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    • 9. 发明授权
    • Process for the preparation of cationically modified formaldehyde resins
of prolonged stability
    • 阳离子改性甲醛树脂的制备方法具有延长的稳定性
    • US4182839A
    • 1980-01-08
    • US921008
    • 1978-06-30
    • Gerard Tesson
    • Gerard Tesson
    • C08G12/34D21H17/51C08G12/32
    • D21H17/51C08G12/34
    • Cationic resins soluble in water and stable in solution, based upon melamine and formaldehyde, primary or secondary aliphatic amines, alkanolamines or a polyamine are prepared by reacting melamine with formaldehyde in a methylolation reaction in methanol in the presence of one or more of the aforementioned amines by heating for a period of fifteen minutes to two hours at an alkaline pH of 7.5 to 10 at a temperature of 60.degree. to 85.degree. C. The methylation-condensation reaction which follows is carried out at a pH of 5 to 6, preferably 5.4 to 5.7 until a viscosity is obtained which has a minimum of seventeen seconds measured at 20.degree. C. by an AFNOR No. 6 consistometric head. The methylation reaction is then terminated by the addition of aqueous formaldehyde and condensation is carried out for thirty minutes to two hours at 60.degree. to 90.degree. C. and a pH of 5.5 to 7, preferably a pH of 6 to 6.5. The product has longterm stability and can be used as a water-resisting or humidity-resistant coating or sizing for paper or as an adhesion promoting coating for solid supports to which a varnish is to be applied.
    • 基于三聚氰胺和甲醛,基于三聚氰胺和甲醛,初级或仲脂肪族胺,链烷醇胺或多胺,溶于水并稳定的阳离子树脂通过在甲醇中的甲氧基化反应中,在一种或多种上述胺 通过在温度为60〜85℃的碱性pH为7.5〜10的温度下加热15分钟〜2小时。以下的甲基化缩合反应在5〜6的pH下进行,优选为5.4 至5.7,直到获得在20℃下通过AFNOR 6号共识头测量的至少17秒的粘度。 然后通过加入甲醛终止甲基化反应,并在60-90℃下进行缩合30分钟至2小时,pH为5.5-7,优选pH6-6.5。 该产品具有长期的稳定性,可用作纸的防水或防湿涂料或施胶剂,或用作要施用清漆的固体支持物的增粘涂层。