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1. 发明申请

US20110319579A1 Catalyst Systems for the Catalytic Oligomerization of Olefinic Monomers 失效
标题翻译：用于烯烃单体催化低聚的催化剂体系
公开(公告)号：US20110319579A1
公开(公告)日：2011-12-29
申请号：US13204020
申请日：2011-08-05
申请人： Eric Johannes Maria DE BOER , Harry VAN DER HEIJDEN , Quoc An ON , Johan Paul SMIT , Arie VAN ZON
发明人： Eric Johannes Maria DE BOER , Harry VAN DER HEIJDEN , Quoc An ON , Johan Paul SMIT , Arie VAN ZON
IPC分类号： C08F4/78 , B01J31/00 , C07F9/6574
CPC分类号： C07C2/34 , B01J31/0265 , B01J31/189 , B01J2231/14 , B01J2231/20 , B01J2531/62 , B01J2531/64 , B01J2531/66 , C07F9/5355 , C07F9/6571 , C07F9/657154 , C07F11/005 , C08F110/02
摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (VI); (R9)(R10)P—N(R3)—P(R4) (VI) wherein: the R9 and R10 groups are independently selected from optionally substituted alkyl or heteroalkyl groups; the R3 group is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.
摘要翻译：本发明涉及一种配体及其在烯烃单体低聚催化剂中的应用，具有通式（VI）的配体; （R 9）（R 10）P-N（R 3）-P（R 4）（VI）其中：R 9和R 10基团独立地选自任选取代的烷基或杂烷基; R 3基团选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4基团是任选取代的亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或与被结合的任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合通过亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的两个氧，硫或氮原子到磷原子。

2. 发明申请

US20100010251A1 PREPARATION OF ALKOXYSULFATES 审中-公开
标题翻译：烷基糖苷的制备
公开(公告)号：US20100010251A1
公开(公告)日：2010-01-14
申请号：US12500488
申请日：2009-07-09
申请人： Jan Hermen Hendrik MEURS , Jasper Roelf Smit , Arie Van Zon
发明人： Jan Hermen Hendrik MEURS , Jasper Roelf Smit , Arie Van Zon
IPC分类号： C07C305/14
CPC分类号： C07C303/24 , C07C305/04 , C07C305/10
摘要： A process for the preparation of alkoxysulfates from organic compounds containing one or more nucleophilic groups by reacting said organic compound, in a water-miscible solvent selected from the group consisting of sulfur-containing solvents such as dimethylsulfoxide (DMSO) or sulfolane, or polar solvents such as tetrahydrofuran (THF), dimethylformamide (DMF), dimethylacetamide (DMA) and hexamethylphosphoric triamide (HMPT), with an alkylene sulfate, in a non-water-miscible solvent selected from the group consisting of chlorinated solvents such as methylene chloride, chloroform, carbon tetrachloride, trichloroethane or chlorinated aromatics, such as chlorobenzene or dichlorobenzene, and non-chlorinated aromatics, such as toluene or xylenes, in the presence of a base selected from the group consisting of hydroxides, carbonates and hydrogen carbonates of alkali metals or alkaline earth metals.
摘要翻译：一种由含有一个或多个亲核基团的有机化合物制备烷氧基硫酸盐的方法，通过使所述有机化合物与选自二氧化硫（DMSO）或环丁砜的含硫溶剂或极性溶剂的水混溶性溶剂例如四氢呋喃（THF），二甲基甲酰胺（DMF），二甲基乙酰胺（DMA）和六甲基磷酰三胺（HMPT））与亚烷基硫酸盐在非水混溶性溶剂中，选自氯化溶剂如二氯甲烷，氯仿，四氯化碳，三氯乙烷或氯化芳族化合物如氯苯或二氯苯，以及非氯化芳族化合物如甲苯或二甲苯，在选自碱金属或碱金属的氢氧化物，碳酸盐和碳酸氢盐的碱的存在下地球金属。

3. 发明授权

US07547783B2 Transition metal complexes 失效
标题翻译：过渡金属络合物
公开(公告)号：US07547783B2
公开(公告)日：2009-06-16
申请号：US11088023
申请日：2005-03-23
申请人： Eric Johannes Maria De Boer , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
发明人： Eric Johannes Maria De Boer , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
IPC分类号： C07F15/00 , B01J31/22 , C08F4/80
CPC分类号： B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0244 , B01J2531/842 , B01J2531/845 , C07F11/005 , C07F15/025 , C07F15/065 , C08F10/00 , C08F4/60089 , C08F4/69224 , C08F4/7042
摘要： A transition metal complex which is a bis-arylimine pyridine MXn complex or a [bis-arylimine pyridine MXp+][NC−]q complex comprising a bis-arylimine pyridine ligand and M is a transition metal atom; n matches the formal oxidation state of the transition metal atom M; X is halide, optionally substituted hydrocarbyl, alkoxide, amide, or hydride; NC− is a non-coordinating anion; and p+q matches the formal oxidation state of the transition metal atom M. The transition metal complexes of the present invention, their complexes with non-coordinating anions and catalyst systems containing such complexes have good solubility in non-polar media and chemically inert non-polar solvents especially aromatic hydrocarbon solvents. The catalyst systems can be used for a wide range of (co-)oligomerization, polymerization and dimerization reactions.
摘要翻译：作为双芳基亚胺吡啶MXn络合物或包含双芳基亚胺吡啶配体的[双芳基亚胺吡啶MXp +] [NC-] q络合物的过渡金属络合物，M为过渡金属原子; n匹配过渡金属原子M的正式氧化态; X是卤化物，任选取代的烃基，醇盐，酰胺或氢化物; NC-是非配位阴离子; 并且p + q与过渡金属原子M的正式氧化态匹配。本发明的过渡金属络合物，其与非配位阴离子的配合物和含有这种络合物的催化剂体系在非极性介质中具有良好的溶解性和化学惰性非极性溶剂，特别是芳族烃溶剂。催化剂体系可用于广泛的（共）低聚，聚合和二聚反应。

4. 发明申请

US20090069517A1 LIGANDS AND CATALYST SYSTEMS FOR THE OLIGOMERIZATION OF OLEFINIC MONOMERS 失效
标题翻译：用于烯烃单体低级化的配体和催化剂体系
公开(公告)号：US20090069517A1
公开(公告)日：2009-03-12
申请号：US11961719
申请日：2007-12-20
申请人： Eric Johannes Maria DE BOER , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
发明人： Eric Johannes Maria DE BOER , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
IPC分类号： C08F4/22 , C07F9/535 , C07D265/30 , B01J31/18 , C07C69/76
CPC分类号： C07F11/005 , B01J31/0265 , B01J31/189 , B01J2231/20 , B01J2531/60 , B01J2531/62 , C07C2/36 , C07C2531/24 , C07F9/5355
摘要： The present invention relates to ligands and catalyst systems and a process for the simultaneous trimerization and tetramerization of olefinic monomers using said ligands, the ligands having the general formula (I): (R1)2P—P(R1)m(R2)n═N(R3) (I) wherein R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R1 groups are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions; and the R2 groups are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions; with the proviso that m is 0 or 1, n is 1 or 2 and the total of m+n is 2.
摘要翻译：本发明涉及配体和催化剂体系，以及使用所述配体同时使烯属单体三聚和四聚的方法，具有通式（I）的配位体：<？in-line-formula description =“In-line Formulas” （R1）2P-P（R1）m（R2）nN（R3）（I）<？in-line-formula description =“In-line formula”end =“tail”？>其中 R3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R1基团独立地选自在至少一个邻位上带有极性取代基的任选取代的芳族基团; 并且R 2基团独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，条件是当基团是芳族的时，其在任何邻位不含极性取代基; 条件是m为0或1，n为1或2，m + n的总数为2。

5. 发明申请

US20090062493A1 LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 有权
标题翻译：烯烃单体催化低级化合物的配体和催化剂体系
公开(公告)号：US20090062493A1
公开(公告)日：2009-03-05
申请号：US11961638
申请日：2007-12-20
申请人： Eric Johannes Maria DE BOER , Harry VAN DER HEIJDEN , Quoc An ON , Johan Paul SMIT , Arie VAN ZON
发明人： Eric Johannes Maria DE BOER , Harry VAN DER HEIJDEN , Quoc An ON , Johan Paul SMIT , Arie VAN ZON
IPC分类号： C08F4/22 , C07F9/535 , B01J31/02
CPC分类号： C07C2/34 , B01J31/0265 , B01J31/189 , B01J2231/14 , B01J2231/20 , B01J2531/62 , B01J2531/64 , B01J2531/66 , C07F9/5355 , C07F9/6571 , C07F9/657154 , C07F11/005 , C08F110/02
摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (I); P(R4)—P(R1)(R2)═N(R3) (I) wherein: the R1 group is selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R2 group is selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups; the R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.
摘要翻译：本发明涉及一种配体及其在烯烃单体低聚催化剂中的应用，具有通式（I）的配体; P（R4）-P（R1）（R2）-N（R3）（I）<？in-line-formula description =“In-line-formula”end =“lead” =“在线式”末端=“尾”→其中：R1基团选自烃基，取代的烃基，杂烃基和取代的杂烃基; R2基团选自烃基，取代的烃基，杂烃基和取代的杂烃基; R3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4基团是任选取代的亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或与被结合的任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合通过亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的两个氧，硫或氮原子到磷原子。

6. 发明申请

US20090057608A1 ALKOXYLATE COMPOSITION AND A PROCESS FOR PREPARING THE SAME 审中-公开
标题翻译：烷氧基化合物及其制备方法
公开(公告)号：US20090057608A1
公开(公告)日：2009-03-05
申请号：US12146231
申请日：2008-06-25
申请人： Michiel Barend ELEVELD , Harmen Van Der Hulst , Jan Hermen Hendrik Meurs , Jasper Roelf Smit , Arie Van Zon
发明人： Michiel Barend ELEVELD , Harmen Van Der Hulst , Jan Hermen Hendrik Meurs , Jasper Roelf Smit , Arie Van Zon
IPC分类号： C07C29/10 , C09K3/00
CPC分类号： C11D1/722 , C08G65/14 , C08G65/2609 , C08G65/2663 , C08G65/337
摘要： A process for the preparation of an alkoxylate composition, said process comprising the steps of: (a) introducing into a reactor system one or more compounds with one or more active hydrogen atoms, selected from the group comprising alkanoic acids, alkanoic amides, alkanoic ethanolamides, alcohols and alkylmercaptans, and a double metal cyanide catalyst; (b) contacting the one or more compounds with one or more active hydrogen atoms and the double metal cyanide catalyst with propylene oxide and/or butylene oxide to form a first product mixture comprising double metal cyanide catalyst and compounds formed by the addition of one of more propylene oxide and/or butylene oxide units to the one or more compounds with one or more active hydrogen atoms; and (c) contacting the first product mixture with ethylene oxide to form a second product mixture comprising compounds formed by the addition of one of more ethylene oxide units to the compounds formed in step (b).
摘要翻译：一种制备烷氧基化物组合物的方法，所述方法包括以下步骤：（a）将一种或多种具有一个或多个活性氢原子的化合物引入反应器系统中，所述活性氢原子选自链烷酸，链烷酰胺，链烷醇乙酰胺，醇和烷基硫醇，以及双金属氰化物催化剂; （b）使一种或多种化合物与一种或多种活性氢原子和双金属氰化物催化剂与环氧丙烷和/或环氧丁烷接触以形成包含双金属氰化物催化剂的第一产物混合物和通过加入以下之一形成的化合物：更多的环氧丙烷和/或环氧丁烷单元与一种或多种具有一个或多个活性氢原子的化合物; 和（c）使第一产物混合物与环氧乙烷接触以形成包含通过向步骤（b）中形成的化合物中加入更多环氧乙烷单元之一形成的化合物的第二产物混合物。

7. 发明申请

US20050215792A1 Transition metal complexes 失效
标题翻译：过渡金属络合物
公开(公告)号：US20050215792A1
公开(公告)日：2005-09-29
申请号：US11088023
申请日：2005-03-23
申请人： Eric Johannes De Boer , Harry Van Der Heijden , Quoc On , Johan Smit , Arie Van Zon
发明人： Eric Johannes De Boer , Harry Van Der Heijden , Quoc On , Johan Smit , Arie Van Zon
IPC分类号： C07F11/00 , C07F13/00 , C07F15/00 , C07F15/02 , C07F15/06 , C08F10/00 , C07C2/02
CPC分类号： B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0244 , B01J2531/842 , B01J2531/845 , C07F11/005 , C07F15/025 , C07F15/065 , C08F10/00 , C08F4/60089 , C08F4/69224 , C08F4/7042
摘要： A transition metal complex which is a bis-arylimine pyridine MXn complex or a [bis-arylimine pyridine MXp+][NC−]q complex comprising a bis-arylimine pyridine ligand and M is a transition metal atom; n matches the formal oxidation state of the transition metal atom M; X is halide, optionally substituted hydrocarbyl, alkoxide, amide, or hydride; NC− is a non-coordinating anion; and p+q matches the formal oxidation state of the transition metal atom M. The transition metal complexes of the present invention, their complexes with non-coordinating anions and catalyst systems containing such complexes have good solubility in non-polar media and chemically inert non-polar solvents especially aromatic hydrocarbon solvents. The catalyst systems can be used for a wide range of (co-)oligomerization, polymerization and dimerization reactions.
摘要翻译：作为双芳基亚胺吡啶MX>络合物或[双芳基亚胺吡啶MX A>> SUP SUP SUP SUP SUP SUP SUP SUP SUP SUP SUP 其包含双芳基亚胺吡啶配体，M为过渡金属原子; n匹配过渡金属原子M的正式氧化态; X是卤化物，任选取代的烃基，醇盐，酰胺或氢化物; NC-是非配位阴离子; 并且p + q与过渡金属原子M的正式氧化态匹配。本发明的过渡金属络合物，其与非配位阴离子的配合物和含有这种络合物的催化剂体系在非极性介质中具有良好的溶解性和化学惰性非极性溶剂，特别是芳族烃溶剂。催化剂体系可用于广泛的（共）低聚，聚合和二聚反应。

8. 发明申请

US20100311932A1 LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：烯烃单体催化低级化合物的配体和催化剂体系
公开(公告)号：US20100311932A1
公开(公告)日：2010-12-09
申请号：US12859337
申请日：2010-08-19
申请人： Eric Johannes Maria DE BOER , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
发明人： Eric Johannes Maria DE BOER , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
IPC分类号： C08F4/22 , C07F9/08 , B01J31/12
CPC分类号： C07C2/34 , B01J31/0265 , B01J31/189 , B01J2231/14 , B01J2231/20 , B01J2531/62 , B01J2531/64 , B01J2531/66 , C07F9/5355 , C07F9/6571 , C07F9/657154 , C07F11/005 , C08F110/02
摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (VI); (R9)(R10)P—N(R3)—P(R4) (VI) wherein: the R9 and R10 groups are independently selected from optionally substituted alkyl or heteroalkyl groups; the R3 group is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.
摘要翻译：本发明涉及一种配体及其在烯烃单体低聚催化剂中的应用，具有通式（VI）的配体; （R 9）（R 10）P-N（R 3）-P（R 4）（VI）其中：R 9和R 10基团独立地选自任选取代的烷基或杂烷基; R 3基团选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4基团是任选取代的亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或与被结合的任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合通过亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的两个氧，硫或氮原子到磷原子。

9. 发明授权

US07589245B2 Process for preparing linear alpha olefins 失效
标题翻译：线性α-烯烃的制备方法
公开(公告)号：US07589245B2
公开(公告)日：2009-09-15
申请号：US11179459
申请日：2005-07-12
申请人： Eric Johannes Maria De Boer , Harry Van Der Heijden , Inge Oosterveld , Arie Van Zon
发明人： Eric Johannes Maria De Boer , Harry Van Der Heijden , Inge Oosterveld , Arie Van Zon
IPC分类号： C07C2/26 , C07C2/34
CPC分类号： C07C2/08 , C07C1/327 , C07C5/2575 , C07C2523/755 , C07C2527/128 , C07C2531/14 , C07C11/02
摘要： A process for the preparation of linear alpha olefins having 2n carbon atoms from linear alpha olefins having n carbon atoms comprising the steps of (a) dimerizing a linear alpha olefin having n carbon atoms in the presence of a dimerization catalyst to produce a linear internal olefin having 2n carbon atoms; (b)(i) reacting the linear internal olefin having 2n carbon atoms produced in step (a) with a trialkylaluminium compound in the presence of a catalytic amount of an isomerization/displacement catalyst in order to cause isomerization of the linear internal olefin and to displace alkyl group(s) from said trialkylaluminium compound to form an alkyl aluminium compound wherein at least one of the alkyl groups bound to aluminium is a linear alkyl which has been derived from the isomerization of said linear internal olefin; and (b)(ii) reacting said alkyl aluminium compound with an alpha olefin optionally in the presence of a displacement catalyst so as to displace said linear alkyl from said alkyl aluminium compound to form a linear alpha olefin having 2n carbon atoms.
摘要翻译：制备具有n个碳原子的直链α-烯烃具有2n个碳原子的直链α-烯烃的方法，包括以下步骤：（a）在二聚催化剂存在下二聚具有n个碳原子的直链α-烯烃以产生线性内烯烃具有2n个碳原子; （b）（i）使催化量的异构化/置换催化剂存在下使步骤（a）中产生的具有2n个碳原子的直链内烯烃与三烷基铝化合物反应，以使线性内烯烃异构化，从所述三烷基铝化合物置换烷基以形成烷基铝化合物，其中至少一个与铝结合的烷基是由所述直链内烯烃的异构化衍生的直链烷基; 和（b）（ii）任选地在置换催化剂存在下使所述烷基铝化合物与α-烯烃反应，以使所述烷基铝化合物的所述直链烷基取代形成具有2n个碳原子的直链α-烯烃。

10. 发明授权

US07462730B2 Branched ester composition 失效
标题翻译：支链酯组成
公开(公告)号：US07462730B2
公开(公告)日：2008-12-09
申请号：US10929080
申请日：2004-08-27
申请人： Kirk Herbert Raney , Arie Van Zon , Marijke De Boer-Wildschut
发明人： Kirk Herbert Raney , Arie Van Zon , Marijke De Boer-Wildschut
IPC分类号： C07C53/00
CPC分类号： A61Q19/00 , A61K8/37 , A61Q15/00 , A61Q17/04 , C07C69/24
摘要： A branched ester composition obtainable by the reaction of a carboxylic acid with a branched alcohol composition under esterification reaction conditions wherein the branched alcohol composition has from about 8 to about 36 carbon atoms and an average number of branches per molecule of from about 0.7 to about 3.0, said branching comprising methyl and ethyl branches. The present invention further relates to personal care compositions for topical application to the skin or hair comprising said branched ester composition. The branched ester composition of the invention provides improved formulation flexibility.
摘要翻译：在酯化反应条件下通过羧酸与支链醇组合物反应获得的支链酯组合物，其中支链醇组合物具有约8至约36个碳原子，每分子平均分支数为约0.7至约3.0 所述支链包括甲基和乙基支链。本发明还涉及用于局部施用于包含所述支链酯组合物的皮肤或头发的个人护理组合物。本发明的支链酯组合物提供改进的制剂柔性。

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