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    • 82. 发明授权
    • Process and composition for protecting and cushioning protrusions
    • 用于保护和缓冲突起的方法和组合物
    • US5079269A
    • 1992-01-07
    • US323960
    • 1989-03-14
    • Ralph J. LockeDavid C. Netherton
    • Ralph J. LockeDavid C. Netherton
    • B65B55/20B65D81/02B65D81/20C08J9/12
    • C08J9/12B65B55/20B65D81/02B65D81/2023C08J2323/04
    • A process for packaging a product, particularly one with sharp protrusions such as cuts of meat, a composition for cushioning the sharp protrusions during packaging and shipping and a foamed material prepared therefrom, the process including the steps of applying a foamed composition to the product to be package; and encasing the product in an outer package. The foamed material can be applied in liquid or semi-liquid form at a point-of-contact temperture less than about l30 .degree. F. with solidification occurring substantially on contact. The foamed material is, preferably, applied selectively to cover the sharp protrusions and contains a chemical substrate which includes a polymer selected from the group consisting of polyethylene, ethylene vinyl acetate and mixtures thereof, an aliphatic hydrocarbon and an antioxidant stabilizer. A suitable gas is encapsulated within the chemical substrate.
    • 一种用于包装产品的方法,特别是具有尖锐突起的产品,例如切肉,用于在包装和运输过程中缓冲尖锐突起的组合物和由其制备的泡沫材料,该方法包括以下步骤:将发泡组合物施加到产品上 包装; 并将产品包装在外包装中。 发泡材料可以在低于约130°F的接触点温度下以液体或半液体形式施加,其中固化基本上在接触时发生。 优选地,发泡材料选择性地施加以覆盖尖锐突起并且包含化学基底,其包括选自聚乙烯,乙烯 - 乙酸乙烯酯及其混合物,脂族烃和抗氧化剂稳定剂的聚合物。 合适的气体被封装在化学基底内。
    • 85. 发明授权
    • Process for producing open-cell polyethylene foam materials and the
resultant product
    • 生产开孔聚乙烯泡沫材料和所得产品的方法
    • US4877814A
    • 1989-10-31
    • US304385
    • 1986-09-05
    • Hiroo Ito
    • Hiroo Ito
    • C08J9/00C08J9/10C08J9/38
    • C08J9/38C08J9/0061C08J9/103C08J2323/04Y10S264/05Y10S264/16Y10S264/18
    • This disclosure relates to a method for producing polyethylene open-cell foam materials, comprising a process step of pressurized heating at a temperature of 110.degree. to 135.degree. C. of a base compound consisting of polyethylene or a copolymer of polyethylene which has been compounded with an azodicarbonamide foaming agent and a bridging agent, in order to obtain a primary intermediate product with a cubical expansion coefficient of 1.0 to 2.0 times; a process step of heating the primary intermediate product under normal atmospheric pressure at a temperature of 150.degree..about.190.degree. C. and thus causing the complete decomposition of the foaming agent in order to obtain a secondary intermediate product having cell membranes capable of being easily ruptured by mechanical compression; and a process step of subjecting said secondary intermediate product to mechanical pressure in order to rupture and interconnect the closed cells; and, as needed, a foaming assist agent, or a high-melting-point resin powder, or both a high-melting-point resin powder and a foaming assist agent are added to and compounded with the base compound so that the resulting products are high-expansive or ultra-high-expansive materials with an expansion ratio of 25 times said base compound, or more, and have an open-cell ratio nof 96.about.100%.
    • 本公开涉及一种生产聚乙烯开孔泡沫材料的方法,包括在110℃至135℃的温度下加压加热由聚乙烯或聚乙烯共聚物组成的基础化合物的加工步骤,所述聚合物与已经与 偶氮二酰胺发泡剂和桥连剂,以获得立方体膨胀系数为1.0至2.0倍的初级中间产物; 在正常大气压下在150°F的温度下加热初级中间产物的工艺步骤,从而引起发泡剂的完全分解,以获得具有能够容易破裂的细胞膜的第二中间产物 通过机械压缩; 以及使所述二次中间产物受到机械压力以使所述闭孔破裂和互连的处理步骤; 并且根据需要,向基础化合物中加入发泡助剂或高熔点树脂粉末,或高熔点树脂粉末和发泡助剂二者并与其混合,得到的产物为 高膨胀性或超高膨胀性材料,其膨胀率为所述碱性化合物的25倍以上,并且具有96%的开孔率。
    • 87. 发明授权
    • Process for the production of expanded reticulated polyethylene
    • 膨胀网状聚乙烯生产方法
    • US4559190A
    • 1985-12-17
    • US657961
    • 1984-10-05
    • Saverio QuintavalleLuciano Gargani
    • Saverio QuintavalleLuciano Gargani
    • B29C44/00B29C44/10B29C69/02B29K23/00B29K105/04C08J9/10
    • B29C44/022B29C44/105C08J9/10B29K2023/00B29K2023/06B29K2105/24C08J2323/04Y10S264/18Y10S264/64
    • Process for the preparation of bodies of expanded cross-linked polyethylene, with closed cells, comprising the steps of:melting a polymer of ethylene selected among ethylene homopolymers, copolymers of ethylene with alpha-olefins, copolymers of ethylene with conjugated diolefins and relevant mixtures;homogenizing the polymer of ethylene in the molten state with a quantity of from 0.1 to 2.5% by weight of a cross-linking agent and with a quantity of from 2 to 25% by weight of an expanding agent, the cross-linking agent and expanding agent having a decomposition temperature higher than the melting point of the polymer of ethylene, the homogenizing step operating at temperatures of from 130.degree. to 150.degree. C., and for times of from 5 to 10 minutes;forming the homogeneous mixture in a solid parallelepiped shape by means of extrusion and subsequent cooling, or by means of moulding wherein the extrusion or moulding step is operated at temperatures within the range of from 130.degree. to 150.degree. C. and for times of from 1 to 10 minutes;placing the solid parallelepiped shaped body inside an air-tight closed container, pressurizing the container by means of an inert gas, and heating the solid parallelepiped shaped body, at a temperature higher than the decomposition temperature of the cross-linking agent and the expanding agent contained therein, wherein this step is operated at 170.degree.-200.degree. C., under 40-70 bar for 20-45 minutes, in the absence, or substantial absence of expansion, such that expansion is limited to less than about 5%;depressurizing the container immediately following the foregoing pressurizing and heating step for a time of from 0.5 to 3 minutes, allowing the body to expand to an end volume smaller than the volume of the container, and recovering the expanded reticulated item from the container.
    • 制备具有闭孔的膨胀交联聚乙烯体的方法,包括以下步骤:熔融选自乙烯均聚物,乙烯与α-烯烃的共聚物,乙烯与共轭二烯烃的共聚物和相关混合物的乙烯聚合物; 将熔融状态的乙烯聚合物以交联剂的0.1至2.5重量%和发泡剂的2至25重量%的量均匀化,交联剂和膨胀 分解温度高于乙烯聚合物的熔点,均化步骤在130〜150℃的温度下操作,时间为5〜10分钟; 通过挤出和随后的冷却形成固体平行六面体形状的均匀混合物,或通过模塑法,其中挤出或模塑步骤在130-150℃的温度下操作,并且从1 至10分钟; 将固体平行六面体成形体放置在气密密闭容器内,借助惰性气体对容器加压,并在高于交联剂和发泡剂分解温度的温度下加热固体平行六面体成形体 其中在不存在或基本不存在膨胀的情况下,该步骤在170℃-200℃,40-70巴条件下操作20-45分钟,使得膨胀限制在小于约5%; 在上述加压和加热步骤之后立即将容器减压0.5至3分钟,使得体膨胀至小于容器体积的端部容积,并从容器中回收膨胀的网状物品。