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    • 1. 发明授权
    • Method of preparing metal-containing soap and soap so produced
    • 制备含金属皂和肥皂的方法
    • US4182685A
    • 1980-01-08
    • US758346
    • 1977-01-10
    • George G. Merkl
    • George G. Merkl
    • C11D3/39C11D9/00C11D9/38C11D13/00
    • C11D3/3945C11D3/3942C11D9/002
    • Metal-containing soaps are prepared by reaction of at least one fatty acid with a water-soluble, multi-metal, inorganic, amide group-containing monomeric or polymeric complex. Such monomeric or polymeric complex is obtained by reacting, in the presence of aqueous ammonia, at least one non-alkaline metal with an alkali metal hydroxide in accordance with a reaction sequence which produces reactive NH.sub.2 groups. Variation of the reaction parameters, particularly pH, will determine whether the soap has detergent or non-detergent properties. To produce a detergent soap also containing effective bleach properties, hydrogen peroxide can be added to the fatty acid and complex reactants.
    • 含金属皂通过至少一种脂肪酸与水溶性多金属,无机,含酰胺基的单体或聚合物络合物的反应来制备。 通过在氨水的存在下,根据产生反应性NH 2基团的反应顺序使至少一种非碱金属与碱金属氢氧化物反应来获得这样的单体或聚合物络合物。 反应参数的变化,特别是pH,将决定皂是否具有洗涤剂或非洗涤剂性质。 为了生产还含有有效漂白剂性质的洗涤剂皂,可将过氧化氢加入到脂肪酸和复合反应物中。
    • 5. 发明授权
    • Process utilizing activated aluminum and products produced thereby
    • 使用活化铝和由此生产的产品的工艺
    • US4017591A
    • 1977-04-12
    • US664999
    • 1976-03-08
    • George G. Merkl
    • George G. Merkl
    • C05D9/02C01B21/20
    • C05D9/02
    • Complex aluminum-containing reaction products are produced by a process which comprises:Reactively contacting in an aqueous mediumA. activated aluminum comprising aluminum metal, at least 99.9% by weight pure, which has been permeated with a second metal or alloy selected from mercury, gallium and indium/gallium allows; andB. a source of NO.sub.x, e.g., NO and/or NO.sub.2 gas, or nitric acid.The product of the above reaction, useful as a fertilizer and/or a bleach or soap precursor contains aluinum, nitrogen in the form of NH, NH.sub.2, and/or NH.sub.3 groups, a minimum of nitrate groups, hydroperoxy groups, and possible minor amounts of nitrite and hydroxy groups. The product is formed as an aqueous solution and appears polymeric in nature.The aluminum containing reaction product can be further reacted with ammonia to increase the nitrogen content and increase the pH of the reaction product toward neutral and/or with hydrogen peroxide to produce a product which is further enriched with hydroperoxy groups. A product with soap characteristics can be obtained by reacting the complex aluminum-coating reaction product with a saturated fatty acid.
    • 复杂的含铝反应产物通过以下方法制备,该方法包括: