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1. 发明申请

US20070163176A1 PROCESS AND APPARATUS FOR THE ENDOTHERMIC GASIFICATION OF CARBON 有权
标题翻译：碳的内热气化过程和装置
公开(公告)号：US20070163176A1
公开(公告)日：2007-07-19
申请号：US11460379
申请日：2006-07-27
申请人： Dietmar Ruger , Olaf Schulze , Jonas Kappeller , Burkhard Moller , Bodo Wolf
发明人： Dietmar Ruger , Olaf Schulze , Jonas Kappeller , Burkhard Moller , Bodo Wolf
IPC分类号： C10J3/00
CPC分类号： C10J3/487 , C10J3/526 , C10J3/64 , C10J3/84 , C10J2200/158 , C10J2300/1609
摘要： A process for the endothermic gasification of solid carbon in an entrained bed facility comprises partial oxidation of fuel(s) and endothermic gasification of solid carbon, preferably preceded by low temperature carbonization such that the carbonization gas is passed to the partial oxidation and the carbonization coke is passed to the endothermic gasification. The hot gas streaming downwardly from the combustion chamber is deflected to produce separation of the liquid slag and is then passed to the endothermic gasification that operates with a rising gas stream and with addition of solid carbon having a grain diameter of up to 20 mm. The speed of the gas at the carbon inlet is higher than, and the speed of the gas at the end of the endothermic gasification is lower than, the suspension rate of the reactive carbon particles, to produce an increase of the relative speed difference between the gas and the carbon particles. Apparatus is also disclosed for carrying out the process.
摘要翻译：在夹带床设备中固体碳的吸热气化的方法包括燃料的部分氧化和固体碳的吸热气化，优选在低温碳化之前，使得碳化气体进入部分氧化和碳化焦炭被传递到吸热气化。从燃烧室向下流动的热气体被偏转以产生液体炉渣的分离，然后被传递到用升高的气流运行的吸热气化，并加入具有高达20mm的粒径的固体碳。碳入口处的气体速度高于吸热气化结束时的气体速度低于反应性碳颗粒的悬浮速度，以产生相对速度差气体和碳颗粒。还公开了用于执行该过程的装置。

2. 发明授权

US5849050A Process for generating burnable gas 失效
标题翻译：产生可燃气体的方法
公开(公告)号：US5849050A
公开(公告)日：1998-12-15
申请号：US693167
申请日：1996-08-14
申请人： Bodo Wolf
发明人： Bodo Wolf
IPC分类号： C10J3/66 , C10J3/00 , C10J3/16 , F02B43/00
CPC分类号： C10J3/66 , C10J2300/0906 , C10J2300/0959 , C10J2300/1628
摘要： A process is disclosed for generating burnable gas by gasifying water- and ballast-containing organic materials, be it coal or garbage. The drying, low temperature carbonization and gasification steps are carried out separately. The heat taken form cooled gasified gas is supplied to the endothermic drying low temperature in low temperature carbonation stages. The low temperature carbonization gas is burned in a melting chamber furnace with air and/or oxygen or oxygen-rich flue gas and the liquid slag is evacuated, whereas the low temperature carbonization coke is blown into the hot combustion gases that leave the melting reactions which take place and give carbon monoxide and hydrogen reduce the carbon is removed from the gasified gas, supplied to the melting chamber furnace and completely burned. The advantage of the invention is that the ashes may be transformed into an elution-resistant granulated building material, in that a tar-free burnable gas is generated and in that oxygen consumption is strongly reduced in comparison with the fly stream gasification process.
摘要翻译： PCT No.PCT / EP95 / 00443 Sec。 371日期：1996年8月14日 102（e）日期1996年8月14日PCT提交1995年2月8日PCT公布。 WO95 / 21903 PCT出版物日期1995年8月17日公开了通过气化含水和含镇流有机材料（无论是煤或垃圾）产生可燃气体的方法。干燥，低温碳化和气化步骤分别进行。将冷却气化气体的热量供给到低温碳酸化阶段的吸热干燥低温。低温碳化气体在具有空气和/或氧气或富氧烟道气的熔炉中燃烧，并且液体炉渣被排空，而将低温碳化焦炭吹入热燃烧气体中，从而使熔融反应物发生并产生一氧化碳和氢气，将碳从气化气中除去，供应到熔炉炉中并完全燃烧。本发明的优点在于，灰分可以转化成耐洗涤的造粒建筑材料，因为与无烟气化过程相比，产生无焦油的可燃气体，并且大大降低了氧消耗。

3. 发明授权

US06458181B1 Method for producing pig iron 失效
标题翻译：生铁生产方法
公开(公告)号：US06458181B1
公开(公告)日：2002-10-01
申请号：US09581700
申请日：2000-06-16
申请人： Bodo Wolf
发明人： Bodo Wolf
IPC分类号： C21B506
CPC分类号： C21B13/002 , C21B5/001 , C21B5/003 , C21B13/14 , C21B2100/22 , C21B2100/44 , Y02P10/136
摘要： Disclosed is a method for producing pig iron using blast furnaces or other appropriate devices, in which materials containing iron are reduced and smelted in the presence of fuels. According to the invention, metallurgical coke can be converted into reduction gas and coke using economical organic exchange gases by combining a multistep process for exchange fuel gasification and a blast furnace process, into which the products of the gasification are fed together or separately at a height of the mouth of the tuyere or through the latter into a melt. The gasification process is also used in the prereduction or iron oxides, fine ores and ore concentrates.
摘要翻译：公开了一种使用高炉或其他合适的装置生产生铁的方法，其中含有铁的材料在燃料存在下被还原和熔炼。根据本发明，冶金焦可以通过组合用于交换燃料气化的多步法和高炉法合并经济的有机交换气体而转化为还原气和焦炭，气化产物在该高炉过程中以高度进料或分开加入的风口或通过后者进入熔体。气化过程也用于预还原或氧化铁，细矿石和矿石精矿。

4. 发明授权

US5373648A Process and device for drying solid materials in an indirectly heated fluidized bed 失效
标题翻译：在间接加热的流化床中干燥固体材料的方法和装置
公开(公告)号：US5373648A
公开(公告)日：1994-12-20
申请号：US30040
申请日：1993-03-18
申请人： Bodo Wolf
发明人： Bodo Wolf
IPC分类号： F26B3/08 , F26B3/084 , F26B17/00
CPC分类号： F26B3/084 , F26B3/08
摘要： A process and apparatus are disclosed for drying solid materials, which allows the thermal energy used for drying to be recovered and the emissions produced during degassing and gasification to be reduced. A solid material which contains an evaporable material, particularly water, is fed to a fluidized bed drier. The solid material is fluidized by fluidizing medium, the fluidizing medium being the evaporable material. The dried solid material is removed from the drier and is fed to further processing, use or disposal. The non-condensable components of the solid material which are insoluble in the condensate of the evaporable material are separated by cooling and condensation of the vapor and released for subsequent use or disposal. The temperature of the fluidized bed is regulated by introducing solid material with a higher content of evaporable material, and by removing the dried solid material from, the fluidized bed, such that the temperature corresponds to the boiling curve of the evaporable material of the solid material removed from the fluidized bed. Therefore, the vapor removed from the fluidized bed contains gaseous substances of the evaporable material, other gaseous impurities and only gaseous components of the solid constituents of the solid material which are volatile below the boiling curve.
摘要翻译： PCT No.PCT / EP90 / 01744 Sec。 371日期1993年3月18日 102（e）1993年3月18日PCT PCT 1990年10月15日PCT公布。出版物WO92 / 05393 日期：1992年4月2日。公开了一种用于干燥固体材料的方法和装置，其允许回收用于干燥的热能，并且减少在脱气和气化期间产生的排放。将含有可蒸发材料，特别是水的固体材料进料到流化床干燥器中。固体材料通过流化介质流化，流化介质是可蒸发材料。将干燥的固体材料从干燥器中取出并进料以进一步加工，使用或处理。不溶于可蒸发材料的冷凝物的固体材料的不可冷凝组分通过蒸气的冷却和冷凝分离，并释放以供后续使用或处置。流化床的温度通过引入具有更高含量的可蒸发材料的固体材料并通过从流化床除去干燥的固体材料来调节，使得温度对应于固体材料的可蒸发材料的沸腾曲线从流化床中取出。因此，从流化床除去的蒸汽含有蒸发材料的气态物质，其它气态杂质，仅含有挥发性低于沸点曲线的固体物质固体成分的气态成分。

5. 发明授权

US5146857A Process for the production of electrical energy and/or heating and process heat 失效
标题翻译：生产电能和/或加热和加工热的方法
公开(公告)号：US5146857A
公开(公告)日：1992-09-15
申请号：US536660
申请日：1991-03-06
申请人： Heinz Spliethoff , Burkhard Moller , Bodo Wolf
发明人： Heinz Spliethoff , Burkhard Moller , Bodo Wolf
IPC分类号： F01K23/00 , F01K17/06 , F23K1/04 , F26B3/084 , F26B23/00 , F26B23/02
CPC分类号： F23K1/04 , F01K17/06 , F26B23/001 , F26B23/028 , F26B3/084 , Y02P70/405
摘要： A partial flue gas stream is used for the production of electrical energy and/or heating and operational heat by utilizing combustion heat from fossil fuels, prior to combustion dried in an indirectly heated fluidized bed dryer, with combustion flue gas used as a carrier medium for the fluidized bed dryer. The mixture of flue gases and steam, deriving from the drying process, is after an intermediate treatment, if necessary, discharged with the main flue gas stream.
摘要翻译： PCT No.PCT / DE89 / 00650 Sec。 371 1991年3月6日 102（e）日期1991年3月6日PCT提交1989年10月12日PCT公布。出版物WO90 / 04702 日期：1990年5月3日。部分烟道气用于在间接加热的流化床干燥器中燃烧干燥之前利用来自化石燃料的燃烧热量生产电能和/或加热和操作热，燃烧烟道气用作流化床干燥器的载体介质。来自干燥过程的烟道气和蒸汽的混合物经过中间处理，如果需要，用主烟道气流排出。

6. 发明授权

US4693729A Method for gasifying solid fuels 失效
标题翻译：气固化燃料的方法
公开(公告)号：US4693729A
公开(公告)日：1987-09-15
申请号：US825628
申请日：1986-02-03
申请人： Georg Beckmann , Bruno Hillinger , Bodo Wolf
发明人： Georg Beckmann , Bruno Hillinger , Bodo Wolf
IPC分类号： C10J3/12 , C10J3/84 , C10J3/14 , C10J3/16
CPC分类号： C10J3/84 , C10J3/12 , C10J2300/0993 , C10J2300/1807 , Y02P20/129
摘要： A method of generating a low-tar generator gas includes contacting the hot tar-containing generator gas in a contact zone with ballast bodies to cool the generator gas and capture tar and dust on the exposed surfaces of the ballast bodies, and admixing the thus heated ballast bodies to the wet solid fuel to be gasified to dry and pre-heat such fuel in preparation for the actual gasification which is performed in two separate gasification zones which are arranged one above the other by reacting the solid fuel with an oxygen-containing gasification medium that is introduced from above into the upper one, and from below into the lower one, of the gasification zones with attendant formation of two conflagration fronts in the gasification zones. The generator gas which is thus generated in the two gasification zones is discharged through a common discharge conduit which has the contact zone incorporated therein. An arrangement for performing this method includes a contact apparatus which bounds the contact zone, is incorporated in the discharge conduit and contains a bed of the ballast bodies, the bed being replenished by ballast bodies which have been separated from ashes after they have been discharged from the lower one of the gasification zones.
摘要翻译：产生低焦油发生器气体的方法包括将接触区中的含有含焦油的发生器气体与压载体接触以冷却发生器气体并捕获压载物的暴露表面上的焦油和灰尘，并将如此加热的将固体燃料压实到待固化的湿固体燃料中以干燥和预热这种燃料，以准备实际的气化，这是在两个分离的气化区中进行的，这两个气化区通过使固体燃料与含氧气化反应从上方引入的介质，从下方进入到气化区的下部，并伴随在气化区中形成两个爆燃前沿。因此，在两个气化区域中产生的发生气体通过并入其中的接触区域的公共排放管道排出。用于执行该方法的装置包括界定接触区的接触装置，并入排放导管中并且包含一个压载体床，该床被压载体补充，压载体在它们已经从较低的一个气化区。

7. 发明授权

US5802840A Process for the low-pollutant conversion of fossil fuels into mechanical power 失效
标题翻译：将化石燃料转化为机械动力的低污染物转化过程
公开(公告)号：US5802840A
公开(公告)日：1998-09-08
申请号：US702544
申请日：1996-09-06
申请人： Bodo Wolf
发明人： Bodo Wolf
IPC分类号： F02B47/10 , F01K25/10 , F02C3/20 , F02C3/34 , F02G1/00
CPC分类号： F02C3/34 , F01K25/103 , F02C3/20 , F02G1/00 , F23L2900/07001 , Y02E20/16 , Y02E20/322 , Y02E20/326 , Y02E20/344 , Y02T10/16
摘要： In a process for the low-pollutant conversion of thermal energy produced by burning fossil fuels into power, the thermal energy produced by burning fossil fuels is delivered directly to the cyclic process by virtue of the fact that in the cyclic process the fuels are burned with oxygen in the presence of carbon dioxide recycled from the cyclic process to form gas turbine operating substances having a temperature of from 800.degree. to 1500.degree. C. Furthermore, according to the invention, the pressure difference between the combustion chamber (1) and the carbon dioxide recycling process is compensated by condensation (11), on the one hand, and evaporation (4, 8) and pre-heating (3) of the carbon dioxide to be recycled and the combustion chamber (1), on the other, by compression (7) and expansion (6) which are performed during the process, preferably with a high-performance gas turbocharger (6, 7). The advantage of the process of the invention resides in the 10 to 20% reduction in the amount of exhaust gas to be discharged into the environment with respect to the prior art, and in the avoidance of nitrogen oxide with a degree of efficiency which is improved in terms of operational economy with respect to the prior art.
摘要翻译： PCT No.PCT / EP95 / 00754 Sec。 371日期1996年9月6日 102（e）日期1996年9月6日PCT 1995年3月2日PCT公布。出版物WO95 / 24545 日期1995年9月14日在将化石燃料燃烧产生的热能的低污染物转化为电力的过程中，通过燃烧化石燃料产生的热能直接传递给循环过程，因为在循环过程中燃料在循环过程循环的二氧化碳存在下用氧气燃烧，形成温度为800°-1500℃的燃气轮机操作物质。此外，根据本发明，燃烧室 1），一方面通过冷凝（11）和要再循环的二氧化碳和燃烧室（1）的蒸发（4,8）和预热（3）来补偿二氧化碳回收过程，另一方面，通过在该过程中进行的压缩（7）和膨胀（6），优选地使用高性能气体涡轮增压器（6,7）。本发明方法的优点在于相对于现有技术将排放到环境中的废气量减少10％至20％，并且避免氮氧化物的效率提高了在现有技术的运行经济方面。

8. 发明申请

US20070093560A1 Process for the holding operation of a Fischer-Tropsch synthesis 审中-公开
标题翻译：费 - 托合成的保持操作方法
公开(公告)号：US20070093560A1
公开(公告)日：2007-04-26
申请号：US11584755
申请日：2006-10-23
申请人： Anton Althapp , Bodo Wolf , Dietmar Ruger , Olaf Schulze
发明人： Anton Althapp , Bodo Wolf , Dietmar Ruger , Olaf Schulze
IPC分类号： C07C27/26
CPC分类号： C10G2/32
摘要： During required change-over to a holding operation in a Fischer-Tropsch synthesis, the reactor is not depressurized after cutting off the supply of fresh synthesis gas to the Fischer-Tropsch reactor, and the temperature is not reduced to below the temperature below which a Fischer-Tropsch reaction no longer takes place. Instead, the reactor is charged with an inert gas, e.g., kept in a vessel at a pressure higher than the operating pressure of the Fischer-Tropsch synthesis, until the reacting components have been flushed out from the Fischer-Tropsch system. While maintaining the pressure and the temperature, the reactor is thus merely inerted for a few seconds, sufficient to interrupt the Fischer-Tropsch reaction. Catalyst damage is avoided, and the liquid phase situation on the catalyst is at least essentially unchanged, facilitating subsequent re-commissioning of the catalyst.
摘要翻译：在需要转换为费 - 托合成中的保持操作期间，在切断向费 - 托反应器的新鲜合成气供应之后，反应器不会减压，并且温度不降低到低于该温度费 - 托反应不再发生。相反，反应器装有惰性气体，例如保持在容器中的压力高于费 - 托合成的操作压力，直至反应组分从费 - 托系统中冲出。在保持压力和温度的同时，反应器仅仅被惰化几秒钟，足以中断费 - 托反应。避免催化剂损伤，并且催化剂上的液相状况至少基本不变，有助于随后重新调试催化剂。

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