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    • 3. 发明授权
    • Tert-alkylphenoxy-substituted polycyclic compounds
    • 叔烷基苯氧基取代的多环化合物
    • US07145010B2
    • 2006-12-05
    • US10472546
    • 2002-03-20
    • Arno BoehmWilli HelferGeorg BeckMatthias KriegerPeter Erk
    • Arno BoehmWilli HelferGeorg BeckMatthias KriegerPeter Erk
    • C07D221/18D06P1/00
    • C07D241/38C07D209/56C07D211/08C07D471/06C07D487/06C08K5/0041C09B3/44C09B5/62C09B47/18C09B69/00C09D5/36C09D11/037
    • Tert-alkylphenoxy-substituted polycyclic compounds of the general formula I where P is a conjugated polycyclic radical which is stable to bases and nucleophiles, optionally bears aryl substituents and contains no group from the group consisting of —CO—NH—CO—, —COOH and —CO—O—CO—; R is C1–C8-alkyl, whose carbon chain may be interrupted by one or more groups selected from the group consisting of —O—, —S—, —NR1—, —CO— and/or —SO2— and which may be monosubstituted or polysubstituted by C1–C6-alkoxy or by a 5- to 7-membered heterocyclic radical which is attached via a nitrogen atom and may contain further heteroatoms and be aromatic; C5–C8-cycloalkyl whose carbon chain may be interrupted by one or more groups selected from the group consisting of —O—, —S—, —NR1—, —CO— and/or —SO2— and which may be monosubstituted or polysubstituted by C1–C6-alkyl; R1 is hydrogen or C1–C6-alkyl; Hal is chlorine and/or bromine; m is from 0 to 15; n is from 1 to 16, subject to the proviso that the sum m+n is ≦16, are prepared and used.
    • 通式I的叔烷基苯氧基取代的多环化合物,其中P是对碱和亲核试剂稳定的共轭多环基团,任选地带有芳基取代基,并且不包含-CO-NH-CO-,-COOH 和-CO-O-CO-; R是C 1 -C 8 - 烷基,其碳链可以被一个或多个选自-O - , - S - , - NR 1 - , - CO - 和/或-SO 2 - ,并且其可以被C 1 -C 1单取代或多取代, 6 - 烷氧基或通过氮原子连接并可以含有其它杂原子并且为芳族的5-至7-元杂环基; C 5 -C 8 -C 8 - 环烷基,其碳链可被一个或多个选自-O - , - S - , - NR < -CO - 和/或-SO 2 - ,并且其可以被C 1 -C 6单取代或多取代, 亚烷基; R 1是氢或C 1 -C 6 - 烷基; Hal是氯和/或溴; m为0〜15; n为1至16,但条件是m + n之和<= 16,并被使用。
    • 7. 发明授权
    • Process for producing perylene-3, 4-dicarboxylic acid imides
    • 生产苝-3,4-二羧酸酰亚胺的方法
    • US6136976A
    • 2000-10-24
    • US147353
    • 1998-12-07
    • Arno BoehmHarald ArmsWilli HelferGeorg Henning
    • Arno BoehmHarald ArmsWilli HelferGeorg Henning
    • C07D221/18C09B5/62C07D471/00C07D239/28C07D401/12C07D403/12
    • C09B5/62C07D221/18
    • Perylene-3,4-dicarboximides I ##STR1## (R.sup.1 is hydrogen; C.sub.1 -C.sub.8 -alkyl; C.sub.5 -C.sub.8 -cycloalkyl; substituted or unsubstituted phenyl or naphthyl;R.sup.2 independently at each occurrence is hydrogen; C.sub.1 -C.sub.18 -alkyl, substituted or unsubstituted aryloxy, arylthio, hetaryloxy or hetarylthio)are prepared by reacting the corresponding perylene-3,4,9,10-tetracarboxylic acid or its anhydride (II) with an amide IIIR.sup.3 --CO--NHR.sup.1 III(R.sup.3 : C.sub.1 -C.sub.4 -alkyl or --NR.sup.4 R.sup.5 where R.sup.4 and R.sup.5 independently are hydrogen or one of the R.sup.1 alkyls, cycloalkyls, phenyls or naphthyls and where if two or more of R.sup.1, R.sup.4 and R.sup.5 are other than hydrogen they are identical)under superatmospheric pressure in the presence of an inert diluent and a transition metal catalyst.
    • PCT No.PCT / EP97 / 02761 Sec。 371 1998年12月7日第 102(e)日期1998年12月7日PCT提交1997年5月28日PCT公布。 公开号WO97 / 46533 日期1997年12月11日亚苯基-3,4-二甲酰亚胺I(R1为氢; C1-C8-烷基; C5-C8-环烷基;取代或未取代的苯基或萘基; R2各自独立地为氢; C1-C18-烷基 ,取代或未取代的芳氧基,芳硫基,杂芳氧基或杂芳硫基)通过相应的苝-3,4,9,10-四羧酸或其酸酐(II)与酰胺IIIR3-CO-NHR1 III(R3:C1- C4烷基或-NR4R5,其中R4和R5独立地是氢或R1烷基,环烷基,苯基或萘基中的一个,并且如果R 1,R 4和R 5中的两个或多个不是氢,则它们相同)在超大气压下 存在惰性稀释剂和过渡金属催化剂。