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1. 发明授权

US07507782B2 Transition-metal complexes with tridentate, nitrogen-containing ligands 失效
标题翻译：过渡金属络合物与三齿，含氮配体
公开(公告)号：US07507782B2
公开(公告)日：2009-03-24
申请号：US10557143
申请日：2004-05-19
申请人： Shahram Mihan , Markus Enders , Olaf Fritz
发明人： Shahram Mihan , Markus Enders , Olaf Fritz
IPC分类号： C08F4/69 , C08F4/602 , C08F4/74 , B01J31/18 , B01J31/22
CPC分类号： C08F10/00 , B01J31/1815 , B01J2531/0247 , B01J2531/46 , B01J2531/56 , B01J2531/62 , C07F7/003 , C07F9/005 , C07F9/6506 , C07F11/005 , C08F110/02 , C08F2500/04 , C08F2500/17 , C08F2500/10 , C08F2500/07 , C08F4/64089 , C08F4/69224 , C08F4/68224 , C08F4/64179 , C08F4/68448 , C08F4/69448
摘要： Transition metal complexes with tridentate, nitrogen-containing, uncharged ligand systems, a catalyst system comprising at least one of the transition metal complexes, the use of the catalyst system for the polymerization or copolymerization of olefins and a process for preparing polyolefins by polymerization or copolymerization of olefins in the presence of the catalyst system.
摘要翻译：具有三齿，含氮，不带电配体体系的过渡金属络合物，包含至少一种过渡金属配合物的催化剂体系，使用催化剂体系进行烯烃的聚合或共聚以及通过聚合或共聚制备聚烯烃的方法的烯烃在催化剂体系的存在下。

2. 发明授权

US07459510B2 Polymerization process 失效
标题翻译：聚合过程
公开(公告)号：US07459510B2
公开(公告)日：2008-12-02
申请号：US11629412
申请日：2005-06-20
申请人： Zerong Lin , Pradeep P. Shirodkar
发明人： Zerong Lin , Pradeep P. Shirodkar
IPC分类号： C08F2/14 , C08F2/00 , C08F4/80
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08F2/14 , C08F2/06 , C08F2500/07 , C08F2500/04 , C08F210/14 , C08F210/08 , C08F4/69224 , C08F4/7042
摘要： This invention relates to a process to polymerize olefins comprising contacting, in a reactor, a pyridyl-di-imine compound and an activator with one or more olefin monomer(s) in the presence of a fluorinated hydrocarbon.
摘要翻译：本发明涉及聚合烯烃的方法，包括在反应器中使吡啶基二亚胺化合物和活化剂与一种或多种烯烃单体在氟化烃存在下接触。

3. 发明申请

US20070207916A1 Catalyst System for Olefin Polymerization, its Production and Use 有权
标题翻译：用于烯烃聚合的催化剂体系，其生产和使用
公开(公告)号：US20070207916A1
公开(公告)日：2007-09-06
申请号：US11578593
申请日：2005-04-21
申请人： Shahram Mihan , Harald Schmitz
发明人： Shahram Mihan , Harald Schmitz
IPC分类号： B01J37/00 , C08F4/44
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F110/02 , Y10S526/943 , C08F2/34 , C08F4/61904 , C08F4/65916 , C08F4/025 , C08F4/60089 , C08F4/69224 , C08F4/7042
摘要： Process for producing a catalyst system, which comprises the following steps: A) provision of a mixture of at least two different organic transition metal compounds, at least one hydrolyzed organoaluminum compound and a solvent and impregnation of a dry porous support component with the mixture from step A), with the total volume of the mixture being from 0.6 to 1.5 times the total pore volume of the support component, and also catalyst systems obtainable in this way and their use for olefin polymerization.
摘要翻译：制备催化剂体系的方法，其包括以下步骤：A）提供至少两种不同的有机过渡金属化合物，至少一种水解的有机铝化合物和溶剂的混合物，并将干燥的多孔载体组分浸渍步骤A），混合物的总体积为载体组分的总孔体积的0.6-1.5倍，以及可以以这种方法获得的催化剂体系及其在烯烃聚合中的用途。

4. 发明授权

US07229943B2 Polymerisation and oligomerisation catalysts 有权
标题翻译：聚合和低聚催化剂
公开(公告)号：US07229943B2
公开(公告)日：2007-06-12
申请号：US10549314
申请日：2004-03-18
申请人： Vernon Charles Gibson , Atanas Kostadinov Tomov
发明人： Vernon Charles Gibson , Atanas Kostadinov Tomov
IPC分类号： C08F4/60 , C08F4/606 , C08F4/602 , C08F4/603
CPC分类号： C08F136/06 , C08F4/63912 , C08F4/7006 , C08F10/00 , C08F110/02 , C08F210/02 , C08F210/16 , C08F4/639 , C08F4/69224 , C08F4/70 , C08F2500/04 , C08F2500/03 , C08F212/08 , C08F232/00 , C08F2500/25 , C08F220/00 , C08F210/14 , C08F4/69284 , C08F4/6925 , C08F4/69215 , C08F4/69146 , C08F4/68224 , C08F4/6825 , C08F4/68215 , C08F4/68043 , C08F4/64089 , C08F4/64099 , C08F4/64093
摘要： A polymerisation catalyst comprising (1) a transition metal compound of Formula A, and optionally (2) an activating quantity of a Lewis acid activator. Z is a five-membered heterocyclic group containing at least one carbon atom, at least one nitrogen atom and at least one other hetero atom selected from nitrogen, sulphur and oxygen, the remaining atoms in the ring being nitrogen or carbon; M is a metal from Group 3 to 11 of the Periodic Table or a lanthanide metal; E1 and E2 are divalent groups from (i) aliphatic hydrocarbon, (ii) alicyclic hydrocarbon, (iii) aromatic hydrocarbon, (iv) alkyl substituted aromatic hydrocarbon (v) heterocyclic groups and (vi) heterosubstituted derivatives of groups (i) to (v); D1 and D2 are donor groups; X is an anionic group, L is a neutral donor group; n=m=zero or 1; y and z are zero or integers. The catalysts are useful for polymerising or oligomerising 1-olefins.
摘要翻译：一种聚合催化剂，其包含（1）式A的过渡金属化合物和任选的（2）活化量的路易斯酸活化剂。 Z是含有至少一个碳原子，至少一个氮原子和至少一个选自氮，硫和氧的其它杂原子的五元杂环基，该环中的剩余原子是氮或碳; M是元素周期表第3至11族的金属或镧系金属; （i）脂族烃，（ii）脂环烃，（iii）芳族烃，（iv）烷基取代的芳族烃（v）的二价基团）杂环基团和（vi）基团（i）至（v）的异取代衍生物; D 1和D 2是供体基团; X是阴离子基团，L是中性给体基团; n = m =零或1; y和z为零或整数。该催化剂可用于聚合或低聚1-烯烃。

5. 发明授权

US07056997B2 Catalyst composition and olefin polymerization using same 失效
公开(公告)号：US07056997B2
公开(公告)日：2006-06-06
申请号：US11138089
申请日：2005-05-26
申请人： Brooke L. Small , Angel Jose Marcucci
发明人： Brooke L. Small , Angel Jose Marcucci
IPC分类号： C08F4/44 , B01J31/23
CPC分类号： B01J31/18 , B01J31/1815 , B01J31/2204 , B01J31/24 , B01J2231/122 , B01J2231/20 , B01J2531/56 , B01J2531/62 , B01J2531/72 , C07F11/005 , C08F4/63912 , C08F4/6392 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2420/02 , C08F4/63904 , C08F2500/02 , C08F2500/23 , C08F210/14 , C08F4/69224 , C08F10/00 , C08F4/69232
摘要： Novel metal complexes, particularly chromium complexes, which contain at least one tridentate ligand are disclosed and prepared. Olefins, particularly ethylene, can be reacted to form butene and/or other homo- or co-oligomers and/or polymers with high α-olefin concentrations by contacting a metal catalyst which contains a transition metal, particularly chromium, complexes having per metal atom at least one tridentate ligand with N, O, or N and O coordinating sites.

6. 发明授权

US06911506B2 Catalyst composition and olefin polymerization using same 失效
公开(公告)号：US06911506B2
公开(公告)日：2005-06-28
申请号：US10013144
申请日：2001-12-10
申请人： Brooke L. Small , Angel Jose Marcucci
发明人： Brooke L. Small , Angel Jose Marcucci
IPC分类号： C07F11/00 , C08F4/60 , C08F4/62 , C08F4/6392 , C08F4/659 , C08F4/68 , C08F4/685 , C08F4/69 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/44 , B01J31/23
CPC分类号： B01J31/18 , B01J31/1815 , B01J31/2204 , B01J31/24 , B01J2231/122 , B01J2231/20 , B01J2531/56 , B01J2531/62 , B01J2531/72 , C07F11/005 , C08F4/63912 , C08F4/6392 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2420/02 , C08F4/63904 , C08F2500/02 , C08F2500/23 , C08F210/14 , C08F4/69224 , C08F10/00 , C08F4/69232
摘要： Novel metal complexes, particularly chromium complexes, which contain at least one tridentate ligand are disclosed and prepared. Olefins, particularly ethylene, can be reacted to form butene and/or other homo- or co-oligomers and/or polymers with high α-olefin concentrations by contacting a metal catalyst which contains a transition metal, particularly chromium, complexes having per metal atom at least one tridentate ligand with N, O, or N and O coordinating sites.

7. 发明申请

US20040007158A1 Solvent-containing pastes containing in addition polyolefin wax 失效
标题翻译：另外含有聚烯烃蜡的含溶剂的糊料
公开(公告)号：US20040007158A1
公开(公告)日：2004-01-15
申请号：US10311373
申请日：2002-12-16
发明人： Shahram Mihan , Andreas Deckers
IPC分类号： C09D004/00
CPC分类号： C08F10/00 , C08F210/02 , C08F2500/23 , C08F2500/17 , C08F4/69224
摘要： Solvent-containing pastes comprising a polyolefin wax component prepared from one or more olefins by catalysis using a single-site catalyst based on a complex of a transition metal from groups 5 to 8 of the Periodic System of the Elements, and use of these pastes.
摘要翻译：含有溶剂的糊料包含由一种或多种烯烃制备的聚烯烃蜡组分，其通过使用基于元素周期系统的组5至8的过渡金属的复合物的单位点催化剂催化，以及这些糊剂的使用。

8. 发明授权

US08067328B2 Polymerisation and oligomerisation catalysts 有权
标题翻译：聚合和低聚催化剂
公开(公告)号：US08067328B2
公开(公告)日：2011-11-29
申请号：US11660050
申请日：2005-07-25
申请人： Vernon Charles Gibson , Atanas Kostadinov Tomov , Grant Berent Jacobsen
发明人： Vernon Charles Gibson , Atanas Kostadinov Tomov , Grant Berent Jacobsen
IPC分类号： C08F4/602 , B01J31/22
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , C08F4/022 , C08F4/69224 , C08F2500/01 , C08F4/64099 , C08F4/64089 , C08F4/68224 , C08F4/6825 , C08F4/68215 , C08F4/69275 , C08F4/6925 , C08F4/69215 , C08F4/69034 , C08F4/69146
摘要： A polymerization catalyst composition comprising (1) a transition metal compound of Formula (A), Z being 5-membered heterocyclic containing at least one carbon, at least one nitrogen and at least one of nitrogen, sulphur and oxygen, the others being nitrogen or carbon; M is a Group 3 to 11 metal or a lanthamide metal; E1 and E2 are divalent groups of aliphatic, alicyclic, aromatic or alkyl substituted aromatic hydrocarbon, or heterocyclic; D1 and D2 are donor atoms or groups; X is an anionic group, L is a neutral donor group; n=m=zero or 1; y and z are zero or integer such that X and L satisfy valency/oxidation state of M, (2) a catalyst-activating support which is a solid particulate substance, insoluble in hydrocarbons, comprising at least magnesium and aluminum atoms and hydrocarbyloxy groups containing 1 to 20 carbon atoms, the molar ration of Mg/Al being in the range 1.0 to 300 and the molar ratio of hydrocarbyloxy groups to aluminum atoms being in the range 0.5 to 2.0, and optionally, (3) an additional activator selected from aluminum alkyl and boron compounds.
摘要翻译：一种聚合催化剂组合物，其包含（1）式（A）的过渡金属化合物，Z为含有至少一个碳，至少一个氮和氮，硫和氧中的至少一个的5元杂环，其余为氮或碳; M是第3至11族金属或花生苷金属; E1和E2是脂族，脂环族，芳族或烷基取代的芳族烃或杂环的二价基团; D1和D2是供体原子或基团; X是阴离子基团，L是中性给体基团; n = m =零或1; y和z为零或整数，使得X和L满足M的化合价/氧化态，（2）催化剂活化载体，其是固体颗粒物质，不溶于烃，包含至少镁和铝原子和含有烃氧基的烃氧基 1〜20个碳原子，Mg / Al的摩尔比在1.0〜300范围内，烃氧基与铝原子的摩尔比在0.5〜2.0的范围内，任选地，（3）另外的活化剂，选自铝烷基和硼化合物。

9. 发明申请

US20100121009A1 CATALYST SYSTEM FOR OLEFIN POLYMERIZATION PROCESS FOR PRODUCING IT AND A PROCESS FOR THE POLYMERIZATION OF ALPHA-OLEFINS USING THE CATALYST SYSTEM 审中-公开
标题翻译：用于生产烯烃聚合方法的催化剂体系和使用催化剂体系合成α-烯烃的方法
公开(公告)号：US20100121009A1
公开(公告)日：2010-05-13
申请号：US12451207
申请日：2008-05-05
申请人： Marc Oliver Kristen , Rolf Mülhaupt , Gil Scheuermann , Alexander Kurek
发明人： Marc Oliver Kristen , Rolf Mülhaupt , Gil Scheuermann , Alexander Kurek
IPC分类号： C08F4/12 , B01J37/30
CPC分类号： C08F10/00 , C08F110/02 , C08F4/7006 , C08F4/69034 , C08F4/025 , C08F2500/20 , C08F2500/04 , C08F4/69224
摘要： The invention relates to a catalyst system comprising a support in which transition metal cations or uncharged transition metal atoms are distributed. The system further comprises one or more separately added ligands which are capable of forming a coordinate or covalent bond with the transition metals. The catalyst system is produced by replacing metal ions present in a support by transition metal ions. The transition metal ions can optionally be reduced. One or more ligands which are capable of forming a coordinate or covalent bond with the transition metal or metals are subsequently added. The catalyst is used for the polymerization of olefins.
摘要翻译：本发明涉及一种催化剂体系，其包括其中分布有过渡金属阳离子或不带电过渡金属原子的载体。该体系还包含一个或多个单独添加的能够与过渡金属形成配位或共价键的配体。通过用过渡金属离子代替载体中存在的金属离子来制备催化剂体系。可以任选地还原过渡金属离子。随后加入能够与过渡金属或金属形成配位或共价键的一个或多个配位体。该催化剂用于烯烃的聚合。

10. 发明申请

US20070185328A1 Transition-metal complexes with tridentate, nitrogen-containing ligands 失效
标题翻译：过渡金属络合物与三齿，含氮配体
公开(公告)号：US20070185328A1
公开(公告)日：2007-08-09
申请号：US10557143
申请日：2004-05-19
申请人： Shahram Mihan , Markus Enders , Olaf Fritz
发明人： Shahram Mihan , Markus Enders , Olaf Fritz
IPC分类号： C07F15/00
CPC分类号： C08F10/00 , B01J31/1815 , B01J2531/0247 , B01J2531/46 , B01J2531/56 , B01J2531/62 , C07F7/003 , C07F9/005 , C07F9/6506 , C07F11/005 , C08F110/02 , C08F2500/04 , C08F2500/17 , C08F2500/10 , C08F2500/07 , C08F4/64089 , C08F4/69224 , C08F4/68224 , C08F4/64179 , C08F4/68448 , C08F4/69448
摘要： Transition metal complexes with tridentate, nitrogen-containing, uncharged ligand systems, a catalyst system comprising at least one of the transition metal complexes, the use of the catalyst system for the polymerization or copolymerization of olefins and a process for preparing polyolefins by polymerization or copolymerization of olefins in the presence of the catalyst system.
摘要翻译：具有三齿，含氮，不带电配体体系的过渡金属络合物，包含至少一种过渡金属配合物的催化剂体系，使用催化剂体系进行烯烃的聚合或共聚以及通过聚合或共聚制备聚烯烃的方法的烯烃在催化剂体系的存在下。

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