)与羧基官能的低聚物(b)的链延伸制备的异氰脲酸酯环的热固性组合物,其是含有一个或多个异氰脲酸酯环的多元醇(i)的反应产物 )和多元羧酸或其酸酐(ii)。 含有一个或多个异氰脲酸酯环的多元醇(i)可以由三(2-羟烷基)异氰脲酸酯与来自己内酯或烯化氧的改性剂或缩水甘油酯或缩水甘油醚及其混合物的反应制备。 含有异氰脲酸酯环的环氧官能性热固性组合物可以进一步与不饱和酸(优选(甲基)丙烯酸)反应得到可固化的聚丙烯酸酯。 环氧官能的异氰脲酸酯和丙烯酸酯官能的异氰脲酸酯热固性组合物可以用多异氰酸酯进一步改性,以产生可用作反应性粘合剂,粘合剂或其它应用的组合物。
    • 9. 发明授权
    • Styrene-free unsaturated polyester
    • 不含苯乙烯的不饱和聚酯
    • US08906999B2
    • 2014-12-09
    • US13396978
    • 2012-02-15
    • Chih-Pin HsuMing Yang ZhaoSteven L. Voeks
    • Chih-Pin HsuMing Yang ZhaoSteven L. Voeks
    • C08K3/06C08G63/553C08G61/08C08L65/00C08L67/06
    • C08G63/553C08G61/08C08G2261/3324C08G2261/418C08G2261/76C08L65/00C08L67/06
    • A thermosetting unsaturated polyester resin (UPR) composition comprising an unsaturated polyester polymer having at least two strained cycloolefinic double bonds and optional unstrained cycloolefinic double bonds, which can be cross-linked through a ring-opening metathesis polymerization (ROMP) or combination of ROMP and cationic or free radical polymerization is provided. No styrene is used in the resin composition. The thermosetting unsaturated polyester resin composition also comprises a catalyst system for the ring-opening metathesis polymerization, and in embodiments, can further comprise one or more optional unsubstituted or substituted cycloolefin monomer containing unsaturation, an optional co-catalyst selected from a cationic initiator or free radical initiator, and optional additives. The cured resin properties can be controlled through adjusting the structure and properties of the unsaturated polyester resin.
    • 一种热固性不饱和聚酯树脂(UPR)组合物,其包含具有至少两个应变环烯烃双键的不饱和聚酯聚合物和任选的非限制性环烯烃双键,其可以通过开环易位聚合(ROMP)或ROMP和 提供阳离子或自由基聚合。 在树脂组合物中不使用苯乙烯。 热固性不饱和聚酯树脂组合物还包括用于开环易位聚合的催化剂体系,并且在实施方案中可进一步包含一种或多种任选的不饱和的未取代或取代的环烯烃单体,任选的助催化剂,其选自阳离子引发剂或游离 自由基引发剂和任选的添加剂。 可以通过调节不饱和聚酯树脂的结构和性能来控制固化的树脂性能。